Organic nanospheres with an internal bicontinuous structure and their responsive phase inversion

2014 ◽  
Vol 50 (62) ◽  
pp. 8480-8483 ◽  
Author(s):  
Zhenhua Ju ◽  
Junpo He
Keyword(s):  
Self Assembly ◽  
Phase Inversion ◽  
Selective Solvents ◽  
Bicontinuous Structure

Responsive nanospheres with an internal bicontinuous structure and shape changing ability through phase inversion were obtained through hierarchical self-assembly of a dendritic block terpolymer in selective solvents.

Self-assembly of amphiphilic di and triblock copolymers of styrene and quaternized 5-(N,N-diethylamino) isoprene in selective solvents

Polymer ◽  
2003 ◽  
Vol 44 (7) ◽  
pp. 2117-2128 ◽  
Author(s):  
Izabel C Riegel ◽  
Dimitrios Samios ◽  
Cesar L Petzhold ◽  
Adi Eisenberg
Keyword(s):  
Self Assembly ◽  
Triblock Copolymers ◽  
Selective Solvents

Orientation- and cosolvent-induced self-assembly of amphiphilic homopolymers in selective solvents

Polymer ◽  
2021 ◽  
Vol 232 ◽  
pp. 124160
Author(s):  
Aleksandr I. Buglakov ◽  
Daniil E. Larin ◽  
Valentina V. Vasilevskaya
Keyword(s):  
Self Assembly ◽  
Selective Solvents ◽  
Amphiphilic Homopolymers

Self-Assembly of Amphiphilic Plasmonic Micelle-Like Nanoparticles in Selective Solvents

2013 ◽  
Vol 135 (21) ◽  
pp. 7974-7984 ◽  
Author(s):  
Jie He ◽  
Xinglu Huang ◽  
Yan-Chun Li ◽  
Yijing Liu ◽  
Taarika Babu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Selective Solvents

Self-assembly of linear diblock copolymers in selective solvents: from single micelles to particles with tri-continuous inner structures

Soft Matter ◽  
2020 ◽  
Vol 16 (26) ◽  
pp. 6056-6062 ◽  
Author(s):  
Xianggui Ye ◽  
Bamin Khomami
Keyword(s):  
Diblock Copolymer ◽  
Self Assembly ◽  
Large Scale ◽  
Diblock Copolymers ◽  
Dissipative Particle Dynamics ◽  
Particle Dynamics ◽  
The Self ◽  
Selective Solvent ◽  
Selective Solvents

Large-scale dissipative particle dynamics (DPD) simulations have been performed to investigate the self-assembly of over 20 000 linear diblock copolymer chains in a selective solvent.

Complex Micelles from Self-Assembly of ABA Triblock Copolymers in B-Selective Solvents

Langmuir ◽  
2010 ◽  
Vol 26 (6) ◽  
pp. 4226-4232 ◽  
Author(s):  
Weixin Kong ◽  
Baohui Li ◽  
Qinghua Jin ◽  
Datong Ding ◽  
An-Chang Shi
Keyword(s):  
Self Assembly ◽  
Triblock Copolymers ◽  
Selective Solvents ◽  
Complex Micelles

Self-Assembly of Single-Tip Metal-Semiconductor Nanorods in Selective Solvents

2011 ◽  
Vol 123 (20) ◽  
pp. 4702-4706 ◽  
Author(s):  
Nana Zhao ◽  
Jemma Vickery ◽  
Gerald Guerin ◽  
Jai Il Park ◽  
Mitchell A. Winnik ◽  
...  
Keyword(s):  
Self Assembly ◽  
Selective Solvents

Self-assembly and adsorption of diblock copolymers from selective solvents. 2. Surface adsorption

1994 ◽  
Vol 27 (3) ◽  
pp. 683-688 ◽  
Author(s):  
Yongjian Zhan ◽  
Wayne L. Mattice
Keyword(s):  
Self Assembly ◽  
Diblock Copolymers ◽  
Surface Adsorption ◽  
Selective Solvents

1998 E.W.R. Steacie Award Lecture Asymmetric amphiphilic block copolymers in solution: a morphological wonderland

1999 ◽  
Vol 77 (8) ◽  
pp. 1311-1326 ◽  
Author(s):  
Neil S Cameron ◽  
Muriel K Corbierre ◽  
Adi Eisenberg
Keyword(s):  
Self Assembly ◽  
Diblock Copolymers ◽  
Amphiphilic Block Copolymers ◽  
Polymer Composition ◽  
Selective Solvents ◽  
Thermodynamic And Kinetic Parameters ◽  
Amphiphilic Diblock Copolymers ◽  
Systematic Understanding ◽  
Selection Of ◽  
Qualitative Discussion

Asymmetric amphiphilic diblock copolymers self-assemble in selective solvents. Since 1995, when we first reported the systematic preparation of a sequence of various "crew-cut" aggregate morphologies from this class of copolymer in solution (1), we have identified a vast array of structures and have begun a detailed investigation of the thermodynamic and kinetic parameters that induce morphogenesis. Not only spheres, rods, bilayer and bicontinuous architectures, as well as inverted structures are observed, but also a selection of mixed, combined and much more complex aggregates is documented. All of these aggregates have a phase-separated insoluble core and a crew-cut soluble corona. Thus, all parameters that permit selective modification of the component of either phase or of the interface provide a window for morphological control. By carefully adjusting the polymer chain environment, it has been possible to develop a systematic understanding of morphogenic parameters, which include, among others, polymer composition, common solvent, initial concentration, temperature, type and concentration of added ions, method of preparation, and added homopolymer. To date, more than 30 publications have appeared in the literature from our group alone on this subject. One of the problems inherent with such a complicated system is the taxonomy or classification: which morphologies correspond to equilibrium positions and which are intermediate or trapped? An attempt at a logical presentation of the observed aggregates is given, preceded by a qualitative discussion of the thermodynamic framework for this system. Where possible, the transitions between morphologies are explained in the context of the thermodynamic parameters. Finally, parallels are drawn between the copolymer aggregates and biological architectures.Key words: crew-cut, morphology, block copolymer, self-assembly, amphiphile.

Influence of selective solvents on self-assembly behaviors of amphiphilic hyperbranched poly(aryl ether ketone)-graft-poly(ethylene glycol) rod–coil copolymer

2016 ◽  
Vol 29 (3) ◽  
pp. 257-265 ◽  
Author(s):  
Jiashuang Luan ◽  
Chunhua Lu ◽  
Yunliang Guo ◽  
Feng Li ◽  
Guibin Wang
Keyword(s):  
Ethylene Glycol ◽  
Self Assembly ◽  
Aryl Ether ◽  
Poly Ethylene Glycol ◽  
Selective Solvents ◽  
Hyperbranched Poly ◽  
Aryl Ether Ketone ◽  
Ether Ketone ◽  
Poly Ethylene
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