The electrically conductive function of high-molecular weight poly(ethylene oxide) in polymer gel electrolytes used for dye-sensitized solar cells

2009 ◽  
Vol 11 (21) ◽  
pp. 4230 ◽  
Author(s):  
Yantao Shi ◽  
Chun Zhan ◽  
Liduo Wang ◽  
Beibei Ma ◽  
Rui Gao ◽  
...  
Ionics ◽  
2019 ◽  
Vol 26 (1) ◽  
pp. 493-502 ◽  
Author(s):  
Liaw Poh Yee ◽  
N. K. Farhana ◽  
Fatin Saiha Omar ◽  
V. Sundararajan ◽  
Shahid Bashir ◽  
...  

Polymers ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3035
Author(s):  
Jan Lukas Storck ◽  
Marius Dotter ◽  
Sonia Adabra ◽  
Michelle Surjawidjaja ◽  
Bennet Brockhagen ◽  
...  

To overcome the long-term stability problems of dye-sensitized solar cells (DSSC) due to solvent evaporation and leakage, gelling the electrolyte with polymers is an appropriate option. Especially for future applications of textile-based DSSCs, which require cost-effective and environmentally friendly materials, such an improvement of the electrolyte is necessary. Therefore, the temporal progressions of efficiencies and fill factors of non-toxic glass-based DSSCs resulting from different gel electrolytes with poly(ethylene oxide) (PEO) are investigated over 52 days comparatively. Dimethyl sulfoxide (DMSO) proved to be a suitable non-toxic solvent for the proposed gel electrolyte without ionic liquids. A PEO concentration of 17.4 wt% resulted in an optimal compromise with a relatively high efficiency over the entire period. Lower concentrations resulted in higher efficiencies during the first days but in a poorer long-term stability, whereas a higher PEO concentration resulted in an overall lower efficiency. Solvent remaining in the gel electrolyte during application was found advantageous compared to previous solvent evaporation. In contrast to a commercial liquid electrolyte, the long-term stability regarding the efficiency was improved successfully with a similar fill factor and thus equal quality.


2021 ◽  
Vol 35 (5) ◽  
pp. 4273-4282
Author(s):  
Dineshkumar Raja ◽  
Balamurugan Selvaraj ◽  
Ganesan Shanmugam ◽  
Arthanareeswari Maruthapillai ◽  
Devikala Sundaramurthy

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