A new Co-nitroimidazolate–dicarboxylate pillared-layer network with various types of channels and ultra-large cages for gas uptake

CrystEngComm ◽  
2016 ◽  
Vol 18 (10) ◽  
pp. 1768-1774 ◽  
Author(s):  
Xiao-Qing Guo ◽  
Miao Wang ◽  
Yan-Feng Tang ◽  
Fei Meng ◽  
Guo-Qing Jiang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Uptake Capacity ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

A 3-D pillared-layer metal–organic framework constructed from unprecedented Co3-Co2-bdc-based layers and 2-nitroimidazole as pillars exhibits various types of pores and a nanometer-sized cavity along with a high CO2 uptake capacity (73.3 cm3 g−1 at 273 K and 1 atm).

A highly porous 4,4-paddlewheel-connected NbO-type metal–organic framework with a large gas-uptake capacity

2013 ◽  
Vol 42 (31) ◽  
pp. 11304 ◽  
Author(s):  
Zhaoxu Wang ◽  
Baishu Zheng ◽  
Heting Liu ◽  
Pinggui Yi ◽  
Xiaofang Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Uptake Capacity ◽  
Gas Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A non-interpenetrated porous metal–organic framework with high gas-uptake capacity

2011 ◽  
Vol 47 (35) ◽  
pp. 9861 ◽  
Author(s):  
Dong Han ◽  
Fei-Long Jiang ◽  
Ming-Yan Wu ◽  
Lian Chen ◽  
Qi-Hui Chen ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Uptake Capacity ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

Synthesis, crystal structure and gas uptake properties of a urea-functionalized rht-type metal–organic framework

Polyhedron ◽  
2015 ◽  
Vol 99 ◽  
pp. 1-6 ◽  
Author(s):  
Qiu-Yan Li ◽  
Ying Quan ◽  
Wei Wei ◽  
Jian Li ◽  
Han Lu ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Metal Organic Framework ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

Formation of a Metal-Organic Framework with High Surface Area and Gas Uptake by Breaking Edges Off Truncated Cuboctahedral Cages

2013 ◽  
Vol 125 (43) ◽  
pp. 11492-11495 ◽  
Author(s):  
Ruirui Yun ◽  
Zhiyong Lu ◽  
Yi Pan ◽  
Xiaozeng You ◽  
Junfeng Bai
Keyword(s):  
Surface Area ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework

A zinc(ii) metal–organic framework with high affinity for CO2 based on triazole and tetrazolyl benzene carboxylic acid

CrystEngComm ◽  
2019 ◽  
Vol 21 (24) ◽  
pp. 3679-3685 ◽  
Author(s):  
Donghai Sheng ◽  
Ying Zhang ◽  
Yang Han ◽  
Guang Xu ◽  
Qingxiang Song ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Metal Organic Framework ◽  
Uptake Capacity ◽  
High Affinity ◽  
Metal Organic ◽  
Organic Framework

A new metal–organic framework {[Zn2(Htzba)2(dmtrz)]·(CH3)2NH}n (1) has already been solvothermally synthesized that exhibits a high CO2 uptake capacity.

A urea decorated (3,24)-connected rht-type metal–organic framework exhibiting high gas uptake capability and catalytic activity

CrystEngComm ◽  
2015 ◽  
Vol 17 (25) ◽  
pp. 4632-4636 ◽  
Author(s):  
Xiao-Jun Wang ◽  
Jian Li ◽  
Qiu-Yan Li ◽  
Pei-Zhou Li ◽  
Han Lu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Gas Uptake ◽  
Metal Organic ◽  
Organic Framework
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