Template confined synthesis of Cu- or Cu2O-doped SiO2aerogels from Cu(ii)-containing composites by in situ alcohothermal reduction

RSC Advances ◽  
2014 ◽  
Vol 4 (90) ◽  
pp. 49541-49546 ◽  
Author(s):  
Weiwei Xu ◽  
Ai Du ◽  
Jun Tang ◽  
Peng Yan ◽  
Xiaoguang Li ◽  
...  

Cu2O- or Cu-contained silica composite aerogels were synthesized by anin situalcohothermal reduction method, and the microstructure evolution mechanism was systematically studied.

2017 ◽  
Vol 5 (11) ◽  
pp. 11117-11123 ◽  
Author(s):  
Bin Yuan ◽  
Jinming Zhang ◽  
Qinyong Mi ◽  
Jian Yu ◽  
Rui Song ◽  
...  

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Tiancun Liu ◽  
Jinlong Wang ◽  
Yi Xu ◽  
Yifan Zhang ◽  
Yong Wang

Highlights A facile method is adopted to obtain cucumber-like lithiophilic composite skeleton. Massive lithiophilic sites in cucumber-like lithiophilic composite skeleton can promote and guide uniform Li depositions. A unique model of stepwise Li deposition and stripping is determined. Abstract The uncontrolled formation of lithium (Li) dendrites and the unnecessary consumption of electrolyte during the Li plating/stripping process have been major obstacles in developing safe and stable Li metal batteries. Herein, we report a cucumber-like lithiophilic composite skeleton (CLCS) fabricated through a facile oxidation-immersion-reduction method. The stepwise Li deposition and stripping, determined using in situ Raman spectra during the galvanostatic Li charging/discharging process, promote the formation of a dendrite-free Li metal anode. Furthermore, numerous pyridinic N, pyrrolic N, and CuxN sites with excellent lithiophilicity work synergistically to distribute Li ions and suppress the formation of Li dendrites. Owing to these advantages, cells based on CLCS exhibit a high Coulombic efficiency of 97.3% for 700 cycles and an improved lifespan of 2000 h for symmetric cells. The full cells assembled with LiFePO4 (LFP), SeS2 cathodes and CLCS@Li anodes demonstrate high capacities of 110.1 mAh g−1 after 600 cycles at 0.2 A g−1 in CLCS@Li|LFP and 491.8 mAh g−1 after 500 cycles at 1 A g−1 in CLCS@Li|SeS2. The unique design of CLCS may accelerate the application of Li metal anodes in commercial Li metal batteries.


2017 ◽  
Vol 238 ◽  
pp. 90-96 ◽  
Author(s):  
Guoqing Zu ◽  
Jun Shen ◽  
Liping Zou ◽  
Wenbing Zou ◽  
Dayong Guan ◽  
...  

2014 ◽  
Vol 584-586 ◽  
pp. 944-950 ◽  
Author(s):  
Dong Fu Zhao ◽  
Mei Liu ◽  
Shi Ji Zhang

The domestic and overseas research progresses of microstructure of the concrete and fatigue damage after treated by high temperature are reviewed. The main research direction and current shortage on the high temperature process, fatigue damage and the microstructure evolution mechanism of concrete are discussed. A view of the application prospects of concrete research on the high temperature process, fatigue damage and the microstructure evolution mechanism of concrete is forecast.


CrystEngComm ◽  
2014 ◽  
Vol 16 (7) ◽  
pp. 1322-1333 ◽  
Author(s):  
Shuijin Lei ◽  
Lei Liu ◽  
Chunying Wang ◽  
Xiaolian Shen ◽  
Donghai Guo ◽  
...  

Author(s):  
Kota Yamamoto ◽  
Hisashi Asanuma ◽  
Hiroaki Takahashi ◽  
Takafumi Hirata

New data reduction method for isotopic measurements using high-gain Faraday amplifiers enables precise uranium isotopic analysis even from transient signals.


Sign in / Sign up

Export Citation Format

Share Document