Synthesis and thermal properties of modified room temperature vulcanized (RTV) silicone rubber using polyhedral oligomeric silsesquioxane (POSS) as a cross linking agent

RSC Advances ◽  
2014 ◽  
Vol 4 (78) ◽  
pp. 41453-41460 ◽  
Author(s):  
Yunhui Shi ◽  
Xiaoxiao Gao ◽  
Dian Zhang ◽  
Yufeng Liu ◽  
Guangsu Huang
Keyword(s):  
Thermal Properties ◽  
Silicone Rubber ◽  
Room Temperature ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Cross Linking ◽  
Oligomeric Silsesquioxane ◽  
Rtv Silicone Rubber

Incompletely condensed tetra-silanol-phenyl-polyhedral oligomeric silsesquioxane (TOPO) was synthesized first and then copolymerized with hydroxy terminated polydimethylsiloxane (HPDMS) as a cross linking agent to prepare room temperature vulcanized (RTV) silicone rubber (TOPO–PDMS).

scholarly journals Synthesis and Characterization of Room Temperature Vulcanized Silicone Rubber Using Methoxyl-Capped MQ Silicone Resin as Self-Reinforced Cross-Linker

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1142 ◽  
Author(s):  
Jianye Ji ◽  
Xin Ge ◽  
Xiaoyan Pang ◽  
Ruoling Liu ◽  
Shuyi Wen ◽  
...  
Keyword(s):  
Silicone Rubber ◽  
Room Temperature ◽  
Degradation Rate ◽  
Light Transmission ◽  
Characteristic Temperature ◽  
Cross Linking ◽  
Silicone Resin ◽  
Cross Linker ◽  
Rtv Silicone Rubber

Methoxyl-capped MQ silicone resin (MMQ) was first synthesized by the hydrosilylation of vinyl-containing MQ silicone resin and trimethoxysilane and then used in condensed room-temperature vulcanized (RTV) silicone rubber as a self-reinforced cross-linker. Results show that modified silicone rubber exhibits good light transmission. Compared with unmodified silicone rubber, the hardness, tensile strength and elongation of MMQ at the break are increased by 26.4 A, 2.68 MPa and 65.1%, respectively. In addition, the characteristic temperature of 10% mass loss is delayed from 353.5 °C to 477.1 °C, the temperature at maximum degradation rate is also delayed from 408.9 °C to 528.4 °C and the residual mass left at 800 °C is increased from 1.2% to 27.7%. These improved properties are assigned to the synergistic effect of the rigid structure of MMQ, the formation of a dense cross-linking structure in polymers and the uniform distribution of MMQ cross-linking agent in RTV silicone rubber.

Preparation and characterization of room temperature vulcanized silicone rubber using α-amine ketoximesilanes as auto-catalyzed cross-linkers

RSC Advances ◽  
2016 ◽  
Vol 6 (44) ◽  
pp. 38447-38453 ◽  
Author(s):  
Qian Zhao ◽  
Qingyang Liu ◽  
Huihui Xu ◽  
Yiling Bei ◽  
Shengyu Feng
Keyword(s):  
Silicone Rubber ◽  
Room Temperature ◽  
Rtv Silicone Rubber

A series of α-amine ketoximesilanes were prepared and used as auto-catalyzed cross-linkers in one component room temperature vulcanized (RTV) silicone rubber.

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