Ligation driven 19F relaxation enhancement in self-assembled Ln(iii) complexes

2015 ◽  
Vol 51 (14) ◽  
pp. 2918-2920 ◽  
Author(s):  
Gemma-Louise Davies ◽  
Asha Brown ◽  
Octavia Blackburn ◽  
Manuel Tropiano ◽  
Stephen Faulkner ◽  
...  

Strong bidentate ligation of a fluorinated isophthalate with a binuclear lanthanide chelate results in the paramagnetic relaxation enhancement of 19F, providing a promising route to a generation of self-assembled 19F contrast agents.


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