scholarly journals Diamond growth from organic compounds in hydrous fluids deep within the Earth

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Maria Luce Frezzotti

Abstract At subduction zones, most diamonds form by carbon saturation in hydrous fluids released from lithospheric plates on equilibration with mantle rocks. Although organic molecules are predicted among dissolved species which are the source for carbon in diamonds, their occurrence is not demonstrated in nature, and the physical model for crustal diamond formation is debated. Here, using Raman microspectroscopy, I determine the structure of carbon-based phases inside fluid inclusions in diamond-bearing rocks from the Alps. The results provide direct evidence that diamond surfaces are coated by sp2-, and sp3-bonded amorphous carbon and functional groups of carboxylic acids (e.g., carboxyl, carboxylate, methyl, and methylene), indicating the geosynthesis of organic compounds in deep hydrous fluids. Moreover, this study suggests diamond nucleation via metastable molecular precursors. As a possible scenario, with carbon saturation by reduction of carboxylate groups, I consider tetrahedral H-terminated C groups as templates for the growth of sp3-structured carbon.

Elements ◽  
2021 ◽  
Vol 17 (1) ◽  
pp. 9-16
Author(s):  
Philippe Agard ◽  
Mark R. Handy

The Alps preserve abundant oceanic blueschists and eclogites that exemplify the selective preservation of fragments of relatively short-lived, small, slow-spreading North Atlantic–type ocean basins whose subducting slabs reach down to the Mantle Transition Zone at most. Whereas no subducted fragments were returned during the first half of the subduction history, those exhumed afterwards experienced conditions typical of mature subduction zones worldwide. Sedimentary-dominated units were under-plated intermittently, mostly at ~30–40 km depth. Some mafic–ultramafic-dominated units formed close to the continent were subducted to ~80 km and offscraped from the slab only a few million years before continental subduction. Spatiotemporal contrasts in burial and preservation of the fragments reveal how along-strike segmentation of the continental margin affects ocean subduction dynamics.


2017 ◽  
Vol 56 (17) ◽  
pp. 10596-10608 ◽  
Author(s):  
Akbar Mohammad ◽  
Prakash Chandra ◽  
Topi Ghosh ◽  
Mauro Carraro ◽  
Shaikh M. Mobin

2000 ◽  
Vol 9 (3-6) ◽  
pp. 246-250 ◽  
Author(s):  
Simon Proffitt ◽  
Christopher H.B. Thompson ◽  
Aurora Gutierrez-Sosa ◽  
Nathan Paris ◽  
Nagindar K. Singh ◽  
...  

1994 ◽  
Vol 368 ◽  
Author(s):  
A. N. Patil ◽  
M. A. Bañares ◽  
X. Lei ◽  
T. P. Fehlner ◽  
E. E. Wolf

ABSTRACTComplex cobalt-carbonyl ligand based clusters of clusters are used as molecular precursors for self-supported model catalysts. These precursors consist of two metal layers: an outer of the complex Co-carbonyl ligands, and a core of metal (e.g. Co or Zn) carboxylate groups. Partial thermolysis at low temperature (LT) of these materials under hydrogen results in almost completely decarbonylated material with a mainly unchanged carboxylate metal core. Complete pyrolysis at higher temperatures (HT) in hydrogen leads to mixed metal environment. These materials were used as a heterogenous catalyst in the gas phase hydrogenation of crotonaldehyde. The maximum yield of 27 % of desired product crotyl alcohol was observed when HT-CoCo was used as the catalyst at 423 K. The catalyst activity and the crotyl alcohol selectivity remained unchanged over 2 days of operation. The bimetallic ZnCo catalysts showed lower selectivity to crotyl alcohol than the CoCo catalysts.


2021 ◽  
Author(s):  
Christopher P. Ender ◽  
Jiaxu Liang ◽  
Jonas Friebel ◽  
Todd Zapata ◽  
Manfred Wagner ◽  
...  

2021 ◽  
Author(s):  
Christopher P. Ender ◽  
Jiaxu Liang ◽  
Jonas Friebel ◽  
Todd Zapata ◽  
Manfred Wagner ◽  
...  

2021 ◽  
Author(s):  
Yossi Mart ◽  
Liran Goren ◽  
Einat Aharonov

<p>The post-Triassic age of all oceanic lithospheres indicates the efficiency and the sustainability of lithospheric subduction, which consumes the basaltic seafloor and recirculates it in the upper mantle. Since at present the initiation of subduction is very rare, comprehension of this cardinal process should be carried through modeling – numeric or analog. While deciphering processes through numeric modeling is commonly comprehensive, the analog models can determine major factor that constrain a tectonic procedure. Analog centrifuge experiments were applied to initiate self-sustained modelled subduction, trying to determine the critical factors that trigger its early stages.</p><p>Analytically we presumed that where densities of two lithospheric plates, juxtaposed across a weakness zone, exceed a critical value, then the denser lithosphere eventually will drive underneath the lighter one, provided the friction across the interface is not too high. Consequently, analog experiments were carried out in a centrifuge at acceleration of ca. 1000 g., deforming miniaturized models of three layers representing the asthenosphere, the ductile and the brittle lithosphere. The lithospheres were modeled to include lighter and denser components, juxtaposed along a slightly lubricated contact plane, where the density difference between these components was ca. 200 kg/m<sup>3</sup>. No mechanism of lateral force was applied in the experiment (even though such a vector exists in nature due to the seafloor spreading at the oceanic ridges), to test the possibility of subduction in domains where such a force is minor or non-existent.</p><p>The analog experiments showed that the penetration of the denser modeled lithosphere under the lighter one led to extension and subsequent break-up of the over-riding plate. That break-up generated seawards trench rollback, normal faulting, rifting, and formed proto-back-arc basins. Lateral differential reduction of the friction between the juxtaposed plates led to the development of arcuate subduction zones. The experimental miniaturization, and subsequent numerical and analytical modeling, suggest that the observed deformation in the analog models could be meaningful to the planet as well.</p><p>Constraints of the analog experimentation setting did not enable the modeling of the subduction beyond the initial stages, but there is ground to presume that at depths of 40-50 km, metamorphic processes of the generation of eclogites would change the initial mineralogy on the subducting plate. Reactions with water would convert basalts into metamorphic serpentinites and schists. Higher temperatures and pressures would melt parts of the subducted slab to generate felsic magmas, which would ascend towards the surface diapirically due to their lighter density. Alternately, low availability of H<sub>2</sub>O would gradually alter the oceanic basalt and gabbro into eclogite, which would sink into the mantle due to its increased density.</p>


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