Controlled synthesis and characterization of poly[methyl(3,3,3-trifluoropropyl)siloxane] with selective end groups

RSC Advances ◽  
2014 ◽  
Vol 4 (99) ◽  
pp. 56279-56287 ◽  
Author(s):  
Hua-Feng Fei ◽  
Wenchun Xie ◽  
Qian Wang ◽  
Xiyin Gao ◽  
Tao Hu ◽  
...  
Keyword(s):  
Mass Distribution ◽  
Molar Mass ◽  
Molar Mass Distribution ◽  
Synthesis And Characterization ◽  
Controlled Synthesis ◽  
Controlled Polymerization ◽  
End Groups ◽  
Polymerization Method

Controlled polymerization method to synthesize poly[methyl(3,3,3-trifluoropropyl)siloxane] with narrow molar mass distribution, broad “termination window”, selective end groups and quantitative transformation.

Characterization of Chemical Composition along the Molar Mass Distribution in Polyolefin Copolymers by GPC Using a Modern Filter-Based IR Detector

2013 ◽  
Vol 330 (1) ◽  
pp. 63-80 ◽  
Author(s):  
A. Ortín ◽  
J. Montesinos ◽  
E. López ◽  
P. del Hierro ◽  
B. Monrabal ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Mass Distribution ◽  
Molar Mass ◽  
Molar Mass Distribution ◽  
Ir Detector

QELSS diffusion data for moderately broad molar mass distribution polymer samples compared with data from classical gradient techniques

1989 ◽  
Vol 54 (7) ◽  
pp. 1821-1829
Author(s):  
Bedřich Porsch ◽  
Simon King ◽  
Lars-Olof Sundelöf
Keyword(s):  
Diffusion Coefficient ◽  
Mass Distribution ◽  
Molar Mass ◽  
Molar Mass Distribution ◽  
Diffusion Data ◽  
Mass Distributions ◽  
Classical Diffusion ◽  
Polydisperse Polymer

The differences between the QELSS and classical diffusion coefficient of a polydisperse polymer resulting from distinct definitions of experimentally accessible average values are calculated for two assumed specific forms of molar mass distributions. Predicted deviations are compared with the experiment using NBS 706 standard polystyrene. QELSS Dz of this sample relates within 2-4% to the classical diffusion coefficient, if the Schulz-Zimm molar mass distribution is assumed to be valid. In general, differences between the height-area and QELSS diffusion coefficient of about 20% may be found for Mw/Mn ~ 2, and this value may increase above 35%, if strongly tailing molar mass distribution pertains to the sample.

Shape-controlled synthesis and characterization of BaZrO3 microcrystals

2004 ◽  
Vol 266 (4) ◽  
pp. 539-544 ◽  
Author(s):  
Zhouguang Lu ◽  
Yougen Tang ◽  
Limiao Chen ◽  
Yadong Li
Keyword(s):  
Synthesis And Characterization ◽  
Controlled Synthesis ◽  
Shape Controlled

scholarly journals Synthesis and Characterization of a Multifunctional Conjugated Polymer

2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Emerson C. G. Campos ◽  
Cristiano Zanlorenzi ◽  
Bruno F. Nowacki ◽  
Gabriela M. Miranda ◽  
Denis A. Turchetti ◽  
...  
Keyword(s):  
Conjugated Polymer ◽  
Molar Mass ◽  
Photophysical Properties ◽  
Gel Permeation Chromatography ◽  
Thermal Characterization ◽  
Polymer Structure ◽  
Synthesis And Characterization ◽  
Metallic Ions ◽  
Scanning Calorimetry

This work reports the synthesis and characterization of a conjugated polymer based on fluorene and terpyridine, namely, poly[(9,9-bis(3-((S)-2-methylbutylpropanoate))fluorene-alt-6,6′-(2,2′:6′,2′′-terpyridin-6-yl)] (LaPPS71). The structure was characterized by 1H and 13C nuclear magnetic resonance (NMR) and Fourier-transform infrared (FTIR) spectroscopy. The molar mass was measured by gel permeation chromatography (GPC). As thermal characterization, the glass transition temperature (Tg) was measured by differential scanning calorimetry (DSC). The polymer structure contains two sites capable of complexation with metallic ions, affording the possibility of obtainment of independent or electronically coupled properties, depending on the complexation site. The photophysical properties were fully explored in solution and solid state, presenting ideal results for the preparation of various metallopolymers, in addition to potential application as a metamaterial, due to the presence of the chiral center in the side chains of the polymer.

Evaluation of post-consumer cellulosic textile waste for chemical recycling based on cellulose degree of polymerization and molar mass distribution

2019 ◽  
Vol 89 (23-24) ◽  
pp. 5067-5075 ◽  
Author(s):  
Helena Wedin ◽  
Marta Lopes ◽  
Herbert Sixta ◽  
Michael Hummel
Keyword(s):  
End Of Life ◽  
Intrinsic Viscosity ◽  
Mass Distribution ◽  
Service Sector ◽  
Molar Mass ◽  
Degree Of Polymerization ◽  
Molar Mass Distribution ◽  
Chemical Recycling ◽  
Cellulose Content ◽  
Cellulosic Textiles

The aim of this study is to improve the understanding of which end-of-life cellulosic textiles can be used for chemical recycling according to their composition, wear life and laundering—domestic versus service sector. For that purpose, end-of-life textiles were generated through laboratorial laundering of virgin fabrics under domestic and industrial conditions, and the cellulose content and its intrinsic viscosity and molar mass distribution were measured in all samples after two, 10, 20, and 50 laundering cycles. Results presented herein also address the knowledge gap concerning polymer properties of end-of-life man-made cellulosic fabrics—viscose and Lyocell. The results show that post-consumer textiles from the home consumer sector, using domestic laundering, can be assumed to have a similar, or only slightly lower, degree of polymerization than the virgin textiles (−15%). Post-consumer textiles from the service sector, using industrial laundering, can be assumed to have a substantially lower degree of polymerization. An approximate decrease of up to 80% of the original degree of polymerization can be expected when they are worn out. A higher relative decrease for cotton than man-made cellulosic textiles is expected. Furthermore, in these laboratorial laundering trials, no evidence evolved that the cellulose content in blended polyester fabrics would be significantly affected by domestic or industrial laundering. With respect to molar mass distribution, domestic post-consumer cotton waste seems to be the most suitable feedstock for chemical textile recycling using Lyocell-type processes, although a pre-treatment step might be required to remove contaminants and lower the intrinsic viscosity to 400–500 ml/g.

Controlled synthesis and characterization of iron oxide micro-particles for Fe-air battery electrode material

2014 ◽  
Vol 293 (1) ◽  
pp. 49-63 ◽  
Author(s):  
Nguyen Viet Long ◽  
Yong Yang ◽  
Cao Minh Thi ◽  
Bui Thi Hang ◽  
Yanqin Cao ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Electrode Material ◽  
Synthesis And Characterization ◽  
Controlled Synthesis ◽  
Micro Particles ◽  
Battery Electrode ◽  
Air Battery
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