scholarly journals Observation of correlated excitations in bimolecular collisions

2018 ◽  
Vol 10 (4) ◽  
pp. 469-473 ◽  
Author(s):  
Zhi Gao ◽  
Tijs Karman ◽  
Sjoerd N. Vogels ◽  
Matthieu Besemer ◽  
Ad van der Avoird ◽  
...  
Keyword(s):  
Bimolecular Collisions

Effect of dielectric constant on the rate of electron spin exchange of Fremy's salt in solution

1986 ◽  
Vol 51 (11) ◽  
pp. 2433-2436 ◽  
Author(s):  
Hamza A. Hussain ◽  
Waleed A. A. Kuder
Keyword(s):  
Aqueous Solution ◽  
Dielectric Constant ◽  
Electron Spin ◽  
Spin Exchange ◽  
Bimolecular Collisions

The rate of electron spin exchange in aqueous solution of potassium nitrosodisulphonate K2(SO3)2NO, has been investigated by ESR and found to depend on the dielectric constant of the medium. This observation lead to the calculation of the collision diameter 2 nm which corresponds to bimolecular collisions between species carrying two nagative charges.

scholarly journals Quantum-State Resolved Bimolecular Collisions of Velocity-Controlled OH with NO Radicals

Science ◽  
2012 ◽  
Vol 338 (6110) ◽  
pp. 1060-1063 ◽  
Author(s):  
M. Kirste ◽  
X. Wang ◽  
H. C. Schewe ◽  
G. Meijer ◽  
K. Liu ◽  
...  
Keyword(s):  
Quantum State ◽  
Quantum State Resolved ◽  
Bimolecular Collisions

Tunnelling in bimolecular collisions

1987 ◽  
Vol 87 (1) ◽  
pp. 81-89 ◽  
Author(s):  
George C. Schatz
Keyword(s):  
Bimolecular Collisions

Far-infrared collision-induced absorption in some compressed gaseous halogenated methanes

1985 ◽  
Vol 63 (4) ◽  
pp. 475-478 ◽  
Author(s):  
Nguyen- Van-Thanh ◽  
I. Rossi
Keyword(s):  
Reasonable Agreement ◽  
Far Infrared ◽  
Molecular Polarizability ◽  
Experimental Literature ◽  
Induced Absorption ◽  
Bimolecular Collisions ◽  
Halogenated Methanes

Calculations of the collision-induced rotational and translational absorptions have been performed for seven pure halogenated methanes CH3F, CH3Cl, CF3H, CF3Cl, CF3Br, CCl3H, and CCl3F. We have considered the theory of Frost for multipole-induced dipolar absorption in bimolecular collisions taking the anisotropy of the molecular polarizability into account. The comparison with experimental literature data of CF3H and CF3Cl was reported; a reasonable agreement was obtained only for CF3Cl.

scholarly journals The mechanism of the hydrogen-oxygen reaction - IV. The activation energy of the initiating process

1946 ◽  
Vol 186 (1007) ◽  
pp. 462-469 ◽  
Keyword(s):  
Activation Energy ◽  
Temperature Coefficient ◽  
Thermal Reaction ◽  
Hydrogen Atoms ◽  
Production Of Hydrogen ◽  
Bimolecular Collisions ◽  
Alkali Chlorides ◽  
Principal Chain ◽  
Oxygen Reaction

On the basis of the theory discussed in the preceding parts of this series, a method has been devised for determining the temperature coefficient and hence the activation energy of the process responsible for starting the chains in the thermal reaction between hydrogen and oxygen. The results are consistent with the view that the production of hydrogen atoms (in bimolecular collisions between hydrogen and other molecules present) is the principal chain initiating reaction at temperatures above 560° C in vessels coated with alkali chlorides.

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