Self-assembly of [Cu3I2]- or [CuI]n-based (n = 2, 4, and ∞) coordination polymers from unsymmetrical bis(pyridyl) and in situ ligands: syntheses, structures, and properties

CrystEngComm ◽  
2014 ◽  
Vol 16 (3) ◽  
pp. 359-368 ◽  
Author(s):  
Zhu-Yan Zhang ◽  
Zhao-Peng Deng ◽  
Xian-Fa Zhang ◽  
Li-Hua Huo ◽  
Hui Zhao ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Structures And Properties

A series of helical coordination polymers based on two racemic bis(pyridylmethylene) propane-1,2-diamine ligands: relationship of conformations, structures and properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7249-7259 ◽  
Author(s):  
Li-Na Zhu ◽  
Zhao-Peng Deng ◽  
Li-Hua Huo ◽  
Shan Gao
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Metal Salts ◽  
Structures And Properties ◽  
Relationship Of ◽  
Diamine Ligands

The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.

Two novel 3D lanthanide supramolecular coordination polymers constructed from paddle wheel SBUs and hydrogen bonding: synthesis, structures and properties

RSC Advances ◽  
2014 ◽  
Vol 4 (59) ◽  
pp. 30963-30967 ◽  
Author(s):  
Qipeng Li ◽  
Shaowu Du
Keyword(s):  
Hydrogen Bonding ◽  
Coordination Polymers ◽  
Luminescent Property ◽  
Temperature Dependent ◽  
Paddle Wheel ◽  
Structures And Properties ◽  
Supramolecular Coordination

Two novel 3D lanthanide supramolecular coordination polymers with lanthanide paddle wheel SBUs were synthesized through in situ generation of formate anions. Their structure and temperature dependent luminescent property are investigated.

A simultaneous disulfide bond cleavage, N,S-bialkylation/N-protonation and self-assembly reaction: syntheses, structures and properties of two hybrid iodoargentates with thiazolyl-based heterocycles

2016 ◽  
Vol 45 (47) ◽  
pp. 19062-19071 ◽  
Author(s):  
Guang-Ning Liu ◽  
Ke Li ◽  
Qing-Shun Fan ◽  
Hui Sun ◽  
Xin-Yu Li ◽  
...  
Keyword(s):  
Disulfide Bond ◽  
Self Assembly ◽  
Bond Cleavage ◽  
Structures And Properties ◽  
Two Hybrid

Unprecedented multiple in situ reactions were found during preparation of hybrid iodoargentates.

Zinc and cadmium metal-directed coordination polymers: in situ flexible tetrazole ligand synthesis, structures, and properties

CrystEngComm ◽  
2015 ◽  
Vol 17 (30) ◽  
pp. 5814-5831 ◽  
Author(s):  
Ruo Ting Dong ◽  
Zhao Ying Ma ◽  
Li Xin Chen ◽  
Lan Fen Huang ◽  
Qian Hong Li ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Conditions ◽  
Structures And Properties ◽  
Cadmium Metal ◽  
Ligand Synthesis ◽  
Coordination Frameworks

Seven zinc and cadmium coordination frameworks were obtained through in situ tetrazole synthesis. By varying the hydrothermal conditions the unprecedented generation of tetrazole ligands were achieved.

Syntheses, Structures, and Properties of Honeycomb and Square Grid Coordination Polymers with In Situ Formed 5-(2′-Pyrimidyl)tetrazolate

2010 ◽  
Vol 10 (7) ◽  
pp. 2908-2915 ◽  
Author(s):  
Jian-Yong Zhang ◽  
Ai-Ling Cheng ◽  
Qian Sun ◽  
Qi Yue ◽  
En-Qing Gao
Keyword(s):  
Coordination Polymers ◽  
Square Grid ◽  
Structures And Properties

Two- and three-dimensional lanthanide-based coordination polymers assembled by the synergistic effect of various lanthanide radii and flexibility of a new binicotinate-containing ligand: in situ synthesis, structures, and properties

RSC Advances ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 2239-2248 ◽  
Author(s):  
Baoming Ji ◽  
Dongsheng Deng ◽  
Junying Ma ◽  
Chaowei Sun ◽  
Bin Zhao
Keyword(s):  
Synergistic Effect ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
In Situ Synthesis ◽  
Coordination Modes ◽  
Design And Synthesis ◽  
Structural Types ◽  
Lanthanide Contraction ◽  
Structures And Properties

The design and synthesis of ten novel coordination polymers was investigated. They have three structural types from 3D to 2D due to the synergistic effect of lanthanide contraction with diverse coordination modes and conformations of the ligand.

scholarly journals Self-Assembly of 1D Double-Chain and 3D Diamondoid Networks of Lanthanide Coordination Polymers through In Situ-Generated Ligands: High-Pressure CO2 Adsorption and Photoluminescence Properties

Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4428
Author(s):  
Chatphorn Theppitak ◽  
Suwadee Jiajaroen ◽  
Nucharee Chongboriboon ◽  
Songwuit Chanthee ◽  
Filip Kielar ◽  
...  
Keyword(s):  
High Pressure ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Chain Structure ◽  
Double Chain ◽  
Hydrothermal Conditions ◽  
3D Network ◽  
High Pressure Co2 ◽  
Secondary Building Units

Two new lanthanide-based coordination polymers, [Sm2(bzz)(ben)6(H2O)3]·0.5H2O (1) and [Eu(bbz)(ben)3] (2), were synthesized and characterized. The described products were formed from in situ-generated benzoate (ben) and N’-benzoylbenzohydrazide (bbz) ligands, which were the products of transformation of originally added benzhydrazide (bzz) under hydrothermal conditions. Compound 1 exhibits a one-dimensional (1D) double-chain structure built up from the connection of the central Sm3+ ions with a mixture of bzz and ben ligands. On the other hand, 2 features a 3D network with a 4-connected (66) dia topology constructed from dinuclear [Eu2(ben)6] secondary building units and bbz linkers. High-pressure CO2 sorption studies of activated 1 show that maximum uptake increases to exceptionally high values of 376.7 cm3 g−1 (42.5 wt%) under a pressure of 50 bar at 298 K with good recyclability. Meanwhile, 2 shows a typical red emission in the solid state at room temperature with the decay lifetime of 1.2 ms.

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