A local hydrophobic environment in a metal–organic framework for boosting photocatalytic CO2 reduction in the presence of water

2019 ◽  
Vol 55 (98) ◽  
pp. 14781-14784 ◽  
Author(s):  
Ning-Yu Huang ◽  
Xue-Wen Zhang ◽  
Yu-Zhi Xu ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Co2 Reduction ◽  
Metal Center ◽  
High Catalytic Activity ◽  
Methylene Groups ◽  
Metal Organic ◽  
Repulsive Forces ◽  
Organic Framework

The methylene groups surrounding the metal center in a metal–organic framework provide hydrophobic repulsive forces to H2O, resulting in a high catalytic activity (TOF = 73.8 h−1, selectivity of 96%) for photodriven CO2 reduction into CO.

High Catalytic Activity of C 60 Pd n Encapsulated in Metal–Organic Framework UiO‐67, for Tandem Hydrogenation Reaction

2018 ◽  
Vol 24 (72) ◽  
pp. 19141-19145 ◽  
Author(s):  
Deng‐Yue Zheng ◽  
Xue‐Meng Zhou ◽  
Suresh Mutyala ◽  
Xiao‐Chun Huang
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Hydrogenation Reaction ◽  
High Catalytic Activity ◽  
Metal Organic ◽  
Organic Framework

A metal–organic framework with in situ generated low-coordinate binuclear Cu(i) units as a highly effective catalyst for photodriven hydrogen production

2020 ◽  
Vol 56 (49) ◽  
pp. 6700-6703
Author(s):  
Ning-Yu Huang ◽  
Hai He ◽  
Hao Li ◽  
Pei-Qin Liao ◽  
Xiao-Ming Chen
Keyword(s):  
Catalytic Activity ◽  
Hydrogen Production ◽  
Synergistic Effect ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Binuclear Copper ◽  
Metal Organic ◽  
Cu Ions ◽  
Organic Framework

Here, we report a metal–organic framework featuring a binuclear copper unit, showing extraordinarily high catalytic activity (102.8 mmol g−1 h−1) for photodriven H2 generation, which is attributed to the synergistic effect between the two Cu ions.

Cobalt nanoparticle-embedded nitrogen-doped carbon/carbon nanotube frameworks derived from a metal–organic framework for tri-functional ORR, OER and HER electrocatalysis

2019 ◽  
Vol 7 (8) ◽  
pp. 3664-3672 ◽  
Author(s):  
Hele Guo ◽  
Qichun Feng ◽  
Jixin Zhu ◽  
Jingsan Xu ◽  
Qianqian Li ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Carbon Nanotube ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Nitrogen Doped ◽  
Metal Organic ◽  
Nitrogen Doped Carbon ◽  
Cobalt Nanoparticle ◽  
Organic Framework

A Co@N-CNTF electrocatalyst derived from a metal–organic framework exhibits high catalytic activity in the ORR, OER and HER.

Interfacial assembly and hydrolysis for synthesizing a TiO2/metal–organic framework composite

Soft Matter ◽  
2017 ◽  
Vol 13 (48) ◽  
pp. 9174-9178 ◽  
Author(s):  
Lifei Liu ◽  
Fanyu Zhang ◽  
Jianling Zhang ◽  
Xiuniang Tan ◽  
Bingxing Zhang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Interfacial Assembly ◽  
Metal Organic ◽  
Organic Framework

The interfacial assembling and hydrolysis route is proposed for fabricating TiO2/UiO-67 composites, which have shown high catalytic activity for photocatalytic CO2 reduction.

scholarly journals A base-free Chan–Lam reaction catalyzed by an easily assembled Cu(II)-carboxylate metal-organic framework

2021 ◽  
pp. 174751982110265
Author(s):  
Xinhai Zhang ◽  
Jianhua Qin ◽  
Ruixuan Ma ◽  
Lei Shi
Keyword(s):  
Catalytic Activity ◽  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Coupling Reaction ◽  
High Catalytic Activity ◽  
Arylboronic Acids ◽  
Metal Organic ◽  
Organic Framework

A new copper(II) metal-organic framework is constructed as a sustainable copper heterogeneous catalyst. Cu-DPTCA, with high catalytic activity, can effectively promote the Chan–Lam coupling reaction of arylboronic acids and amines without adding any base or additive.

Metal–organic framework-derived hybrid of Fe3C nanorod-encapsulated, N-doped CNTs on porous carbon sheets for highly efficient oxygen reduction and water oxidation

2016 ◽  
Vol 6 (16) ◽  
pp. 6365-6371 ◽  
Author(s):  
Pingping Zhao ◽  
Xing Hua ◽  
Wei Xu ◽  
Wei Luo ◽  
Shengli Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Oxygen Reduction ◽  
Porous Carbon ◽  
Water Oxidation ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Highly Efficient ◽  
Metal Organic ◽  
Organic Framework

A hybrid of Fe3C@CNTs grown on N-doped porous carbon sheets derived from MOF exhibited exceedingly high catalytic activity toward ORR and OER.

Palladium nanoparticles encapsulated inside the pores of a metal–organic framework as a highly active catalyst for carbon–carbon cross-coupling

RSC Advances ◽  
2014 ◽  
Vol 4 (97) ◽  
pp. 54487-54493 ◽  
Author(s):  
Ningzhao Shang ◽  
Shutao Gao ◽  
Xin Zhou ◽  
Cheng Feng ◽  
Zhi Wang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Palladium Nanoparticles ◽  
Active Catalyst ◽  
Metal Organic Framework ◽  
Cross Coupling ◽  
High Catalytic Activity ◽  
Coupling Reactions ◽  
Highly Active ◽  
Metal Organic ◽  
Organic Framework

Palladium nanoparticles were successfully encapsulated in the cages of MIL-101, which exhibited high catalytic activity toward the C–C coupling reactions.

Visible light-enhanced thermal decomposition performance of ammonium perchlorate with a metal–organic framework-derived Ag-embedded porous ZnO nanocomposite

2018 ◽  
Vol 42 (22) ◽  
pp. 18001-18009 ◽  
Author(s):  
Jingfeng Wang ◽  
Yang Li ◽  
Yadong Qiao ◽  
Guangzhi Yu ◽  
Jinzhu Wu ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Catalytic Activity ◽  
Visible Light ◽  
Ammonium Perchlorate ◽  
Metal Organic Framework ◽  
High Catalytic Activity ◽  
Metal Organic ◽  
Organic Framework

An Ag-embedded porous ZnO nanocomposite (Ag–ZnO NC) fabricated using an MOF exhibits high catalytic activity for the thermal decomposition of AP under the assistance of visible light.

A Highly Stable Zn9-Pyrazolate Metal-Organic Framework with Metallosalen Ligands as Carbon Dioxide Cycloaddition Catalyst

2022 ◽  
Author(s):  
Rong Cao ◽  
Fa-Xue Ma ◽  
Fu-Qi Mi ◽  
Meng-Jiao Sun ◽  
Tao Huang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Three Dimensional ◽  
High Catalytic Activity ◽  
Cycloaddition Reactions ◽  
Metal Organic ◽  
Organic Framework

A three-dimensional (3D) metal-organic framework constructed from unprecedented Zn9O2(OH)2(pyz)12 (pyz = pyrazolate) clusters and Ni(salen)-derived linkers was reported. The MOF exhibits high catalytic activity for CO2 cycloaddition reactions with excellent...

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