Direct determination of free sulfur dioxide in wine and dried apple samples by using a gas generating and purging device coupled to a continuous flow (injection) system

The Analyst ◽  
1995 ◽  
Vol 120 (7) ◽  
pp. 2013-2018 ◽  
Author(s):  
Zheng-liang Zhi ◽  
Angel Ríos ◽  
Miguel Valcárcel
1982 ◽  
Vol 28 (3) ◽  
pp. 440-443 ◽  
Author(s):  
B F Rocks ◽  
R A Sherwood ◽  
C Riley

Abstract In this flow-injection system for direct determination of lithium in serum by atomic absorption spectroscopy, the 10-microL sample is manually injected into a continuously flowing non-segmented stream of de-ionized water, which is pumped, via a dispersion tube, to the spectrometer's nebulizer. Controlled dispersion of the sample zone, before it is introduced into the nebulizer, produces the required sample dilution. Effects of varying the length of the dispersion tube, the flow rate, and the sample size were studied. Analytical readout is obtained, in the form of transient peaks, 5 s after sample injection. It is necessary to include physiological concentrations of sodium and potassium in the standard because each of these cations enhances the lithium absorbance signal. Analytical recovery (98.5 to 101%) and CV (about 2%) are good, and results compare well with those obtained by aspiration of prediluted samples (n = 121, r = 0.99).


1987 ◽  
Vol 59 (4) ◽  
pp. 666-670 ◽  
Author(s):  
Angel. Rios ◽  
M. D. Luque de Castro ◽  
Miguel. Valcarcel ◽  
Horacio A. Mottola

The Analyst ◽  
1990 ◽  
Vol 115 (5) ◽  
pp. 575-579 ◽  
Author(s):  
Maria Rosario Pereiro García ◽  
Marta Elena Díaz García ◽  
Alfredo Sanz-Medel

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