Excited state quenching kinetics of zinc meso-tetrakis (N-methylpyridinium-4-yl) porphyrin by methyl viologen in AOT reverse micelles

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Sílvia M. B. Costa
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Debasis Banik ◽  
Niloy Kundu ◽  
Surajit Ghosh ◽  
Chiranjib Banerjee ◽  
...  

1989 ◽  
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2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Reza Farhoosh

AbstractEffect of hydroxytyrosol (HT) and tert-butylhydroquinone (TBHQ) on the kinetics of lipid hydroperoxides (LOOH) accumulation during the initiation and propagation peroxidations of canola and fish oils at 60 °C was studied. The initiation kinetics of the inhibited peroxidation indicated considerable relative activities, A, for HT and TBHQ in the canola (> 3200 and > 27,000, respectively) and fish (> 120 and > 5000, respectively) oils. The critical concentrations of LOOH reverse micelles (CMCL = 33 mM and 57 mM in the canola and fish, respectively, oils) significantly decreased, on average, to about one-third and 8% of the initial values for HT and TBHQ, respectively. Interestingly, the propagation kinetics of the inhibited peroxidation demonstrated that the antioxidants were still able to inhibit peroxidation, so that the relative propagation oxidizability parameter Rn′ was significantly improved to < 0.5 for HT and to < 0.2 for TBHQ in the canola and fish, respectively, oils.


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