Phase Composition, Electrical Conductivity, and Stability of ZrO2–Sc2O3–Cr2O3Solid Electrolytes

2004 ◽  
Vol 40 (10) ◽  
pp. 1073-1078 ◽  
Author(s):  
Yu. N. Karavaev ◽  
A. D. Neuimin ◽  
E. G. Vovkotrub
2011 ◽  
Vol 04 (02) ◽  
pp. 117-122 ◽  
Author(s):  
W. ZAJAC ◽  
J. MARZEC ◽  
W. MAZIARZ ◽  
A. RAKOWSKA ◽  
J. MOLENDA

The effect of annealing of nanosized LiFePO 4 powder on microstructure, phase composition, iron valence state and electrical conductivity has been studied. Careful microstructural characterization of the as-prepared powder using high resolution TEM revealed presence of {010}-type crystal planes at the surface of crystallites, which seem to be beneficial to electrochemical activity. The second part of the work is focused on explanation of presence and evolution of Fe 3+ detected in the material. Transmission and CEMS modes of Mössbauer spectroscopy together with TEM allowed for ruling out concept of amorphous layers containing Fe 3+ ions covering crystalline LiFePO 4 grains.


2018 ◽  
Vol 18 (2) ◽  
pp. 54-63
Author(s):  
O.V. Samoylova ◽  
◽  
E.A. Trofimov ◽  
N.A. Shaburova ◽  
V.I. Geraskin

2011 ◽  
Vol 396-398 ◽  
pp. 786-790 ◽  
Author(s):  
Ke Wu Peng ◽  
Peng Zhang ◽  
Jian Guo Xie ◽  
He Li Ma

Liquidus temperature, electrical conductivity and phase composition of Al2O3-CaO-SiO2-CaF2 System were studied. The results showed that the liquidus temperature of the slag decreased with increasing CaF2 content, and its electrical conductivity increased with increasing CaF2 content and temperature. When the content of CaF2 is 20%, the liquidus temperature is 1469°C. When the contents of CaF2 is 10%,its main phase compositions are composed of Ca5Al6O14、Al2Ca3(SiO4)3、Al2(SiF6)3 and Ca3Al10O18. Ca2AlF7、Ca2Al3O6F becomes more and more with increasing the content CaF2 because of F1- replacing O2- in molten slag.


2014 ◽  
Vol 513-517 ◽  
pp. 24-27 ◽  
Author(s):  
Jia Meng Guo ◽  
Ke Wu Peng ◽  
Lei Yi ◽  
He Li Ma ◽  
Ren Chen

Liquidus temperature, electrical conductivity and phase composition of Al2O3-CaO-SiO2-CaF2-MgO slag system were studied. The results showed that the liquidus temperature of the slag decreased with increasing MgO content, and its electrical conductivity increased with increasing MgO content and temperature. When the content of MgO is 5 %, the main phase compositions of the slag are composed of MgAl2O4, Ca2SiO2F2, CaAl4O7 and Ca5Al6O14. When the content of MgO is 7 %, the main phase compositions of Al2O3-CaO-SiO2-CaF2-MgO are composed of MgAl2O4, Ca4Si2O7F2, CaAl4O7 and Ca5Al6O14.And the content of MgAl2O4 and Mg2SiO4 increased with increasing MgO.


ChemInform ◽  
2010 ◽  
Vol 30 (50) ◽  
pp. no-no
Author(s):  
K. I. Furaleva ◽  
S. G. Prutchenko ◽  
A. V. Mitin ◽  
E. D. Politova

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