scholarly journals Synthesis of donor–acceptor conjugated polymers based on benzo[1,2-b:4,5-b′]dithiophene and 2,1,3-benzothiadiazole via direct arylation polycondensation: towards efficient C–H activation in nonpolar solvents

2014 ◽  
Vol 5 (19) ◽  
pp. 5784-5792 ◽  
Author(s):  
Xiaochen Wang ◽  
Mingfeng Wang
Keyword(s):  
Conjugated Polymers ◽  
Boiling Point ◽  
Direct Arylation ◽  
Nonpolar Solvents ◽  
Donor Acceptor ◽  
High Boiling Point ◽  
Direct Arylation Polymerization ◽  
Direct Arylation Polycondensation

1,2-Dimethylbenzene, as a nonpolar high boiling point solvent, has been discovered to be a superior medium to perform direct-arylation polymerization.

Direct arylation polymerization of asymmetric push–pull aryl halides

2017 ◽  
Vol 8 (16) ◽  
pp. 2438-2441 ◽  
Author(s):  
Liyan You ◽  
Saadia T. Chaudhry ◽  
Yan Zhao ◽  
Junchen Liu ◽  
Xikang Zhao ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Aryl Halides ◽  
Direct Arylation ◽  
Donor Acceptor ◽  
Direct Arylation Polymerization ◽  
Polymerization Method

Recently, direct arylation polymerization (DArP) has emerged as a greener polymerization method for donor–acceptor (D–A) type conjugated polymers.

Influence of the aryl spacer in 2,5-dialkoxyphenylene and diaryl substituted thieno[3,4-c]pyrrole-4,6-dione copolymers

2018 ◽  
Vol 6 (22) ◽  
pp. 5992-5998 ◽  
Author(s):  
Robert M. Pankow ◽  
John D. Munteanu ◽  
Barry C. Thompson
Keyword(s):  
Conjugated Polymers ◽  
Direct Arylation ◽  
Donor Acceptor ◽  
Direct Arylation Polymerization ◽  
Polymerization Conditions

Polymerization conditions for direct arylation polymerization (DArP) now allow for the preparation of conjugated polymers, such as donor–acceptor copolymers, where undesired couplings (donor–donor, acceptor–acceptor, or branching defects) are undetectable.

Direct Arylation Polycondensation towards Water/Alcohol-Soluble Conjugated Polymers as Electron Transporting Layers for Organic Solar Cells

2021 ◽  
Author(s):  
Kaiwen Lin ◽  
Qingwu Yin ◽  
Zhenfeng Wang ◽  
Boming Xie ◽  
Chunhui Duan ◽  
...  
Keyword(s):  
Solar Cells ◽  
Conjugated Polymers ◽  
Organic Solar Cells ◽  
Direct Arylation ◽  
Direct Arylation Polycondensation ◽  
Water Alcohol

Two water/alcohol soluble conjugated polymers (WSCPs), based on naphthalenediimide and amino-functionalized 3,4-(propylenedioxy)thiophene were synthesized via direct arylation polycondensation (DArP). The polymers worked well as electron transporting layers (ETLs) for fullerene-based...

Synthesis of conjugated polymers using aryl-bromides via Cu-catalyzed direct arylation polymerization (Cu-DArP)

2019 ◽  
Vol 10 (48) ◽  
pp. 6545-6550 ◽  
Author(s):  
Liwei Ye ◽  
Robert M. Pankow ◽  
Alexander Schmitt ◽  
Barry C. Thompson
Keyword(s):  
Conjugated Polymers ◽  
Copper Catalysts ◽  
Aryl Bromide ◽  
Direct Arylation ◽  
First Report ◽  
Aryl Bromides ◽  
Direct Arylation Polymerization

The first report on direct arylation polymerization with copper catalysts and aryl-bromide monomers expands the sustainability and practicality of DArP.

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