Synthesis of well-defined functionalized poly(2-(diisopropylamino)ethyl methacrylate) using ATRP with sodium dithionite as a SARA agent

2014 ◽  
Vol 5 (12) ◽  
pp. 3919-3928 ◽  
Author(s):  
Joana R. Góis ◽  
Nuno Rocha ◽  
Anatoliy V. Popov ◽  
Tamaz Guliashvili ◽  
Krzysztof Matyjaszewski ◽  
...  

2-(Diisopropylamino)ethyl methacrylate was polymerized by Atom Transfer Radical Polymerization using sodium dithionite as a reducing agent and supplemental activator with a Cu(ii)Br2/Me6TREN catalytic system.

2015 ◽  
Vol 6 (10) ◽  
pp. 1875-1882 ◽  
Author(s):  
Francisco Catalão ◽  
Joana R. Góis ◽  
A. S. M. Trino ◽  
Arménio C. Serra ◽  
Jorge F. J. Coelho

The detailed synthesis of poly(glycidyl methacrylate) (PGMA) by atom transfer radical polymerization (ATRP) using a catalytic system of Fe(0)/Cu(ii)Br2 at room temperature is reported.


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