Bonding in radon hexafluoride: An unusual relativistic problem?

2003 ◽  
Vol 5 (6) ◽  
pp. 1103-1105 ◽  
Author(s):  
Michael Filatov ◽  
Dieter Cremer
Keyword(s):  
ChemInform ◽  
2003 ◽  
Vol 34 (22) ◽  
Author(s):  
Michael Filatov ◽  
Dieter Cremer
Keyword(s):  

1980 ◽  
Vol 56 (3) ◽  
pp. 263-288 ◽  
Author(s):  
D. Dominici ◽  
J. Gomis ◽  
G. Longhi
Keyword(s):  

2007 ◽  
Vol 22 (14n15) ◽  
pp. 2609-2618 ◽  
Author(s):  
ANTONIO S. DE CASTRO

The intrinsically relativistic problem of spinless particles subject to a general mixing of vector and scalar kink-like potentials (~ tanh γx) is investigated. The problem is mapped into the exactly solvable Sturm–Liouville problem with the Rosen–Morse potential and exact bounded solutions for particles and antiparticles are found. The behavior of the spectrum is discussed in some detail. An apparent paradox concerning the uncertainty principle is solved by recurring to the concept of effective Compton wavelength.


1984 ◽  
Vol 39 (8) ◽  
pp. 720-732
Author(s):  
Eberhard Kern

The non-relativistic motion of a particle in a central field with 1/r potential, e.g. the motion of an electron in the Coulomb field of a charged nucleus at rest, is described by the equation of motion (non-relativistic Kepler problem) m x″ = α · x /r3 with α = ez e (product of the charges of the central body ez and the electron e). From this equation of motion, three statements of conservation can be derived: in respect of the energy E, of the angular momentum L and of the Lenz vector Λ = m {x′× L + α ·x/r}. The geometric meaning of Λ is that of a vector pointing in the direction of the perihelion of the particle orbits (conic sections). It will be demonstrated that also at the relativistic Kepler problem, which is based on the equation of motion an analogous Lenz vector exists. It represents a quantity of conservation - in the same way as the relativistic energy and the relativistic angular momentum. For the transitional case → ∞, where the relativistic problem turns into the non-relativistic problem, the relativistic Lenz vector also turns into the non-relativistic Lenz vector. The generalised (relativistic) Lenz vector has also a geometric meaning. Its direction coincides with the oriented axis of symmetry of the orbits (rosettes, spirals, hyperbola-type curves etc.). The quantity of conservation Λ occupies a special position in respect of the quantities of conservation energy and angular momentum. Whereas the energy and the angular momentum correspond with a symmetry of time and space, the Lenz quantity of conservation corresponds with a symmetry of the orbits. The fact that the Lenz vector can relativistically be generalised touches thereby on principal aspects.


The non-relativistic problem of scattering of a particle by a target possessing discrete excited states can be expressed in terms of ‘physical’ resonance states, i.e. solutions of the wave equation for complex energy in which in the asymptotic form of the wave function in each channel one of the two possible exponential terms (which for real energy represent the incoming and outgoing wave) vanishes. This representation is possible provided the interaction between the particles and the target vanishes exactly beyond a certain distance. If the interaction decreases exponentially a similar representation may in some cases still be obtained by analytic continuation; it contains also ‘redundant’ eigenstates in which the coefficient of one of the asymptotic waves tends to infinity. Possible generalizations of the method are discussed.


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