Very low amount of TiO2 on N-doped carbon nanotubes significantly improves oxygen reduction activity and stability of supported Pt nanoparticles

2015 ◽  
Vol 17 (16) ◽  
pp. 10767-10773 ◽  
Author(s):  
Anqi Zhao ◽  
Justus Masa ◽  
Wei Xia

Highly dispersed TiO2 on nitrogen-doped carbon nanotubes is used to tackle the carbon corrosion problem when used as support for Pt in electrocatalysis.

2015 ◽  
Vol 51 ◽  
pp. 27-32 ◽  
Author(s):  
Roberto Bresciani ◽  
Stefania Marzorati ◽  
Alessandro Lascialfari ◽  
Benedetta Sacchi ◽  
Nadia Santo ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (44) ◽  
pp. 25051-25056 ◽  
Author(s):  
Yanhong Yin ◽  
Hengbo Zhang ◽  
Rongzhen Gao ◽  
Aili Wang ◽  
Xinxin Mao ◽  
...  

In this work, a Co–N doped carbon nanotube (CNT) catalyst was fabricated via a simple pyrolysis approach.


2017 ◽  
Vol 62 (20) ◽  
pp. 1365-1372 ◽  
Author(s):  
Hao Fan ◽  
Lijun Yang ◽  
Yu Wang ◽  
Xiali Zhang ◽  
Qingsong Wu ◽  
...  

2015 ◽  
Vol 17 (34) ◽  
pp. 21950-21959 ◽  
Author(s):  
Yuhang Li ◽  
Guoyu Zhong ◽  
Hao Yu ◽  
Hongjuan Wang ◽  
Feng Peng

DFT calculations reveal a mixed mechanism for the oxygen reduction reaction catalyzed by nitrogen-doped carbon nanotubes in acidic electrolyte.


2020 ◽  
Vol 529 ◽  
pp. 147174 ◽  
Author(s):  
Hui Peng ◽  
Miaoran Zhang ◽  
Kanjun Sun ◽  
Xuan Xie ◽  
Haikuo Lei ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 864 ◽  
Author(s):  
Zhenhua Yao ◽  
Ruiyang Fan ◽  
Wangyang Ji ◽  
Tingxuan Yan ◽  
Maocong Hu

In this work, non-traditional metal-free polynitrogen chain N8− deposited on a nitrogen-doped carbon nanotubes (PN-NCNT) catalyst was successfully synthesized by a facile cyclic voltammetry (CV) approach, which was further tested in an oxygen reduction reaction (ORR). The formation of PN on NCNT was confirmed by attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR) and Raman spectroscopy. Partial positive charge of carbon within NCNT facilitated electron transfer and accordingly induced the formation of more PN species compared to CNT substrate as determined by temperature-programmed decomposition (TPD). Rotating disk electrode (RDE) measurements suggested that a higher current density was achieved over PN-NCNT than that on PN-CNT catalyst, which can be attributed to formation of the larger amount of N8− on NCNT. Kinetic study suggested a four-electron pathway mechanism over PN-NCNT. Moreover, it showed long stability and good methanol tolerance, which indicates its great potential application. This work provides insights on designing and synthesizing non-traditional metal-free catalysts for ORR in fuel cells.


2016 ◽  
Vol 28 (19) ◽  
pp. 3777-3784 ◽  
Author(s):  
Zhao‐Qing Liu ◽  
Hui Cheng ◽  
Nan Li ◽  
Tian Yi Ma ◽  
Yu‐Zhi Su

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