Crystallographic determination of solid-state structural transformations in a dynamic metal–organic framework

2014 ◽  
Vol 50 (20) ◽  
pp. 2615-2617 ◽  
Author(s):  
Gui-Lian Li ◽  
Guang-Zhen Liu ◽  
Lu-Fang Ma ◽  
Ling-Yun Xin ◽  
Xiao-Ling Li ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Organic Framework ◽  
Structural Transformations ◽  
Hierarchical Pores ◽  
Metal Organic ◽  
Organic Framework

A dynamic MOF with hierarchical pores displays various SC–SC structural transformations including reversible desolvation–resolvation, I2 uptake–release, and photochemical [2+2] cycloaddition.

Rapid determination of the optical and redox properties of a metal–organic framework via in situ solid state spectroelectrochemistry

2012 ◽  
Vol 48 (33) ◽  
pp. 3945 ◽  
Author(s):  
Pavel M. Usov ◽  
Cesimiro Fabian ◽  
Deanna M. D'Alessandro
Keyword(s):  
Solid State ◽  
Rapid Determination ◽  
Metal Organic Framework ◽  
Redox Properties ◽  
Metal Organic ◽  
Organic Framework

scholarly journals HKUST-1@IL-Li Solid-state Electrolyte with 3D Ionic Channels and Enhanced Fast Li+ Transport for Lithium Metal Batteries at High Temperature

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 736
Author(s):  
Man Li ◽  
Tao Chen ◽  
Seunghyun Song ◽  
Yang Li ◽  
Joonho Bae
Keyword(s):  
High Temperature ◽  
Solid State ◽  
Solid Electrolyte ◽  
Metal Organic Framework ◽  
Ionic Channels ◽  
Transference Numbers ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Metal Organic ◽  
Organic Framework

The challenge of safety problems in lithium batteries caused by conventional electrolytes at high temperatures is addressed in this study. A novel solid electrolyte (HKUST-1@IL-Li) was fabricated by immobilizing ionic liquid ([EMIM][TFSI]) in the nanopores of a HKUST-1 metal–organic framework. 3D angstrom-level ionic channels of the metal–organic framework (MOF) host were used to restrict electrolyte anions and acted as “highways” for fast Li+ transport. In addition, lower interfacial resistance between HKUST-1@IL-Li and electrodes was achieved by a wetted contact through open tunnels at the atomic scale. Excellent high thermal stability up to 300 °C and electrochemical properties are observed, including ionic conductivities and Li+ transference numbers of 0.68 × 10-4 S·cm-1 and 0.46, respectively, at 25 °C, and 6.85 × 10-4 S·cm-1 and 0.68, respectively, at 100 °C. A stable Li metal plating/stripping process was observed at 100 °C, suggesting an effectively suppressed growth of Li dendrites. The as-fabricated LiFePO4/HKUST-1@IL-Li/Li solid-state battery exhibits remarkable performance at high temperature with an initial discharge capacity of 144 mAh g-1 at 0.5 C and a high capacity retention of 92% after 100 cycles. Thus, the solid electrolyte in this study demonstrates promising applicability in lithium metal batteries with high performance under extreme thermal environmental conditions.

Simultaneous adsorption and determination of bisphenol compounds in water medium with a Zr(IV)-based metal-organic framework

2021 ◽  
Vol 188 (3) ◽  
Author(s):  
Liming Yu ◽  
Jie Cheng ◽  
Haosen Yang ◽  
Jie Lv ◽  
Peilong Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Water Medium ◽  
Simultaneous Adsorption ◽  
Metal Organic ◽  
Organic Framework

Magnetic porous carbon derived from Zn/Co metal–organic framework as an adsorbent for extraction and determination of carbamates

2020 ◽  
Vol 187 (9) ◽  
Author(s):  
Meng Wang ◽  
Jingjing Wang ◽  
Kangkang Wang ◽  
Tingxiang Chen ◽  
Jide Wang
Keyword(s):  
Porous Carbon ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

One-step solid-state thermolysis of a metal–organic framework: a simple and facile route to large-scale of multiwalled carbon nanotubes

2008 ◽  
pp. 1581 ◽  
Author(s):  
Linyun Chen ◽  
Junfeng Bai ◽  
Chunzhao Wang ◽  
Yi Pan ◽  
Manfred Scheer ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Solid State ◽  
Multiwalled Carbon Nanotubes ◽  
Large Scale ◽  
Metal Organic Framework ◽  
Multiwalled Carbon ◽  
Metal Organic ◽  
One Step ◽  
Facile Route ◽  
Organic Framework

scholarly journals Mechanical energy storage performance of an aluminum fumarate metal–organic framework

2016 ◽  
Vol 7 (1) ◽  
pp. 446-450 ◽  
Author(s):  
Pascal G. Yot ◽  
Louis Vanduyfhuys ◽  
Elsa Alvarez ◽  
Julien Rodriguez ◽  
Jean-Paul Itié ◽  
...  
Keyword(s):  
Energy Storage ◽  
Mechanical Energy ◽  
Metal Organic Framework ◽  
Storage Performance ◽  
Metal Organic ◽  
Organic Framework

Determination of the mechanical energy storage performance of the aluminum fumarate metal–organic framework A520.

Li-based MOF-derived multifunctional PEO polymer solid-state electrolyte for lithium energy storage

2022 ◽  
Author(s):  
Xiang Han ◽  
Tiantian Wu ◽  
Lanhui Gu ◽  
Dian Tian
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
Isophthalic Acid ◽  
Solid State Electrolyte ◽  
Metal Organic ◽  
Solvothermal Conditions ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework containing Li-oxygen clusters, namely {[Li2(IPA)]·DMF}n (1) (H2IPA = isophthalic acid), has been constructed under solvothermal conditions. The Li-based MOF can be applied to lithium energy...

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