Zero valent metal/RAFT agent mediated CRP of functional monomers at room temperature: a promising catalyst system for CRP

2015 ◽  
Vol 6 (3) ◽  
pp. 359-363 ◽  
Author(s):  
Yuwei Gu ◽  
Junfei Zhao ◽  
Qingqing Liu ◽  
Xiangqiang Pan ◽  
Wei Zhang ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Room Temperature ◽  
Catalyst System ◽  
Functional Monomers ◽  
Control Radical Polymerization ◽  
Raft Agent

A facile approach to synthesize GMA polymers using Fe(0)/RAFT agent mediated control radical polymerization.

Photocontrolled iodine-mediated reversible-deactivation radical polymerization with a semifluorinated alternating copolymer as the macroinitiator

2020 ◽  
Vol 11 (47) ◽  
pp. 7497-7505
Author(s):  
Jiannan Cheng ◽  
Kai Tu ◽  
Enjie He ◽  
Jinying Wang ◽  
Lifen Zhang ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Room Temperature ◽  
Blue Led ◽  
Led Light ◽  
Alternating Copolymers ◽  
Alternating Copolymer ◽  
Reversible Deactivation ◽  
Novel Strategy ◽  
Reversible Deactivation Radical Polymerization

A novel strategy for preparing block copolymers with semifluorinated alternating copolymers as macroinitiators was established by photocontrolled iodine-mediated RDRP under irradiation with blue LED light at room temperature.

Reverse Atom-Transfer Radical Polymerization at Room Temperature

2001 ◽  
Vol 22 (6) ◽  
pp. 439-443 ◽  
Author(s):  
Wenxin Wang ◽  
Deyue Yan ◽  
Xuling Jiang ◽  
Christophe Detrembleur ◽  
Philippe Lecomte ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Room Temperature ◽  
Atom Transfer

Blue Light Driven Free-Radical Polymerization using Arylazo Sulfones as Initiators

2021 ◽  
Author(s):  
Andrea Nitti ◽  
Angelo Martinelli ◽  
Fabrice Batteux ◽  
Stefano Protti ◽  
Maurizio Fagnoni ◽  
...  
Keyword(s):  
Free Radical ◽  
Visible Light ◽  
Radical Polymerization ◽  
Blue Light ◽  
Room Temperature ◽  
Free Radical Polymerization

The polymerization of a broad range of electron-poor olefins has been achieved under free-radical conditions by using arylazo sulfones as visible light photoinitiators. The process proceeds smoothly at room temperature...

Aromatic thioketone-mediated radical polymerization of methacrylates and the preparation of amphiphilic quasi-block copolymers

2020 ◽  
Vol 11 (18) ◽  
pp. 3251-3259
Author(s):  
Haoyu Yu ◽  
Jianwei Shao ◽  
Dong Chen ◽  
Li Wang ◽  
Wantai Yang
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Control Radical Polymerization ◽  
Strong Ability

TfXT exhibits strong ability to control radical polymerization of methyl methacrylate and has been used in preparing amphiphilic quasi-block copolymer.

Aqueous Room Temperature Metal-Catalyzed Living Radical Polymerization of Vinyl Chloride

2002 ◽  
Vol 124 (18) ◽  
pp. 4940-4941 ◽  
Author(s):  
Virgil Percec ◽  
Anatoliy V. Popov ◽  
Ernesto Ramirez-Castillo ◽  
Michael Monteiro ◽  
Bogdan Barboiu ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Room Temperature ◽  
Living Radical Polymerization ◽  
Metal Catalyzed
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