Enhanced water stability and CO2 gas sorption properties of a methyl functionalized titanium metal–organic framework

A methyl-modified metal–organic framework (m-TiBDC) exhibiting significantly enhanced hydrostability than unmodified TiBDC maintains its framework structure and also CO2 gas adsorption capacity even after its immersion in water for 2 hours.

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Facile hydrothermal synthesis of manganese-metal organic framework nanostructures in the presence of various organic ligands for SO2 and CO2 gas adsorption

Journal of Porous Materials ◽

10.1007/s10934-015-0090-y ◽

2015 ◽

Vol 23 (2) ◽

pp. 375-380 ◽

Cited By ~ 6

Author(s):

Mehdi Ranjbar ◽

Mohammad Ali Taher ◽

Abbas Sam

Keyword(s):

Hydrothermal Synthesis ◽

Gas Adsorption ◽

Metal Organic Framework ◽

Organic Ligands ◽

Co2 Gas ◽

Metal Organic ◽

Organic Framework

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Microporous La(III) Metal−Organic Framework Using a Semirigid Tricarboxylic Ligand: Synthesis, Single-Crystal to Single-Crystal Sorption Properties, and Gas Adsorption Studies

Crystal Growth & Design ◽

10.1021/cg100078b ◽

2010 ◽

Vol 10 (8) ◽

pp. 3410-3417 ◽

Cited By ~ 58

Author(s):

Prem Lama ◽

Arshad Aijaz ◽

Subhadip Neogi ◽

Leonard J. Barbour ◽

Parimal K. Bharadwaj

Keyword(s):

Single Crystal ◽

Gas Adsorption ◽

Metal Organic Framework ◽

Sorption Properties ◽

Adsorption Studies ◽

Metal Organic ◽

Ligand Synthesis ◽

Organic Framework

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Synthesis of MIL-101(Cr) Metal Organic Framework by Green Synthesis for CO2 Gas Adsorption

IOP Conference Series Earth and Environmental Science ◽

10.1088/1755-1315/945/1/012074 ◽

2021 ◽

Vol 945 (1) ◽

pp. 012074

Author(s):

Pui San Ho ◽

Kok Chung Chong ◽

Soon Onn Lai ◽

Shee Keat Mah ◽

Sze Shin Lee ◽

...

Keyword(s):

Adsorption Capacity ◽

Gas Adsorption ◽

Metal Organic Framework ◽

Critical Role ◽

Operating Cost ◽

Solvent Free ◽

Molar Ratio ◽

Promising Alternative ◽

Metal Organic ◽

Organic Framework

Abstract Global warming issue due to the excessive carbon dioxide gas emission have raised strong interest in capturing or reducing the CO2 from flue gas or atmosphere. Physisorption-based CO2 capture applying the metal organic framework (MOF) provides a promising alternative for capturing CO2 due to the simplicity, low operating cost, and low energy requirement of the adsorption approach combined with the high CO2 adsorption capacity MOF material. In this study, a series of Chromium based MIL MOF with a variety molar ratio of chromium metal to 1,4-Benzene Dicarboxylate (BDC) organic linker were prepared via the solvent-free method (mechanochemical) to develop a clean and efficient way of synthesising MOF samples as promising CO2 adsorbents. The XRD results and FTIR spectra have confirmed the successful fabrication of MIL-101(Cr) MOF using the solvent-free method. The SEM images illustrated fine growth of irregular shaped coarse particles for Cr MOF with equal mole ratio of Cr to BDC. The MIL-101(Cr) samples were also tested on their CO2 adsorption capacity to understand the influence of molar ratio of the starting materials on the CO2 adsorption capacity. It was found that the MIL-101(Cr)1 led to the formation of a product with the highest CO2 uptake capacity of 18.78 mmol/g. In contrast, the EDS analysis result revealed that all the samples synthesised in this work were well incorporated with the Chromium element. It is therefore suggested that the molar ratio of Cr to BDC plays a critical role in determining the CO2 gas adsorption capacity.

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