Combining the incompatible: Block copolymers consecutively displaying activated esters and amines and their use as protein-repellent surface modifiers with multivalent biorecognition

2015 ◽  
Vol 6 (3) ◽  
pp. 476-486 ◽  
Author(s):  
Daniel Hoenders ◽  
Thomas Tigges ◽  
Andreas Walther
Keyword(s):  
Block Copolymers ◽  
Diblock Copolymers ◽  
Primary Amines ◽  
Facile Synthesis ◽  
Activated Esters ◽  
Surface Modifiers

We present the facile synthesis and orthogonal functionalization of diblock copolymers consisting of two incompatible segments, i.e. primary amines and activated esters, and demonstrate their use as protein-repellent brush layers with multivalent biorecognition.

Mechanical and Structural Consequences of Associative Dynamic Cross-Linking in Acrylic Diblock Copolymers

2019 ◽  
Author(s):  
Jacob Ishibashi ◽  
Yan Fang ◽  
Julia Kalow
Keyword(s):  
Block Copolymers ◽  
Rheological Properties ◽  
Diblock Copolymers ◽  
Cross Linking ◽  
Statistical Copolymer

<p>Block copolymers are used to construct covalent adaptable networks that employ associative exchange chemistry (vitrimers). The resulting vitrimers display markedly different nanostructural, thermal and rheological properties relative to those of their statistical copolymer-derived counterparts. This study demonstrates that prepolymer sequence is a versatile strategy to modify the properties of vitrimers.</p>

ChemInform Abstract: A Facile Synthesis of β-Substituted α-Allenyl Primary Amines.

ChemInform ◽  
1987 ◽  
Vol 18 (45) ◽  
Author(s):  
J. R. MCCARTHY ◽  
C. L. BARNEY ◽  
D. P. MATTHEWS ◽  
T. M. BARGAR
Keyword(s):  
Primary Amines ◽  
Facile Synthesis

Facile Synthesis of Main-Chain Degradable Block Copolymers for Performance Enhanced Dismantlable Adhesion

2012 ◽  
Vol 4 (4) ◽  
pp. 2057-2064 ◽  
Author(s):  
Eriko Sato ◽  
Takashi Hagihara ◽  
Akikazu Matsumoto
Keyword(s):  
Block Copolymers ◽  
Main Chain ◽  
Facile Synthesis

Amphiphilic Diblock Copolymers of Poly(glycidol) with Biodegradable Polyester/Polycarbonate. Organocatalytic One-Pot ROP and Self-Assembling Property

2021 ◽  
Author(s):  
Tingyu He ◽  
Atsushi Narumi ◽  
Yanqiu Wang ◽  
Liang Xu ◽  
Shin-ichiro Sato ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Diblock Copolymers ◽  
Amphiphilic Block Copolymers ◽  
Synthetic Method ◽  
Biodegradable Polyester ◽  
One Pot ◽  
Self Assembling ◽  
Amphiphilic Diblock Copolymers

A synthetic method for a series of poly(glycidol) (PG)-based amphiphilic block copolymers is presented with an emphasis on the catalyst switch method from an organic superbase (t-Bu-P4) to another with...

Self-crosslinking assemblies with tunable nanostructures from photoresponsive polypeptoid-based block copolymers

2020 ◽  
Vol 11 (2) ◽  
pp. 337-343 ◽  
Author(s):  
Jirui Wei ◽  
Jing Sun ◽  
Xu Yang ◽  
Sifan Ji ◽  
Yuhan Wei ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Diblock Copolymers ◽  
New Family

A series of reversible crosslinking assemblies with tunable morphologies are obtained from a new family of photoresponsive polypeptoid-based diblock copolymers.

Facile synthesis and catalytic activity of well-defined amphiphilic block copolymers based on N -vinylimidazolium

2013 ◽  
Vol 24 (12) ◽  
pp. 1089-1093 ◽  
Author(s):  
Chang Peng ◽  
Kai Huang ◽  
Mingsong Han ◽  
Wei Meng ◽  
Yuanqin Xiong ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Block Copolymers ◽  
Amphiphilic Block Copolymers ◽  
Facile Synthesis

Synthesis, characterization and association behavior of linear-dendritic amphiphilic diblock copolymers based on poly(ethylene oxide) and a dendron derived from 2,2′-bis(hydroxymethyl)propionic acid

2015 ◽  
Vol 6 (12) ◽  
pp. 2274-2282 ◽  
Author(s):  
Weiwei Zhang ◽  
Weiwei Jiang ◽  
Delong Zhang ◽  
Guangyue Bai ◽  
Pengxiao Lou ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Ethylene Oxide ◽  
Propionic Acid ◽  
Diblock Copolymers ◽  
Association Behavior ◽  
Poly Ethylene Oxide ◽  
Amphiphilic Diblock Copolymers ◽  
Poly Ethylene

Two new amphiphilic linear-dendritic block copolymers have been synthesized and characterized. And their association behaviors have also been studied.

Dilute Solutions of Block Copolymers. 1. Diblock Copolymers

1998 ◽  
Vol 31 (13) ◽  
pp. 4342-4349 ◽  
Author(s):  
O. F. Olaj ◽  
B. Neubauer ◽  
G. Zifferer
Keyword(s):  
Block Copolymers ◽  
Diblock Copolymers ◽  
Dilute Solutions
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