Modes of eastern equatorial Pacific thermocline variability: Implications for ENSO dynamics over the last glacial period

2009 ◽  
Vol 24 (3) ◽  
Author(s):  
Guillaume Leduc ◽  
Laurence Vidal ◽  
Olivier Cartapanis ◽  
Edouard Bard
2010 ◽  
Vol 7 (2) ◽  
pp. 1959-1993 ◽  
Author(s):  
E. Douville ◽  
M. Paterne ◽  
G. Cabioch ◽  
P. Louvat ◽  
J. Gaillardet ◽  
...  

Abstract. The "δ11B-pH" technique was applied to modern and ancient Porites from the sub-equatorial Pacific areas (Tahiti and Marquesas) spanning a time interval from 0 to 20 720 calendar years to determine the amplitude of pH changes between the Last Glacial Period and the Holocene. Boron isotopes were measured by Multi-Collector-Inductively Coupled Plasma Mass Spectrometry (MC-ICPMS) with an external reproducibility of 0.25‰, allowing a precision of ±0.025 pH-units. The boron concentration [B] and isotopic composition of modern samples indicate that the temperature strongly controls the partition coefficient KD for different aragonite species. Modern coral δ11B values and the reconstructed sea surface pH values for different Pacific areas match the measured pH expressed on the Sea Water Scale and confirm the calculation parameters that were previously determined by laboratory calibration exercises. Most ancient sea surface pH reconstructions near Marquesas are higher than modern values. These values range between 8.20 and 8.26 for the Holocene and reached 8.31 at the end of the last glacial period (20.7 kyr BP). At the end of the Younger Dryas (11.50±0.1 kyr BP), the central sub-equatorial Pacific experienced a dramatic drop of up to 0.2 pH-units from the average pH of 8.2 before and after this short event. Using the CO2SYS program, we recalculated the aqueous pCO2 to be 400±24 ppmV at around 11.5 kyr BP for corals at Marquesas and ~500 ppmV near Tahiti where it was assumed that pCO2 in the atmosphere was 250 ppmV. Throughout the Holocene, the difference in pCO2 between the ocean and the atmosphere at Marquesas (ΔpCO2) indicates that the surface waters behave as a moderate CO2 sink (−67 to −11 ppmV) during El Niño-like conditions. In contrast, during the last glacial/interglacial transition, this area was a moderate source of CO2 (−9 to 56 ppmV) for the atmosphere, highlighting predominant La Niña-like conditions. Such conditions were particularly pronounced at the end of the Younger Dryas with a large amount of CO2 released with ΔpCO2 of +140 ppmV. This last finding provides further evidence of the marked changes to the water mass pH and temperature properties in the equatorial Pacific at the Younger Dryas- Holocene transition and the strong impact of oceanic dynamic on the atmospheric CO2 content.


2010 ◽  
Vol 7 (8) ◽  
pp. 2445-2459 ◽  
Author(s):  
E. Douville ◽  
M. Paterne ◽  
G. Cabioch ◽  
P. Louvat ◽  
J. Gaillardet ◽  
...  

Abstract. The "δ11B-pH" technique was applied to modern and ancient corals Porites from the sub-equatorial Pacific areas (Tahiti and Marquesas) spanning a time interval from 0 to 20.720 calendar years to determine the amplitude of pH changes between the Last Glacial Period and the Holocene. Boron isotopes were measured by Multi-Collector – Inductively Coupled Plasma Mass Spectrometry (MC-ICPMS) with an external reproducibility of 0.25‰, allowing a precision of about ±0.03 pH-units for pH values between 8 and 8.3. The boron concentration [B] and isotopic composition of modern samples indicate that the temperature strongly controls the partition coefficient KD for different aragonite species. Modern coral δ11B values and the reconstructed sea surface pH values for different Pacific areas match the measured pH expressed on the seawater scale and confirm the calculation parameters that were previously determined by laboratory calibration exercises. Most ancient sea surface pH reconstructions near Marquesas are higher than modern values. These values range between 8.19 and 8.27 for the Holocene and reached 8.30 at the end of the last glacial period (20.7 kyr BP). At the end of the Younger Dryas (11.50±0.1 kyr BP), the central sub-equatorial Pacific experienced a dramatic drop of up to 0.2 pH-units from the average pH of 8.2 before and after this short event. Using the marine carbonate algorithms, we recalculated the aqueous pCO2 to be 440±25 ppmV at around 11.5 kyr BP for corals at Marquesas and ~500 ppmV near Tahiti where it was assumed that pCO2 in the atmosphere was 250 ppmV. Throughout the Holocene, the difference in pCO2 between the ocean and the atmosphere at Marquesas (ΔpCO2) indicates that the surface waters behave as a moderate CO2 sink or source (−53 to 20 ppmV) during El Niño-like conditions. By contrast, during the last glacial/interglacial transition, this area was a marked source of CO2 (21 to 92 ppmV) for the atmosphere, highlighting predominant La Niña-like conditions. Such conditions were particularly pronounced at the end of the Younger Dryas with a large amount of CO2 released with ΔpCO2 of +185±25 ppmV. This last finding provides further evidence of the marked changes in the surface water pH and temperature in the equatorial Pacific at the Younger Dryas-Holocene transition and the strong impact of oceanic dynamic on the atmospheric CO2 content.


2020 ◽  
Vol 532 ◽  
pp. 116012 ◽  
Author(s):  
Jessica B. Volz ◽  
Bo Liu ◽  
Male Köster ◽  
Susann Henkel ◽  
Andrea Koschinsky ◽  
...  

2017 ◽  
Vol 13 (4) ◽  
pp. 345-358 ◽  
Author(s):  
Marília C. Campos ◽  
Cristiano M. Chiessi ◽  
Ines Voigt ◽  
Alberto R. Piola ◽  
Henning Kuhnert ◽  
...  

Abstract. Abrupt millennial-scale climate change events of the last deglaciation (i.e. Heinrich Stadial 1 and the Younger Dryas) were accompanied by marked increases in atmospheric CO2 (CO2atm) and decreases in its stable carbon isotopic ratios (δ13C), i.e. δ13CO2atm, presumably due to outgassing from the ocean. However, information on the preceding Heinrich Stadials during the last glacial period is scarce. Here we present δ13C records from two species of planktonic foraminifera from the western South Atlantic that reveal major decreases (up to 1 ‰) during Heinrich Stadials 3 and 2. These δ13C decreases are most likely related to millennial-scale periods of weakening of the Atlantic meridional overturning circulation and the consequent increase (decrease) in CO2atm (δ13CO2atm). We hypothesise two mechanisms that could account for the decreases observed in our records, namely strengthening of Southern Ocean deep-water ventilation and weakening of the biological pump. Additionally, we suggest that air–sea gas exchange could have contributed to the observed δ13C decreases. Together with other lines of evidence, our data are consistent with the hypothesis that the CO2 added to the atmosphere during abrupt millennial-scale climate change events of the last glacial period also originated in the ocean and reached the atmosphere by outgassing. The temporal evolution of δ13C during Heinrich Stadials 3 and 2 in our records is characterized by two relative minima separated by a relative maximum. This w structure is also found in North Atlantic and South American records, further suggesting that such a structure is a pervasive feature of Heinrich Stadial 2 and, possibly, also Heinrich Stadial 3.


2013 ◽  
Vol 160 (5) ◽  
pp. 1285-1296 ◽  
Author(s):  
D. W. Foltz ◽  
S. D. Fatland ◽  
M. Eléaume ◽  
K. Markello ◽  
K. L. Howell ◽  
...  

2021 ◽  
Author(s):  
Mohamed M. Ezat ◽  
Tine L. Rasmussen ◽  
Mathis P. Hain ◽  
Mervyn Greaves ◽  
James W B Rae ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document