Ionic liquid induced spontaneous symmetry breaking: emergence of predominant handedness during the self-assembly of tetrakis(4-sulfonatophenyl)porphyrin (TPPS) with achiral ionic liquid

2011 ◽  
Vol 13 (38) ◽  
pp. 17205 ◽  
Author(s):  
Li Zhang ◽  
Ye Tian ◽  
Minghua Liu
Keyword(s):  
Ionic Liquid ◽  
Symmetry Breaking ◽  
Spontaneous Symmetry Breaking ◽  
Self Assembly ◽  
The Self

Symmetry Breaking in the Self-Assembly of Partially Fluorinated Benzene-1,3,5-tricarboxamides

2012 ◽  
Vol 51 (45) ◽  
pp. 11297-11301 ◽  
Author(s):  
Patrick J. M. Stals ◽  
Peter A. Korevaar ◽  
Martijn A. J. Gillissen ◽  
Tom F. A. de Greef ◽  
Carel F. C. Fitié ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Self Assembly ◽  
The Self

Spontaneous Symmetry Breaking during Self-Assembly of a Double Stranded Biphenolate-Based Ti(IV)-Helicate

2010 ◽  
Vol 49 (14) ◽  
pp. 6369-6371 ◽  
Author(s):  
Carine Diebold ◽  
Pierre Mobian ◽  
Clarisse Huguenard ◽  
Lionel Allouche ◽  
Marc Henry
Keyword(s):  
Symmetry Breaking ◽  
Spontaneous Symmetry Breaking ◽  
Self Assembly

Chiral symmetry breaking during the self-assembly of monolayers from achiral purine molecules

1996 ◽  
Vol 43 (5) ◽  
pp. 419-424 ◽  
Author(s):  
Stephen J. Sowerby ◽  
Wolfgang M. Heckl ◽  
George B. Petersen
Keyword(s):  
Symmetry Breaking ◽  
Chiral Symmetry ◽  
Self Assembly ◽  
Chiral Symmetry Breaking ◽  
The Self

Self-assembly of subwavelength nanostructures with symmetry breaking in solution

Nanoscale ◽  
2016 ◽  
Vol 8 (5) ◽  
pp. 2951-2959 ◽  
Author(s):  
Xiang-Dong Tian ◽  
Shu Chen ◽  
Yue-Jiao Zhang ◽  
Jin-Chao Dong ◽  
Rajapandiyan Panneerselvam ◽  
...  
Keyword(s):  
Symmetry Breaking ◽  
Self Assembly ◽  
Building Blocks ◽  
The Self

The self-assembly of asymmetric nanostructures with adjustable building blocks (Au nanospheres: 90–250 nm and Ag nanocubes: 100–160 nm) and meanwhile with interparticle gaps controlled by silica shells (from 1 nm to beyond 10 nm).

scholarly journals Symmetry Breaking in Self-Assembled Nanoassemblies

Symmetry ◽  
2019 ◽  
Vol 11 (8) ◽  
pp. 950 ◽  
Author(s):  
Yutao Sang ◽  
Minghua Liu
Keyword(s):  
Symmetry Breaking ◽  
Self Assembly ◽  
Mirror Symmetry ◽  
Covalent Bond ◽  
The Self ◽  
Control Methods ◽  
Supramolecular Chirality ◽  
Dispersed System ◽  
Chiral Materials ◽  
And Control

The origin of biological homochirality, e.g., life selects the L-amino acids and D-sugar as molecular component, still remains a big mystery. It is suggested that mirror symmetry breaking plays an important role. Recent researches show that symmetry breaking can also occur at a supramolecular level, where the non-covalent bond was crucial. In these systems, equal or unequal amount of the enantiomeric nanoassemblies could be formed from achiral molecules. In this paper, we presented a brief overview regarding the symmetry breaking from dispersed system to gels, solids, and at interfaces. Then we discuss the rational manipulation of supramolecular chirality on how to induce and control the homochirality in the self-assembly system. Those physical control methods, such as Viedma ripening, hydrodynamic macro- and micro-vortex, superchiral light, and the combination of these technologies, are specifically discussed. It is hoped that the symmetry breaking at a supramolecular level could provide useful insights into the understanding of natural homochirality and further designing as well as controlling of functional chiral materials.

The self-assembly of an imidazolium surfactant in an aprotic ionic liquid. 1. Comparison in aprotic and protic ionic liquids

Soft Matter ◽  
2020 ◽  
Vol 16 (31) ◽  
pp. 7246-7249
Author(s):  
Qintang Li ◽  
Kun Tong ◽  
Meng Sun ◽  
Meihuan Yao ◽  
Wenchang Zhuang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Self Assembly ◽  
Cohesive Energy ◽  
The Self ◽  
Protic Ionic Liquids

Dramatic aggregation behaviours could happen in the aprotic and protic ionic liquids in spite of their similar cohesive energy.

The self-assembly of ionic liquids surfactants in ethanolammonium nitrate ionic liquid

2018 ◽  
Vol 254 ◽  
pp. 130-136 ◽  
Author(s):  
Yuanchao Pei ◽  
Lihui Hao ◽  
Jie Ru ◽  
Yuling Zhao ◽  
Huiyong Wang ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Self Assembly ◽  
The Self
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