scholarly journals A novel chiral porous metal–organic framework: asymmetric ring opening reaction of epoxide with amine in the chiral open space

2008 ◽  
pp. 820-822 ◽  
Author(s):  
Koichi Tanaka ◽  
Shinji Oda ◽  
Motoo Shiro
Keyword(s):  
Ring Opening ◽  
Open Space ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Ring Opening Reaction ◽  
Metal Organic ◽  
Asymmetric Ring Opening ◽  
Organic Framework ◽  
Asymmetric Ring Opening Reaction

The mechanism of an asymmetric ring-opening reaction of epoxide with amine catalyzed by a metal–organic framework: insights from combined quantum mechanics and molecular mechanics calculations

2017 ◽  
Vol 46 (11) ◽  
pp. 3470-3481 ◽  
Author(s):  
Kazuki Doitomi ◽  
Kai Xu ◽  
Hajime Hirao
Keyword(s):  
Quantum Mechanics ◽  
Molecular Mechanics ◽  
Ring Opening ◽  
Metal Organic Framework ◽  
Molecular Mechanics Calculations ◽  
Π Interactions ◽  
Ring Opening Reaction ◽  
Metal Organic ◽  
Asymmetric Ring Opening ◽  
Asymmetric Ring Opening Reaction

QM/MM computations suggest that the asymmetric ring-opening reaction of epoxide with amine is controlled by CH–π interactions between aniline and a naphthol moiety.

ChemInform Abstract: Enantioselective Ring-Opening Reaction of Epoxides with MeOH Catalyzed by Homochiral Metal-Organic Framework.

ChemInform ◽  
2012 ◽  
Vol 43 (41) ◽  
pp. no-no
Author(s):  
Koichi Tanaka ◽  
Ken-ichi Otani ◽  
Takanori Murase ◽  
Shyota Nishihote ◽  
Zofia Urbanczyk-Lipkowska
Keyword(s):  
Ring Opening ◽  
Metal Organic Framework ◽  
Ring Opening Reaction ◽  
Metal Organic ◽  
Organic Framework

Change in synthetic strategy for MOF fabrication: from 2D non-porous to 3D porous architecture and its sorption and emission property studies

2016 ◽  
Vol 40 (3) ◽  
pp. 1953-1956 ◽  
Author(s):  
Kapil Tomar ◽  
Anoop K. Gupta ◽  
Mayank Gupta
Keyword(s):  
Single Crystal ◽  
Open Space ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Emission Property ◽  
Single Crystal Xrd ◽  
Synthetic Strategy ◽  
Porous Architecture ◽  
Metal Organic ◽  
Organic Framework

A bipyrazole based novel six-connected porous metal–organic framework was synthesized and characterized by single crystal XRD. The compound has a large open space with 41% porosity in the crystal.

scholarly journals Asymmetric ring-opening reaction of meso-epoxides with aromatic amines using homochiral metal–organic frameworks as recyclable heterogeneous catalysts

RSC Advances ◽  
2018 ◽  
Vol 8 (49) ◽  
pp. 28139-28146 ◽  
Author(s):  
Koichi Tanaka ◽  
Maya Kinoshita ◽  
Jun Kayahara ◽  
Yutaro Uebayashi ◽  
Kazusada Nakaji ◽  
...  
Keyword(s):  
Aromatic Amines ◽  
Ring Opening ◽  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Amino Alcohols ◽  
Ring Opening Reaction ◽  
Ring Opening Reactions ◽  
Metal Organic ◽  
Asymmetric Ring Opening

Asymmetric ring-opening reactions of meso-epoxides by aromatic amines were achieved by using some chiral metal–organic frameworks. The corresponding β-amino alcohols were obtained with good yields and enantioselectivities (up to 97% ee).

Improved catalytic performance of porous metal–organic frameworks for the ring opening of styrene oxide

CrystEngComm ◽  
2017 ◽  
Vol 19 (29) ◽  
pp. 4219-4226 ◽  
Author(s):  
Diana Julião ◽  
André D. S. Barbosa ◽  
Andreia F. Peixoto ◽  
Cristina Freire ◽  
Baltazar de Castro ◽  
...  
Keyword(s):  
Ring Opening ◽  
Heterogeneous Catalysts ◽  
Metal Organic Framework ◽  
Styrene Oxide ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Catalytic Performance ◽  
Metal Organic ◽  
Organic Framework

An emerging strategy to improve the performance of porous metal–organic framework (MOF) materials as heterogeneous catalysts is reported.

Enantioselective Ring-Opening Reaction of Epoxides with MeOH Catalyzed by Homochiral Metal–Organic Framework

2012 ◽  
Vol 85 (6) ◽  
pp. 709-714 ◽  
Author(s):  
Koichi Tanaka ◽  
Ken-ichi Otani ◽  
Takanori Murase ◽  
Shyota Nishihote ◽  
Zofia Urbanczyk-Lipkowska
Keyword(s):  
Ring Opening ◽  
Metal Organic Framework ◽  
Ring Opening Reaction ◽  
Metal Organic ◽  
Organic Framework

Multifunctionality in an Ion-Exchanged Porous Metal–Organic Framework

2021 ◽  
Vol 143 (3) ◽  
pp. 1365-1376
Author(s):  
Sérgio M. F. Vilela ◽  
Jorge A. R. Navarro ◽  
Paula Barbosa ◽  
Ricardo F. Mendes ◽  
Germán Pérez-Sánchez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Organic Framework
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