The 1∶1 and 2∶1 complexes of diethyl ether with tin tetrachloride and their stability, studied by 119Sn NMR spectroscopy†

Author(s):  
Dan Fǎrcaşiu ◽  
Rodica Leu ◽  
Paula J. Ream
Polyhedron ◽  
1990 ◽  
Vol 9 (11) ◽  
pp. 1389-1395 ◽  
Author(s):  
Song-Ping Huang ◽  
Sandeep Dhingra ◽  
Mercouri G. Kanatzidis

1984 ◽  
Vol 39 (8) ◽  
pp. 1037-1041 ◽  
Author(s):  
Susanna Kerschl ◽  
Bernd Wrackmeyer

AbstractDimethylbis(phenylethynyl)stannane (1) reacts with trialkylboranes, BR3 (2), to give bis(alkenyl stannanes (5) (R = C2H5), 1-bora-4-stanna-2,5-cyclohexadienes (6 ) (R = C2H5, C3H7i), 1- stanna-2,4-cyclopentadienes (7) (R = C2H5) and l-stanna-3-cyclopentenes (8 ) (R = CH3, C2H5). 13C and 119Sn NMR data prove the structure of the reaction products (5 to 8 ). 119Sn NMR is useful (i) for following the course of the reaction (mechanism!) and (ii) for quantitative analysis of the product distribution. Deorganoboration reactions play an important role in the formation of the various heterocyclic systems.


2020 ◽  
Vol 124 (28) ◽  
pp. 15015-15027
Author(s):  
Michelle Ha ◽  
Abhoy Karmakar ◽  
Guy M. Bernard ◽  
Enoc Basilio ◽  
Arun Krishnamurthy ◽  
...  

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