Coordination polymers based on a glycine-derivative ligand

CrystEngComm ◽  
2014 ◽  
Vol 16 (35) ◽  
pp. 8119-8137 ◽  
Author(s):  
Sérgio M. F. Vilela ◽  
Duarte Ananias ◽  
Patrícia Silva ◽  
Mariela Nolasco ◽  
Luís D. Carlos ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Hydrothermal Conditions ◽  
Glycine Derivative

The combination of a glycine-derivative supramolecular salt with lanthanide(iii) chloride hydrates under hydrothermal conditions (120 °C, 48 h) produced a family of isotypical materials formulated as [Ln(bodt)(Hbodt)].

scholarly journals Investigation of the Preparation and Reactivity of Metal-Organic Frameworks of Cerium and Pyridine-2,4,6-Tricarboxylate

2021 ◽  
Author(s):  
Juliana Fonseca de Lima ◽  
Fernanda V.S. Moreno ◽  
Bruno A.T. Menezes ◽  
Jader da Silva Barbosa ◽  
Matthew C. Waddington ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Hydrothermal Conditions ◽  
Metal Organic

The synthesis of three coordination polymers of cerium(III) and the ligand pyridine-2,4,6-tricarboxylate (PTC) is reported. Two of the materials crystallise under hydrothermal conditions at 180 °C, with [Ce(PTC)(H2O)2]·1.5H2O, (1), being...

A threefold interpenetrated two-dimensional zinc(II) supramolecular architecture based on 3-nitrobenzoic acid and 4,4′-bipyridine

2016 ◽  
Vol 72 (2) ◽  
pp. 128-132 ◽  
Author(s):  
Long Tang ◽  
Ji-Jiang Wang ◽  
Feng Fu ◽  
Sheng-Wen Wang ◽  
Qi-Rui Liu
Keyword(s):  
Coordination Polymers ◽  
Crystal Engineering ◽  
Critical Factor ◽  
Building Blocks ◽  
Zigzag Chain ◽  
Great Success ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Hydrothermal Conditions ◽  
Nitrobenzoic Acid

With regard to crystal engineering, building block or modular assembly methodologies have shown great success in the design and construction of metal–organic coordination polymers. The critical factor for the construction of coordination polymers is the rational choice of the organic building blocks and the metal centre. The reaction of Zn(OAc)2·2H2O (OAc is acetate) with 3-nitrobenzoic acid (HNBA) and 4,4′-bipyridine (4,4′-bipy) under hydrothermal conditions produced a two-dimensional zinc(II) supramolecular architecture,catena-poly[[bis(3-nitrobenzoato-κ2O,O′)zinc(II)]-μ-4,4′-bipyridine-κ2N:N′], [Zn(C7H4NO4)2(C10H8N2)]nor [Zn(NBA)2(4,4′-bipy)]n, which was characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and single-crystal X-ray diffraction analysis. The ZnIIions are connected by the 4,4′-bipy ligands to form a one-dimensional zigzag chain and the chains are decorated with anionic NBA ligands which interact further through aromatic π–π stacking interactions, expanding the structure into a threefold interpenetrated two-dimensional supramolecular architecture. The solid-state fluorescence analysis indicates a slight blue shift compared with pure 4,4′-bipyridine and HNBA.

scholarly journals Syntheses, Structures, and Characteristics of Three Metal Complexes Constructed Using Hexacarboxylic Acid

Molecules ◽  
2019 ◽  
Vol 24 (24) ◽  
pp. 4431 ◽  
Author(s):  
Lingshu Meng ◽  
Lun Zhao ◽  
Guanlin Guo ◽  
Xin Liu ◽  
Zhijun Liang ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Thermogravimetric Analysis ◽  
Coordination Polymers ◽  
Electrochemical Behavior ◽  
Room Temperature ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Hexadentate Ligand ◽  
Xrd Techniques

In this study, three new 3D coordination polymers (CPs), {[Cd3(L)(H2O)6]·H2O}n (1), {[Cu1.5(L)0.5(bimb)1.5]·5H2O·DMF}n (2), and {[Mn1.5(H3L)(bibp)0.5(H2O)2]·3H2O}n (3) (bimb= 1,3-bis(imidazol-1-yl)benzene, bibp= 1,4-bis((4-imidazol-1-yl)benzyl)piperazine), were prepared under solvothermal or hydrothermal conditions based on a hexadentate ligand (1,3,5-triazine-2,4,6-triamine hexa-acetic acid (H6L)). Structural elucidations were carried out by IR spectra along with single-crystal X-ray diffraction analysis, while thermogravimetric analysis (TGA) (dynamic and isothermal) and XRD techniques were used for property evaluations of the polymers. Furthermore, the fluorescence properties and detection of the Fe3+ ions in 1 were tested at room temperature, and the electrochemical behavior of 2 is also stated in this article.

Metal Ion-Driven Assembly of Two New Coordination Polymers Constructed by Asymmetric Tricarboxylate and Imidazole-Containing Ligands: Syntheses, Crystal Structures, and Luminescent Properties

2015 ◽  
Vol 68 (1) ◽  
pp. 121 ◽  
Author(s):  
Wenlong Liu ◽  
Xueying Wang ◽  
Mengqiang Wu ◽  
Bing Wang
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymers ◽  
Metal Ion ◽  
Three Dimensional ◽  
Luminescent Properties ◽  
Dimensional Structure ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
X Ray ◽  
Dimethyl Benzene

Two new coordination polymers, namely, {[Cd3(bpt)2(bimb)2]·2(H2O)}n (1) and [Zn3(bpt)2(bimb)2]n (2) (bpt = biphenyl-3,4′,5-tricarboxylate, bimb = 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene), have been obtained under hydrothermal conditions. Their structures have been determined by single-crystal X-ray diffraction analysis and further characterised by elemental analysis and infrared spectroscopy. Complex 1 exhibits a trinodal (4,4,4)-connected topology with Schläfli symbol of (4.62.83)4.(64.82). Complex 2 is also a three-dimensional structure and displays a (3,4,6)-connected topology with Schläfli symbol of (4.62)2.(42.66.85.102).(64.82). It is shown that the asymmetrically tricarboxylate can bear diverse structures regulated by metal ions. The photoluminescence behaviours of compounds 1 and 2 were also discussed.

Assembly of a series of coordination polymers built from rigid a tetracarboxylate ligand and flexible bis(imidazole) linker: syntheses, structural diversities, luminescence sensing, and photocatalytic properties

2018 ◽  
Vol 47 (4) ◽  
pp. 1202-1213 ◽  
Author(s):  
Xiu-Tang Zhang ◽  
Hong-Tai Chen ◽  
Bin Li ◽  
Guang-Zeng Liu ◽  
Xin-Zheng Liu
Keyword(s):  
Coordination Polymers ◽  
Photocatalytic Properties ◽  
Tetracarboxylic Acid ◽  
Hydrothermal Conditions

CPs have been constructed from the reaction of terphenyl-4,2′′,5′′,4′-tetracarboxylic acid and two different bis(imidazole) bridging linkers under hydrothermal conditions.

Structures and Luminescent Properties of a Series of Zinc(II) and Cadmium(II) 4,4′-Oxydiphthalate Coordination Polymers with Various Ligands Based on Bis(pyridyl imidazole) under Hydrothermal Conditions

2008 ◽  
Vol 8 (5) ◽  
pp. 1610-1616 ◽  
Author(s):  
Shun-Li Li ◽  
Ya-Qian Lan ◽  
Jian-Fang Ma ◽  
Yao-Mei Fu ◽  
Jin Yang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Luminescent Properties ◽  
Hydrothermal Conditions

Lanthanide coordination polymers based on designed bifunctional 2-(2,2′:6′,2″-terpyridin-4′-yl)benzenesulfonate ligand: syntheses, structural diversity and highly tunable emission

2019 ◽  
Vol 75 (5) ◽  
pp. 855-864 ◽  
Author(s):  
Yi-Chen Hu ◽  
Chao Bai ◽  
Huai-Ming Hu ◽  
Chuan-Ti Li ◽  
Tian-Hua Zhang ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Emission Spectra ◽  
Green Emission ◽  
Structural Diversity ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
Lanthanide Coordination Polymers ◽  
Connected Node ◽  
Tunable Emission

Seven novel lanthanide coordination polymers, [Eu(STP)(glu)] n (1), [Ln4(STP)2(glu)5] n ·4nH2O [Ln = Er (2), Yb (3)], [Ln(STP)(1,3-bdc)] n ·0.5nH2O [Ln = Tb (4), Yb (5)], and [Ln(STP)(1,2-bdc)] n [Ln = Eu (6), Tb (7)] [NaSTP = sodium 2-(2,2′:6′,2″-terpyridin-4′-yl)benzenesulfonate, H2glu = glutaric acid, H2(1,3-bdc) = benzene-1,3-dicarboxylic acid, H2(1,2-bdc) = benzene-1,2-dicarboxylic acid], have been prepared under hydrothermal conditions and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compound (1) possesses a 2D layered structure based on 1D chains with STP− and glu2− anions acting as bridges. Compounds (2) and (3) are isomorphous and show a rare 3D tcj/hc net with a tetranuclear Ln3+ unit regarded as a seven-connected node and a glu2− anion serving as a three-connected node. Compounds (4) and (5) are isomorphous and exhibit six-connected pcu nets by denoting binuclear units to six-connected nodes. Compounds (6) and (7) display 3D 3,5T1 nets with (1,2-bdc)2− anions and dimetallic units serving as three- and five-connected nodes, respectively. The Eu compounds (1) and (6) demonstrate typically red emission, while the Tb compounds (4) and (7) exhibit characteristic green emission. The emission spectra of heteronuclear compounds [Eu x Tb1−x (STP)(1,2-bdc)] n (0 ≤ x ≤ 1) as efficient luminescent tags were investigated. The intermetallic energy transfer of Tb to Eu was also evaluated.

Structural investigation of one- and three-dimensional lanthanide(III) coordination polymers based on functionalized terpyridine carboxylate and aromatic dicarboxylate ligands

2019 ◽  
Vol 75 (4) ◽  
pp. 422-432 ◽  
Author(s):  
Chao Bai ◽  
Bin Liu ◽  
Huai-Ming Hu ◽  
Jin-Dian Li ◽  
Xiaofang Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Investigation ◽  
Three Dimensional ◽  
Topological Type ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
One Dimensional ◽  
X Ray ◽  
Lanthanide Coordination Polymers ◽  
3D Networks

Three series of lanthanide coordination polymers, namely catena-poly[[lanthanide(III)-μ2-(benzene-1,2-dicarboxylato)-μ2-[2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]] monohydrate], {[Ln(C8H4O4)(C22H14N3O2)]·H2O} n or {[Ln(1,2-bdc)(L)]·H2O} n , with lanthanide (Ln) = dysprosium (Dy, 1), holmium (Ho, 2) and erbium (Er, 3), poly[bis(μ2-benzene-1,3-dicarboxylato)bis[μ2-2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]dilanthanide(III)], [Ln2(C8H4O4)2(C22H14N3O2)2] n or [Ln2(1,3-bdc)2(L)2] n , with Ln = gadolinium (Gd, 4), Ho (5) and Er (6), and poly[(μ2-benzene-1,4-dicarboxylato)[μ2-2-(2,2′:6′,2′′-terpyridin-4′-yl)benzoato]lanthanide(III)], [Ln(C8H4O4)(C22H14N3O2)] n or [Ln(1,4-bdc)(L)] n , with Ln = Dy (7), Ho (8), Er (9) and ytterbium (Yb, 10), were synthesized under hydrothermal conditions and characterized by elemental analysis, IR and single-crystal X-ray diffraction. Compounds 1–3 possess one-dimensional loop chains with Ln2(COO)2 units, which are extended into three-dimensional (3D) supramolecular structures by π–π interactions. Isostructural compounds 5 and 6 show 6-connected 3D networks, with pcu topology consisting of Ln2(COO)2 units. Compounds 7–10 display 8-connected 3D frameworks with the topological type rob, consisting of Ln2(COO)2 units. The influence of the coordination orientations of the aromatic dicarboxylate groups on the crystal structures is discussed.

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