An unusual carbon–carbon bond scission reaction with molecular oxygen under mild conditions; formation of piperidines from 1-azabicyclo[2.2.2]octanes

1997 ◽  
pp. 3679-3684 ◽  
Author(s):  
Timothy Norris ◽  
Dinos Santafianos ◽  
Jon Bordner
Keyword(s):  
Molecular Oxygen ◽  
Carbon Bond ◽  
Mild Conditions ◽  
Carbon Carbon Bond ◽  
Bond Scission

Carbon–Carbon Bond Cleavage and Esterification of Phenylacetonitrile and its Derivatives Affording the Corresponding Benzoic Esters

2007 ◽  
Vol 2007 (6) ◽  
pp. 323-324 ◽  
Author(s):  
Zhiyuan Wang ◽  
Junhui Kang ◽  
Mingxin Yu
Keyword(s):  
Potassium Iodide ◽  
Elemental Analysis ◽  
Bond Cleavage ◽  
Carbon Bond ◽  
H Nmr ◽  
Mild Conditions ◽  
Carbon Carbon Bond

Phenylacetonitrile and its derivatives were treated with alcohols in the presence of potassium iodide and iodine affording the corresponding benzoate esters via degradation, oxidation and esterification under mild conditions. The products were characterised by IR, 1H NMR, MS and elemental analysis.

Effects of iron-oxygen precursor phase on carbon-carbon bond scission in benzyl(naphthylbenzyl)methane

1994 ◽  
Vol 8 (1) ◽  
pp. 56-62 ◽  
Author(s):  
John C. Linehan ◽  
Dean W. Matson ◽  
John G. Darab
Keyword(s):  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Precursor Phase ◽  
Bond Scission
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