Efficient hydridoirida-β-diketone-catalyzed hydrolysis of ammonia- or amine-boranes for hydrogen generation in air

2013 ◽  
Vol 42 (32) ◽  
pp. 11652 ◽  
Author(s):  
María A. Garralda ◽  
Claudio Mendicute-Fierro ◽  
Antonio Rodríguez-Diéguez ◽  
José M. Seco ◽  
Carlos Ubide ◽  
...  
Keyword(s):  
Hydrogen Generation ◽  
Amine Boranes ◽  
Hydrolysis Of

Ruthenium supported on MIL-101 as an efficient catalyst for hydrogen generation from hydrolysis of amine boranes

2014 ◽  
Vol 38 (9) ◽  
pp. 4032 ◽  
Author(s):  
Nan Cao ◽  
Teng Liu ◽  
Jun Su ◽  
Xiaojun Wu ◽  
Wei Luo ◽  
...  
Keyword(s):  
Hydrogen Generation ◽  
Efficient Catalyst ◽  
Amine Boranes ◽  
Hydrolysis Of

scholarly journals Ru Nanoparticles Supported on MIL-101 by Double Solvents Method as High-Performance Catalysts for Catalytic Hydrolysis of Ammonia Borane

2015 ◽  
Vol 2015 ◽  
pp. 1-5 ◽  
Author(s):  
Tong Liu ◽  
Qingtao Wang ◽  
Bingzheng Yan ◽  
Mei Zhao ◽  
Wenbo Li ◽  
...  
Keyword(s):  
High Performance ◽  
Hydrogen Generation ◽  
Catalytic Hydrolysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ru Nanoparticles ◽  
Amine Boranes ◽  
Adsorption Desorption ◽  
Hydrolysis Of ◽  
Catalytic Test

Highly dispersed crystalline Ru nanoparticles (NPs) were successfully immobilized inside the pores of MIL-101 by a double solvents method (DSM). HRTEM clearly demonstrated the uniform distribution of the ultrafine Ru NPs throughout the interior cavities of MIL-101. The synthesized Ru@MIL-101 catalyst was also characterized by X-ray diffraction (XRD), N2adsorption desorption, and ICP-AES. The catalytic test indicated that the Ru NPs supported MIL-101 material exhibited exceedingly high activity and excellent durability for hydrogen generation from the catalytic hydrolysis of amine boranes.

ISOBAM-stabilized Ni2+ colloidal catalysts: high catalytic activities for hydrogen generation from hydrolysis of KBH4

2020 ◽  
Vol 31 (13) ◽  
pp. 134003 ◽  
Author(s):  
Yuantao Pei ◽  
Liqiong Wang ◽  
Liang Huang ◽  
Yuetong Hu ◽  
Quanli Jia ◽  
...  
Keyword(s):  
Hydrogen Generation ◽  
Catalytic Activities ◽  
Hydrolysis Of

Hydrogen Generation by Hydrolysis of the Ball Milled Al-C-KCl Composite Powder in Distilled Water

2012 ◽  
Vol 519 ◽  
pp. 87-91 ◽  
Author(s):  
Xia Ni Huang ◽  
Zhang Han Wu ◽  
Ke Cao ◽  
Wen Zeng ◽  
Chun Ju Lv ◽  
...  
Keyword(s):  
Particle Size ◽  
Reaction Temperature ◽  
Fine Particle ◽  
Composite Powder ◽  
Hydrogen Generation ◽  
Aluminum Particle ◽  
Generation Rate ◽  
Composite Powders ◽  
Fine Particle Size ◽  
Hydrolysis Of

In the present investigation, the Al-C-KCl composite powders were prepared by a ball milling processing in an attempt to improve the hydrogen evolution capacity of aluminum in water. The results showed that the hydrogen generation reaction is affected by KCl amount, preparation processing, initial aluminum particle size and reaction temperature. Increasing KCl amount led to an increased hydrogen generation volume. The use of aluminum powder with a fine particle size could promote the aluminum hydrolysis reaction and get an increased hydrogen generation rate. The reaction temperature played an important role in hydrogen generation rate and the maximum hydrogen generation rate of 44.8 cm3 min-1g-1of Al was obtained at 75oC. The XRD results identified that the hydrolysis byproducts are bayerite (Al(OH)3) and boehmite (AlOOH).

PtxNi1−x nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane

2009 ◽  
Vol 34 (21) ◽  
pp. 8785-8791 ◽  
Author(s):  
Xiaojing Yang ◽  
Fangyi Cheng ◽  
Jing Liang ◽  
Zhanliang Tao ◽  
Jun Chen
Keyword(s):  
Hydrogen Generation ◽  
Ammonia Borane ◽  
Hydrolysis Of

Hydrogen generation from hydrolysis of sodium borohydride using Ni–Ru nanocomposite as catalysts

2009 ◽  
Vol 34 (5) ◽  
pp. 2153-2163 ◽  
Author(s):  
Cheng-Hong Liu ◽  
Bing-Hung Chen ◽  
Chan-Li Hsueh ◽  
Jie-Ren Ku ◽  
Ming-Shan Jeng ◽  
...  
Keyword(s):  
Sodium Borohydride ◽  
Hydrogen Generation ◽  
Hydrolysis Of
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