Monitoring the formation of carbide crystal phases during the thermal decomposition of 3d transition metal dicarboxylate complexes

2014 ◽  
Vol 43 (32) ◽  
pp. 12236-12242 ◽  
Author(s):  
Zachary J. Huba ◽  
Everett E. Carpenter
Keyword(s):  
Thermal Decomposition ◽  
Transition Metal ◽  
Single Molecule ◽  
Crystal Phases

Presented is a detailed study of the decomposition of late row 3d metal dicarboxylate complexes. It is shown that these complexes can be efficient single molecule precursors for the formation of carbide crystal phases.

A Mononuclear Transition Metal Single-Molecule Magnet in a Nuclear Spin-Free Ligand Environment

2014 ◽  
Vol 53 (19) ◽  
pp. 10716-10721 ◽  
Author(s):  
Majed S. Fataftah ◽  
Joseph M. Zadrozny ◽  
Dylan M. Rogers ◽  
Danna E. Freedman
Keyword(s):  
Transition Metal ◽  
Single Molecule ◽  
Nuclear Spin ◽  
Free Ligand ◽  
Single Molecule Magnet ◽  
Ligand Environment

Regulation of magnetic relaxation behavior by replacing 3d transition metal ions in [M2Dy2] complexes containing two different organic chelating ligands

2019 ◽  
Vol 48 (27) ◽  
pp. 10011-10022 ◽  
Author(s):  
Hui-Sheng Wang ◽  
Cheng-Ling Yin ◽  
Zhao-Bo Hu ◽  
Yong Chen ◽  
Zhi-Quan Pan ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Single Molecule ◽  
Magnetic Relaxation ◽  
Transition Metal Ions ◽  
Relaxation Behavior ◽  
Organic Ligands ◽  
Chelating Ligands ◽  
Single Molecule Magnet

Two [MIII2DyIII2] complexes (M = Fe for 1 and Co for 2) with mixed organic ligands were obtained. Complex 2 exhibits single molecule magnet behavior with Ueff = 64.0(9) K.

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