Photo-induced charge recombination kinetics in MAPbI3−xClx perovskite-like solar cells using low band-gap polymers as hole conductors

2014 ◽  
Vol 50 (93) ◽  
pp. 14566-14569 ◽  
Author(s):  
Jose Manuel Marin-Beloqui ◽  
Javier Pérez Hernández ◽  
Emilio Palomares

We measured the charge recombination kinetics using transient photovoltage (TPV) and laser transient absorption spectroscopy (L-TAS) in MAPbI3−xClx perovskite solar cells using low band gap polymers as hole transport materials (HTMs).

ACS Photonics ◽  
2015 ◽  
Vol 2 (5) ◽  
pp. 589-594 ◽  
Author(s):  
Dongqin Bi ◽  
Ahmed M. El-Zohry ◽  
Anders Hagfeldt ◽  
Gerrit Boschloo

2015 ◽  
Vol 3 (44) ◽  
pp. 22154-22161 ◽  
Author(s):  
Alba Matas Adams ◽  
Jose Manuel Marin-Beloqui ◽  
Georgiana Stoica ◽  
Emilio Palomares

This works shows the influence of the mesoporous TiO2 nature over the carrier recombination kinetics and the perovskite efficiency.


2020 ◽  
Author(s):  
Meenakshi Pegu ◽  
Laura Calio ◽  
Mehrad Ahmadpour ◽  
Horst-Günter Rubahn ◽  
Samrana Kazim ◽  
...  

<p>Semi-transparent perovskite solar cells have the competitive edge of being employed for building integrated photovoltaics due to their aesthetic benefits as light harvesting windows / facades. Perovskites have received considerable attention in recent years as a thin film photovoltaic alternative, that can also be tweaked for its transparency, evolving from potentially high bandgaps that are suited for semi-transparent solar cell fabrication. Due to the existing trade of between the efficiency and transparency of a perovskite solar cell, tuning the band gap can address this by making a bridge between the aforementioned parameters. We report our findings on the use of a wide-bandgap perovskite MAPbBr<sub>3</sub>, with a rational energetic level hole transport materials based on polycyclic aromatic hydrocarbon molecules that can be a promising alternative class of p-type material. In the present work, DBP (Dibenzo{[f,f' ]-4,4',7,7'-tetraphenyl}diindeno[1,2,3-cd :1',2',3'-lm]perylene, was evaluated with high band gap as well as with (FAPbI<sub>3</sub>)<sub>0.85</sub>(MAPbBr<sub>3</sub>)<sub>0.15 </sub>perovskites<sub> </sub>for the fabrication of solar cell. DBP based solar cells yielded competitive power conversion efficiencies as compared to classical HTMs.</p>


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