Synthesis of thiophene-containing conjugated polymers from 2,5-thiophenebis(boronic ester)s by Suzuki polycondensation

2013 ◽  
Vol 4 (4) ◽  
pp. 895 ◽  
Author(s):  
Meifang Liu ◽  
Yulan Chen ◽  
Chi Zhang ◽  
Cuihong Li ◽  
Weiwei Li ◽  
...  

2016 ◽  
Vol 49 (13) ◽  
pp. 4757-4762 ◽  
Author(s):  
Yunyan Qiu ◽  
Joshua C. Worch ◽  
Andria Fortney ◽  
Chakicherla Gayathri ◽  
Roberto R. Gil ◽  
...  


2020 ◽  
Vol 9 (8) ◽  
pp. 1167-1171
Author(s):  
Alessandro Sanzone ◽  
Adiel Calascibetta ◽  
Mauro Monti ◽  
Sara Mattiello ◽  
Mauro Sassi ◽  
...  




Synlett ◽  
2018 ◽  
Vol 29 (19) ◽  
pp. 2515-2522 ◽  
Author(s):  
Mindy Levine ◽  
Daniel Jones ◽  
Ryan Vallee

Eight new fluorescent conjugated polymers were synthesized by the Suzuki polycondensation reaction of 9,9-dioctylfluorene-2,7-diboronic acid bis(1,3-propanediol) ester and a conjugated dihalogenated monomer. The photophysical properties of these polymers were investigated as well-dissolved solutions in chloroform and as nanoparticle suspensions in water. Several of the polymers had large Stokes shifts (greater than 100 nm) and others demonstrated unique changes in the fluorescence properties in aggregated verse nonaggregated forms. Preliminary applications of these polymers in the detection of common bisphenols are also reported.



2016 ◽  
Vol 19 (3) ◽  
pp. 99-107
Author(s):  
Tam Huu Nguyen ◽  
Thu Anh Nguyen ◽  
Viet Quoc Nguyen ◽  
Trung Thanh Nguyen ◽  
Ha Tran Nguyen

A new monomer of N-benzoyl dithieno[2,3-b:2’,3’-d]pyrrole (BDP), has been successfully prepared via copper-catalyzed amidation. Then, this monomer was brominated to form 2,6-dibromo-n-benzoyl dithieno[2,3-b:2’,3’-d]pyrrole (DiBDP) monomer. The structures of monomers were confirmed via the nuclear magnetic resonance (1HNMR) and Fourier transform infrared (FT-IR). BDP and DiBDP monomers will be used as monomers for Suzuki polycondensation reaction to synthesize the donor-acceptor (D-A) conjugated polymers.



2014 ◽  
Vol 52 (11) ◽  
pp. 1525-1528 ◽  
Author(s):  
Il Hak Bae ◽  
In-Hwan Lee ◽  
Sangmoon Byun ◽  
Jooyoung Chung ◽  
B. Moon Kim ◽  
...  


Author(s):  
J. Fink

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.



1992 ◽  
Vol 1 (Part_2) ◽  
pp. 189-199
Author(s):  
K. Lüders ◽  
S. Blumstengel


2003 ◽  
Vol 771 ◽  
Author(s):  
Adosh Mehta ◽  
Pradeep Kumar ◽  
Jie Zheng ◽  
Robert M. Dickson ◽  
Bobby Sumpter ◽  
...  

AbstractDipole emission pattern imaging experiments on single chains of common conjugated polymers (solubilized poly phenylene vinylenes) isolated by ink-jet printing techniques have revealed surprising uniformity in transition moment orientation perpendicular to the support substrate. In addition to uniform orientation, these species show a number of striking differences in photochemical stability, polarization anisotropy,[1] and spectral signatures[2] with respect to similar (well-studied) molecules dispersed in dilute thin-films. Combined with molecular mechanics simulation, these results point to a structural picture of a folded macromolecule as a highly ordered cylindrical nanostructure whose long-axis (approximately collinear with the conjugation axis) is oriented, by an electrostatic interaction, perpendicular to the coverglass substrate. These results suggest a number of important applications in nanoscale photonics and molecular-scale optoelectronics.



2000 ◽  
Vol 154 (1) ◽  
pp. 245-252 ◽  
Author(s):  
Zhonghua Peng ◽  
Yongchun Pan ◽  
Bubin Xu ◽  
Jianheng Zhang


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