Influence of atmosphere on the thermal decomposition of some transition metal oxalates

1968 ◽  
Vol 30 (10) ◽  
pp. 2689-2695 ◽  
Author(s):  
E.D. Macklen
Keyword(s):  
Thermal Decomposition ◽  
Transition Metal

Monitoring the formation of carbide crystal phases during the thermal decomposition of 3d transition metal dicarboxylate complexes

2014 ◽  
Vol 43 (32) ◽  
pp. 12236-12242 ◽  
Author(s):  
Zachary J. Huba ◽  
Everett E. Carpenter
Keyword(s):  
Thermal Decomposition ◽  
Transition Metal ◽  
Single Molecule ◽  
Crystal Phases

Presented is a detailed study of the decomposition of late row 3d metal dicarboxylate complexes. It is shown that these complexes can be efficient single molecule precursors for the formation of carbide crystal phases.

Thermal decomposition of bivalent transition metal malonates in various atmospheres

1978 ◽  
Vol 23 (1) ◽  
pp. 125-133 ◽  
Author(s):  
Kazuo Muraishi ◽  
Kenzo Nagase ◽  
Nobuyuki Tanaka
Keyword(s):  
Thermal Decomposition ◽  
Transition Metal ◽  
Bivalent Transition Metal

Chemical Vapor Deposition of Binary Metal Germanides

1990 ◽  
Vol 187 ◽  
Author(s):  
M.J. Hampden-Smith ◽  
J. Garvey ◽  
D. Lei ◽  
J.C. Huffman
Keyword(s):  
Thermal Decomposition ◽  
Grain Size ◽  
Chemical Vapor Deposition ◽  
Transition Metal ◽  
Vapor Deposition ◽  
Chemical Vapor ◽  
Solution Model ◽  
Binary Metal ◽  
Decomposition Experiments

AbstractA series of transition metal substituted germacyclopent-3-ene compounds containing transition metal-germanium bonds have been prepared with supporting ligands which are designed to be easily removed either thermally or photochemically. In solution, model thermal decomposition experiments show that either the geramanium or the transition metal substituents may be removed, depending on the nature of the metal. Preliminary hot-wall CVD experiments using manganese and cobalt derivatives result in films with small grain size.

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