Effect of Ru surface composition on the CO tolerance of Ru modified carbon supported Pt catalysts

2004 ◽  
Vol 6 (8) ◽  
pp. 1792 ◽  
Author(s):  
E. M. Crabb ◽  
M. K. Ravikumar ◽  
D. Thompsett ◽  
M. Hurford ◽  
A. Rose ◽  
...  
2016 ◽  
Vol 4 (20) ◽  
pp. 7674-7682 ◽  
Author(s):  
Yaqiang Duan ◽  
Ye Sun ◽  
Lei Wang ◽  
Ying Dai ◽  
Baibing Chen ◽  
...  

To improve the sluggish kinetics of the methanol oxidation reaction (MOR), one efficient way is to improve the properties of catalyst supports to enhance the activity and durability of Pt-based catalysts.


Catalysts ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 88
Author(s):  
Diana García-Pérez ◽  
Maria Consuelo Alvarez-Galvan ◽  
Jose M. Campos-Martin ◽  
Jose L. G. Fierro

Catalysts based on zirconia- and alumina-supported tungsten oxides (15 wt % W) with a small loading of platinum (0.3 wt % Pt) were selected to study the influence of the reduction temperature and the nature of the support on the hydroisomerization of n-dodecane. The reduction temperature has a major influence on metal dispersion, which impacts the catalytic activity. In addition, alumina and zirconia supports show different catalytic properties (mainly acid site strength and surface area), which play an important role in the conversion. The NH3-TPD profiles indicate that the acidity in alumina-based catalysts is clearly higher than that in their zirconia counterparts; this acidity can be attributed to a stronger interaction of the WOx species with alumina. The PtW/Al catalyst was found to exhibit the best catalytic performance for the hydroisomerization of n-dodecane based on its higher acidity, which was ascribed to its larger surface area relative to that of its zirconia counterparts. The selectivity for different hydrocarbons (C7–10, C11 and i-C12) was very similar for all the catalysts studied, with branched C12 hydrocarbons being the main products obtained (~80%). The temperature of 350 °C was clearly the best reduction temperature for all the catalysts studied in a trickled-bed-mode reactor.


Carbon ◽  
2002 ◽  
Vol 40 (13) ◽  
pp. 2375-2380 ◽  
Author(s):  
Yi Cheng Liu ◽  
Xin Ping Qiu ◽  
Yu Qing Huang ◽  
Wen Tao Zhu

2017 ◽  
Vol 281 ◽  
pp. 507-511 ◽  
Author(s):  
Sondomoyee K. Moromi ◽  
S.M.A. H. Siddiki ◽  
Kenichi Kon ◽  
Takashi Toyao ◽  
Ken-ichi Shimizu

2017 ◽  
Vol 101 ◽  
pp. 107-110 ◽  
Author(s):  
Lihua Yang ◽  
Xuewen Li ◽  
Yanyan Sun ◽  
Linhai Yue ◽  
Jie Fu ◽  
...  

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