Poly(methacrylic acid)-based AB and ABC block copolymer nano-objects prepared via RAFT alcoholic dispersion polymerization

2014 ◽  
Vol 5 (10) ◽  
pp. 3466-3475 ◽  
Author(s):  
M. Semsarilar ◽  
V. Ladmiral ◽  
A. Blanazs ◽  
S. P. Armes
Keyword(s):  
Block Copolymer ◽  
Methacrylic Acid ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Triblock Copolymers ◽  
Abc Triblock Copolymers

A series of well-defined amphiphilic methacrylic AB diblock and ABC triblock copolymers are synthesized via polymerization-induced self-assembly using an alcoholic dispersion polymerization formulation.

Aqueous Dispersion Polymerization: A New Paradigm for in Situ Block Copolymer Self-Assembly in Concentrated Solution

2011 ◽  
Vol 133 (39) ◽  
pp. 15707-15713 ◽  
Author(s):  
Shinji Sugihara ◽  
Adam Blanazs ◽  
Steven P. Armes ◽  
Anthony J. Ryan ◽  
Andrew L. Lewis
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Aqueous Dispersion ◽  
New Paradigm ◽  
Concentrated Solution

Microwave-assisted synthesis of block copolymer nanoparticles via RAFT with polymerization-induced self-assembly in methanol

2016 ◽  
Vol 7 (2) ◽  
pp. 297-301 ◽  
Author(s):  
Elden T. Garrett ◽  
Yiwen Pei ◽  
Andrew B. Lowe
Keyword(s):  
Block Copolymer ◽  
Comparative Study ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Microwave Assisted Synthesis ◽  
Conductive Heating ◽  
Microwave Assisted

A comparative study of microwave-assisted (MA) and conductive heating in RAFT dispersion polymerization formulations in MeOH that result in polymerization-induced self-assembly is detailed.

Synthesis of star thermoresponsive amphiphilic block copolymer nano-assemblies and the effect of topology on their thermoresponse

2019 ◽  
Vol 10 (3) ◽  
pp. 403-411 ◽  
Author(s):  
Mengjiao Cao ◽  
Huijun Nie ◽  
Yuwen Hou ◽  
Guang Han ◽  
Wangqing Zhang
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Amphiphilic Block Copolymer

Well-defined multi-arm star thermoresponsive block copolymer nano-assemblies of [poly(N-isopropylacrylamide)-block-polystyrene]n [(PNIPAM-b-PS)n] with n = 1, 2, 3 and 4 arms were synthesized by RAFT dispersion polymerization via polymerization-induced self-assembly.

Self-assembly of grafted Y-shaped ABC triblock copolymers in solutions

2008 ◽  
Vol 129 (15) ◽  
pp. 154903 ◽  
Author(s):  
Yuhua Yin ◽  
Run Jiang ◽  
Baohui Li ◽  
Qinghua Jin ◽  
Datong Ding ◽  
...  
Keyword(s):  
Self Assembly ◽  
Triblock Copolymers ◽  
Abc Triblock Copolymers

scholarly journals Influence of nucleobase stoichiometry on the self-assembly of ABC triblock copolymers

2016 ◽  
Vol 52 (48) ◽  
pp. 7564-7567 ◽  
Author(s):  
Keren Zhang ◽  
Samantha J. Talley ◽  
Ya Peng Yu ◽  
Robert B. Moore ◽  
Mitsuhiro Murayama ◽  
...  
Keyword(s):  
Long Range ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
The Self ◽  
Patterned Substrates ◽  
Abc Triblock Copolymers ◽  
Self Assembled

ABC triblock copolymers bearing adenine- and thymine-functionalized external blocks self-assembled into long-range, ordered lamellar microphase-separated morphologies on non-patterned substrates.

Self-assembly of PS-PNaSS-PS triblock copolymers from solution to the solid state

2017 ◽  
Vol 8 (21) ◽  
pp. 3357-3363 ◽  
Author(s):  
Sabrina Nehache ◽  
Mona Semsarilar ◽  
Martin In ◽  
Philippe Dieudonné-George ◽  
Joséphine Lai-Kee-Him ◽  
...  
Keyword(s):  
Solid State ◽  
Block Copolymer ◽  
Nanostructured Materials ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Morphological Development

Morphological development of block copolymer assemblies from solution to the solid state is explored to yield nanostructured materials.

Synthesis of poly(ionic liquid)-based nano-objects with morphological transitionsviaRAFT polymerization-induced self-assembly in ethanol

2018 ◽  
Vol 9 (7) ◽  
pp. 824-827 ◽  
Author(s):  
Yongqi Yang ◽  
Jinwen Zheng ◽  
Shoukuo Man ◽  
Xiaolan Sun ◽  
Zesheng An
Keyword(s):  
Ionic Liquid ◽  
Block Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Full Range ◽  
Poly Ionic Liquid

A full range of morphologies including spheres, worms and vesicles was observed in poly(ionic liquid)-based block copolymer nano-objectsviaethanolic dispersion polymerization.

scholarly journals Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization

2014 ◽  
Vol 136 (29) ◽  
pp. 10174-10185 ◽  
Author(s):  
Nicholas J. Warren ◽  
Steven P. Armes
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Aqueous Dispersion

Synthesis and Solution Self-Assembly of Polyferrocene-Based AB Diblock and ABC Triblock Copolymers

2003 ◽  
pp. 75-84 ◽  
Author(s):  
Xiao-Song Wang ◽  
Mitchell A. Winnik ◽  
Ian Manners
Keyword(s):  
Self Assembly ◽  
Triblock Copolymers ◽  
Abc Triblock Copolymers

scholarly journals Adding a solvophilic comonomer to the polymerization-induced self-assembly of block copolymer and homopolymer: a cooperative strategy for preparing large compound vesicles

RSC Advances ◽  
2017 ◽  
Vol 7 (73) ◽  
pp. 46069-46081 ◽  
Author(s):  
Chundong Huang ◽  
Jianbo Tan ◽  
Qin Xu ◽  
Jun He ◽  
Xueliang Li ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Binary Mixture ◽  
Self Assembly ◽  
Dispersion Polymerization ◽  
Cooperative Strategy ◽  
Large Compound

We report a RAFT dispersion polymerization of styrene and 4-vinylpyridine in methanol/water at 70 °C. The polymerization was mediated by a binary mixture of DDMAT and mPEG45-DDMAT.

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