scholarly journals Highly-efficient charge separation and polaron delocalization in polymer–fullerene bulk-heterojunctions: a comparative multi-frequency EPR and DFT study

2013 ◽  
Vol 15 (24) ◽  
pp. 9562 ◽  
Author(s):  
Jens Niklas ◽  
Kristy L. Mardis ◽  
Brian P. Banks ◽  
Gregory M. Grooms ◽  
Andreas Sperlich ◽  
...  
Crystals ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 717
Author(s):  
Hassan Algadi ◽  
Ahmad Umar ◽  
Hasan Albargi ◽  
Turki Alsuwian ◽  
Sotirios Baskoutas

A low-cost and simple drop-casting method was used to fabricate a carbon nanodot (C-dot)/all-inorganic perovskite (CsPbBr3) nanosheet bilayer heterojunction photodetector on a SiO2/Si substrate. The C-dot/perovskite bilayer heterojunction photodetector shows a high performance with a responsivity (R) of 1.09 A/W, almost five times higher than that of a CsPbBr3-based photodetector (0.21 A/W). In addition, the hybrid photodetector exhibits a fast response speed of 1.318/1.342 µs and a highly stable photocurrent of 6.97 µA at 10 V bias voltage. These figures of merits are comparable with, or much better than, most reported perovskite heterojunction photodetectors. UV–Vis absorption and photoluminescent spectra measurements reveal that the C-dot/perovskite bilayer heterojunction has a band gap similar to the pure perovskite layer, confirming that the absorption and emission in the bilayer heterojunction is dominated by the top layer of the perovskite. Moreover, the emission intensity of the C-dot/perovskite bilayer heterojunction is less than that of the pure perovskite layer, indicating that a significant number of charges were extracted by the C-dot layer. The studied band alignment of the C-dots and perovskites in the dark and under emission reveals that the photodetector has a highly efficient charge separation mechanism at the C-dot/perovskite interface, where the recombination rate between photogenerated electrons and holes is significantly reduced. This highly efficient charge separation mechanism is the main reason behind the enhanced performance of the C-dot/perovskite bilayer heterojunction photodetector.


2019 ◽  
Vol 174 ◽  
pp. 237-245 ◽  
Author(s):  
M. Hannula ◽  
H. Ali-Löytty ◽  
K. Lahtonen ◽  
J. Saari ◽  
A. Tukiainen ◽  
...  

2020 ◽  
Vol 522 ◽  
pp. 146356 ◽  
Author(s):  
Junlan Guo ◽  
Yinghua Liang ◽  
Li Liu ◽  
Jinshan Hu ◽  
Huan Wang ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 15077-15083 ◽  
Author(s):  
Yuhua Ma ◽  
Jiajia Wang ◽  
Shimei Xu ◽  
Zhendong Zheng ◽  
Juan Du ◽  
...  

As a film photocatalyst, a Ag2O/sodium alginate supramolecular hydrogel exhibited excellent photocatalytic degradability, great adsorptivity, highly efficient charge separation and reusability.


Nano Letters ◽  
2012 ◽  
Vol 12 (4) ◽  
pp. 1965-1971 ◽  
Author(s):  
A. D. Mohite ◽  
D. E. Perea ◽  
S. Singh ◽  
S. A. Dayeh ◽  
I. H. Campbell ◽  
...  

2019 ◽  
Vol 44 (5) ◽  
pp. 2797-2810 ◽  
Author(s):  
Yinghua Liang ◽  
Rong Shang ◽  
Jinrong Lu ◽  
Weijia An ◽  
Jinshan Hu ◽  
...  

2022 ◽  
pp. 120787
Author(s):  
Shengjun Liu ◽  
Dianjun Chi ◽  
Qichao Zou ◽  
Yan Ma ◽  
Rong Chen ◽  
...  

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