Nanotwin-assisted nitridation in FeNi nanopowders for synthesis of rare-earth-free magnets

L10-ordered FeNi alloy (tetrataenite), a promising candidate for rare-earth-free and low-cost permanent magnet applications, is attracting increasing attention from academic and industrial communities. Highly ordered single-phase L10-FeNi is difficult to synthesis efficiently because of its low chemical order-disorder transition temperature (200–320 ℃). A non-equilibrium synthetic route utilizing a nitrogen topotactic reaction has been considered a valid approach, although the phase transformation mechanism is currently unknown. Herein, we investigated the basis of this reaction, namely the formation mechanism of the tetragonal FeNiN precursor phase during the nitridation of FeNi nanopowders. Detailed microstructure analysis revealed that the FeNiN precursor phase could preferentially nucleated at the nanotwinned region during nitridation and subsequently grew following a massive transformation, with high-index irrational orientation relationships and ledgewise growth motion detected at the migrating phase interface. This is the first report of a massive phase transformation detected in an Fe-Ni-N system and provides new insights into the phase transformation during the nitriding process. This work is expected to promote the synthetic optimization of fully ordered FeNi alloys for various magnetic applications.

Structure of the amorphous titania precursor phase of N-doped photocatalysts

Amorphous titania samples prepared by ammonia solution neutralization of titanyl sulphate have been characterized by chemical and thermal analyses, and with reciprocal-space and real-space fitting of wide-angle synchrotron X-ray scattering data.

A Comparative Study of Pathological Nanomineral Aggregates with Distinct Morphology in Human Aortic Atherosclerotic Plaques

Calcification exists in atherosclerotic plaques in the form of nanomineral aggregates and is closely related to the development of atherosclerosis. Spheroidal and massive calcification are two major types of calcification found in atherosclerotic tissue. However, the exact difference between these two types of calcification is still not clear. Samples composed entirely of spheroidal calcifications and massive calcifications were isolated from aortic atherosclerotic plaques and tested using both bulk and microscopic analysis techniques. Scanning electron microscopy and transmission electron microscopy showed that spheroidal calcifications had a core–shell structure. Massive calcifications were composed of randomly arranged nanocrystals. Synchrotron radiation X-ray diffraction, Raman spectroscopy and selected area electron diffraction showed amorphous calcium phosphate, whitlockite and carbonate hydroxyapatite all existing in spheroidal calcification, while massive calcification only consisted of carbonate hydroxyapatite. We conclude that amorphous calcium phosphate may act as a precursor phase of spheroidal calcifications that eventually transforms into a crystalline phase, while whitlockite in lesions could aggravate the progression of atherosclerosis.

Edge modes of gravity. Part III. Corner simplicity constraints

In the tetrad formulation of gravity, the so-called simplicity constraints play a central role. They appear in the Hamiltonian analysis of the theory, and in the Lagrangian path integral when constructing the gravity partition function from topological BF theory. We develop here a systematic analysis of the corner symplectic structure encoding the symmetry algebra of gravity, and perform a thorough analysis of the simplicity constraints. Starting from a precursor phase space with Poincaré and Heisenberg symmetry, we obtain the corner phase space of BF theory by imposing kinematical constraints. This amounts to fixing the Heisenberg frame with a choice of position and spin operators. The simplicity constraints then further reduce the Poincaré symmetry of the BF phase space to a Lorentz subalgebra. This picture provides a particle-like description of (quantum) geometry: the internal normal plays the role of the four-momentum, the Barbero-Immirzi parameter that of the mass, the flux that of a relativistic position, and the frame that of a spin harmonic oscillator. Moreover, we show that the corner area element corresponds to the Poincaré spin Casimir. We achieve this central result by properly splitting, in the continuum, the corner simplicity constraints into first and second class parts. We construct the complete set of Dirac observables, which includes the generators of the local $$ \mathfrak{sl}\left(2,\mathrm{\mathbb{C}}\right) $$ sl 2 ℂ subalgebra of Poincaré, and the components of the tangential corner metric satisfying an $$ \mathfrak{sl}\left(2,\mathrm{\mathbb{R}}\right) $$ sl 2 ℝ algebra. We then present a preliminary analysis of the covariant and continuous irreducible representations of the infinite-dimensional corner algebra. Moreover, as an alternative path to quantization, we also introduce a regularization of the corner algebra and interpret this discrete setting in terms of an extended notion of twisted geometries.

Textural Characteristics of Barren and Mineralized Colloform Quartz Bands at the Low-Sulfidation Epithermal Deposits of the Omu Camp in Hokkaido, Japan: Implications for Processes Resulting in Bonanza-Grade Precious Metal Enrichment

The Miocene low-sulfidation epithermal deposits of the Omu camp in northeastern Hokkaido, Japan, are small past-producers of precious metals and represent significant exploration targets for high-grade Au and Ag ores. The quartz textures of ore samples and the distribution of ore minerals within quartz veins were studied to identify the processes that resulted in the bonanza-grade precious metal enrichment in these deposits. In the high-grade vein samples, which are crustiform or brecciated in hand specimen, ore minerals exclusively occur within colloform quartz bands. High-magnification microscopy reveals that ore-bearing colloform bands consist of fine-grained quartz exhibiting relic microsphere textures and quartz having a mosaic texture that formed through recrystallization of the microspheres. The presence of relic microspheres is evidence that the microcrystalline quartz hosting the ore minerals formed through recrystallization of a noncrystalline silica precursor phase. The ore-hosting colloform bands composed of agglomerated microspheres alternate with barren colloform quartz bands that are composed of fibrous chalcedonic quartz and mosaic quartz formed through recrystallization of the chalcedony. The findings of this study are consistent with previous models linking bonanza-grade precious metal enrichment and the formation of bands of noncrystalline silica in low-sulfidation epithermal veins to episodic vigorous boiling or flashing of the hydrothermal system in the near-surface environment.