Transition-metal-free persulfuration to construct unsymmetrical disulfides and mechanistic study of the sulfur redox process
Keyword(s):
A sulfur redox process has been developed between sulfinate and thiosulfate, which efficiently affords diverse unsymmetrical disulfides and provides a new method to modify pharmaceuticals and natural products with this biologically active moiety without extra oxidant or reductant.
Keyword(s):
Keyword(s):
2000 ◽
Vol 122
(11)
◽
pp. 2613-2620
◽