Two contrasting ethynyl hydroboration pathways in the formation of a novel tris-hydroboration product from reaction of dimesitylborane with 2,5-diethynylpyridineElectronic supplementary information (ESI) available: NMR data for 4, rotatable 3-D molecular structure diagrams of optimised geometries in CHIME format and energy data for optimised geometries. See http://www.rsc.org/suppdata/cc/b3/b316250h/

A polycationic dendrimer as noncovalent support for anionic organometallic complexesElectronic supplementary information (ESI) available: 1H NMR data (including T1 and T2 data) and IR data for 1, 2, 2a, 3, 3a, 4 and 5. ESI-MS and elemental analysis data for 3. Space-filling model of the calculated molecular structure of 3. See http://www.rsc.org/suppdata/cc/b2/b201491b/

Chemical Communications ◽

10.1039/b201491b ◽

2002 ◽

pp. 1636-1637 ◽

Cited By ~ 38

Author(s):

Rob van de Coevering ◽

Mark Kuil ◽

Robertus J. M. Klein Gebbink ◽

Gerard van Koten

Keyword(s):

Molecular Structure ◽

1H Nmr ◽

Elemental Analysis ◽

Analysis Data ◽

Supplementary Information ◽

Elemental Analysis Data ◽

Space Filling ◽

Esi Ms ◽

Nmr Data ◽

T1 And T2

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Intra- and inter-molecular carboranyl C–H⋯N hydrogen bonds in pyridyl-containing ortho-carboranesElectronic supplementary information (ESI) available: rotatable 3-D molecular structure diagrams of experimental structures of 1–4 and of MP2/6-31G* optimised geometries 1a–7b in CHIME format. Computed GIAO NMR data for 1b–4c. See http://www.rsc.org/suppdata/dt/b2/b209931d/

Dalton Transactions ◽

10.1039/b209931d ◽

2002 ◽

pp. 475-482 ◽

Cited By ~ 75

Author(s):

Elena S. Alekseyeva ◽

Andrei S. Batsanov ◽

Lynn A. Boyd ◽

Mark A. Fox ◽

Thomas G. Hibbert ◽

...

Keyword(s):

Molecular Structure ◽

Hydrogen Bonds ◽

Supplementary Information ◽

Nmr Data

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Sterically controlled reactivity of palladium(ii) tetranuclear cyclometallated complexes. Crystal and molecular structure of the novel tetranuclear compound [Pd2{1,3-[C(H)NCH2C4H7O]2C6H2}(µ-Cl)(Cl)(PPh3)]2Electronic supplementary information (ESI) available: 1H and 31P NMR data for compounds 1–15 and 17. See http://www.rsc.org/suppdata/nj/b1/b111671a/

New Journal of Chemistry ◽

10.1039/b111671a ◽

2002 ◽

Vol 26 (7) ◽

pp. 895-901 ◽

Cited By ~ 16

Author(s):

Alberto Fernández ◽

Esther Pereira ◽

Jesús J. Fernández ◽

Margarita López-Torres ◽

Antonio Suárez ◽

...

Keyword(s):

Molecular Structure ◽

31P Nmr ◽

Crystal And Molecular Structure ◽

Supplementary Information ◽

The Novel ◽

Nmr Data ◽

Cyclometallated Complexes

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Engineered biosynthesis of novel spinosyns bearing altered deoxyhexose substituentsElectronic supplementary information (ESI) available: 1H and 13C NMR data for compounds 5–8. See http://www.rsc.org/suppdata/cc/b2/b200536k/

Chemical Communications ◽

10.1039/b200536k ◽

2002 ◽

pp. 618-619 ◽

Cited By ~ 25

Author(s):

Sabine Gaisser ◽

Christine J. Martin ◽

Barrie Wilkinson ◽

Rose M. Sheridan ◽

Rachel E. Lill ◽

...

Keyword(s):

13C Nmr ◽

Supplementary Information ◽

1H And 13C Nmr ◽

Nmr Data

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Molecular structure and infrared spectra of dimethyl oxalateElectronic Supplementary Information available. See http://www.rsc.org/suppdata/cp/b1/b107232n/

Physical Chemistry Chemical Physics ◽

10.1039/b107232n ◽

2002 ◽

Vol 4 (6) ◽

pp. 1014-1020 ◽

Cited By ~ 9

Author(s):

Susy Branco Lopes ◽

Leszek Lapinski ◽

Rui Fausto

Keyword(s):

Molecular Structure ◽

Infrared Spectra ◽

Supplementary Information

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3{5}-tert-Butylpyrazole is a ditopic receptor for zinc(ii) halidesElectronic supplementary information (ESI) available: tabulated and plotted NMR data for 1–3 in the presence and absence of added NBun4X (X– = Cl–, Br–, I–, BF4–). See http://www.rsc.org/suppdata/cc/b2/b200551b/

Chemical Communications ◽

10.1039/b200551b ◽

2002 ◽

pp. 704-705 ◽

Cited By ~ 35

Author(s):

Xiaoming Liu ◽

Colin A. Kilner ◽

Malcolm A. Halcrow

Keyword(s):

Supplementary Information ◽

Nmr Data ◽

Ditopic Receptor ◽

Presence And Absence

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The first biosynthetic studies of the azinomycins: acetate incorporation into azinomycin BElectronic supplementary information (ESI) available: experimental procedures for fermentation of S. sahachiroi and isolation of azinomycin B, NMR data from labeling experiments. See http://www.rsc.org/suppdata/cc/b4/b400093e/

Chemical Communications ◽

10.1039/b400093e ◽

2004 ◽

pp. 990 ◽

Cited By ~ 20

Author(s):

Christophe Corre ◽

Philip A. S. Lowden

Keyword(s):

Supplementary Information ◽

Acetate Incorporation ◽

Nmr Data ◽

Azinomycin B ◽

Biosynthetic Studies

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1,2-Hydroboration of Alkyn-1-yldichlorosilanes using Triethylborane

Zeitschrift für Naturforschung B ◽

10.1515/znb-2008-1105 ◽

2008 ◽

Vol 63 (11) ◽

pp. 1267-1275 ◽

Cited By ~ 7

Author(s):

Bernd Wrackmeyer ◽

Ezzat Khan ◽

Wolfgang Milius

Keyword(s):

Molecular Structure ◽

Single Crystal ◽

Hydrogen Transfer ◽

X Ray Diffraction ◽

X Ray ◽

Ethyl Group ◽

Nmr Data

Abstract Triethylborane, BEt3, can act as a 1,2-hydroborating reagent towards alkyn-1-ylsilanes, depending on the nature of the silane. A mechanism is proposed invoking hydrogen transfer from the β -carbon of one ethyl group, quite different from the 1,2-hydroboration mechanism using tri-n-propylborane, BnPr3. The structure of the products has been confirmed by comparison with that obtained using 9-borabicyclo[3.3.1]nonane, 9-BBN, as a well established 1,2-hydroborating reagent. All products have been characterized by a consistent set of NMR data (1H, 11B, 13C and 29Si NMR). The molecular structure of (Z)-1-dichlorosilyl-1-[9-(9-borabicyclo[3.3.1]nonyl)]-2-phenylethene has been determined by single crystal X-ray diffraction.

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Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligandsElectronic supplementary information (ESI) available: Table ESI1: Selection of kinetic parameters. Fig. ESI1: Eyring plots. See http://www.rsc.org/suppdata/dt/b4/b400661e/

Dalton Transactions ◽

10.1039/b400661e ◽

2004 ◽

pp. 1424 ◽

Cited By ~ 4

Author(s):

Vincenzo Passarelli ◽

Franco Benetollo ◽

Pierino Zanella

Keyword(s):

Molecular Structure ◽

Kinetic Parameters ◽

Structure Elucidation ◽

Supplementary Information ◽

Solution Dynamics ◽

Selection Of

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Synthese und Eigenschaften einiger Silylethinylsilane; Molekülstruktur von Tetrakis(trimethylsilylethinyl)silan / Synthesis and Properties of Some Silylethynylsilane; Molecular Structure of Tetrakis(trimethylsilylethynyl)silane

Zeitschrift für Naturforschung B ◽

10.1515/znb-1988-0109 ◽

1988 ◽

Vol 43 (1) ◽

pp. 49-52 ◽

Cited By ~ 20

Author(s):

Hubert Schmidbaur ◽

Jan Ebenhöch

Keyword(s):

Molecular Structure ◽

Crystal Structure ◽

Single Crystal ◽

Silicon Atom ◽

Grignard Reagent ◽

X Ray Diffraction ◽

Tetrahedral Geometry ◽

X Ray ◽

Nmr Data

Abstract Trimethylsilylethine (1) has been prepared from C2H2, sodium and Me3SiCl in anisole. The product can be converted into a Grignard reagent Me3SiC≡CMgCl using iPrMgCl. This reagent yields the compounds Me3SiC≡CSiH3, (Me3SiC≡C)2SiH2, (Me3SiC≡C)3SiH, and (Me3SiC≡C)4Si (2-5) when treated with equivalent amounts of H3SiBr, H2SiBr2, HSiCl3, or SiCl4. respectively. The new silanes have been characterized by NMR data. The crystal structure of (Me3SiC≡C)4Si has been determined by single crystal X-ray diffraction. It shows the expected tetrahedral geometry at he central silicon atom with four linear SiC≡CSi linkages.

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