Understanding the role of the dye/oxide interface via SnO2-based MK-2 dye-sensitized solar cells

2015 ◽  
Vol 17 (23) ◽  
pp. 15193-15200 ◽  
Author(s):  
Dae-Yong Son ◽  
Chang-Ryul Lee ◽  
Hee-Won Shin ◽  
In-Hyuk Jang ◽  
Hyun Suk Jung ◽  
...  

The interfacial blocking layer between dye and oxide was found to play crucial roles in retarding recombination, increasing diffusion, accelerating dye regeneration and narrowing the density of states.

2017 ◽  
Vol 53 (49) ◽  
pp. 6629-6632 ◽  
Author(s):  
Vediappan Sudhakar ◽  
Arulraj Arulkashmir ◽  
Kothandam Krishnamoorthy

A polymer–graphene blocking layer decreases back electron transfer and increases dye regeneration that improved the DSSC efficiency to 10.4%.


2016 ◽  
Vol 40 (7) ◽  
pp. 6228-6237 ◽  
Author(s):  
Sankarapanicker Suresh ◽  
Thrithamarassery Gangadharan Deepak ◽  
Chengsheng Ni ◽  
Chandrasekharan Nair Omanaamma Sreekala ◽  
Malladi Satyanarayana ◽  
...  

Role of Nb2O5 amorphous/crystalline blocking layers were investigated in DSSCs and a theoretical explanation was deduced from transient voltage decay analysis.


Langmuir ◽  
2012 ◽  
Vol 28 (15) ◽  
pp. 6485-6493 ◽  
Author(s):  
Elizabeth A. Gibson ◽  
Loïc Le Pleux ◽  
Jérôme Fortage ◽  
Yann Pellegrin ◽  
Errol Blart ◽  
...  

2019 ◽  
Author(s):  
Ana Lucia Pinto ◽  
Luis Cruz ◽  
Vânia Gomes ◽  
Hugo Cruz ◽  
Giuseppe Calogero ◽  
...  

2013 ◽  
Vol 1 (13) ◽  
pp. 4345 ◽  
Author(s):  
Xiu Wang ◽  
Ran Deng ◽  
Sneha A. Kulkarni ◽  
Xiaoyan Wang ◽  
Stevin Snellius Pramana ◽  
...  

2014 ◽  
Vol 67 (5) ◽  
pp. 819
Author(s):  
Syed Mujtaba Shah ◽  
Zafar Iqbal ◽  
Muzaffar Iqbal ◽  
Naila Shahzad ◽  
Amina Hana ◽  
...  

Porphyrin dyes have an inherent tendency to aggregate. This leads to a self-quenching phenomenon that hinders electron transfer to the conduction band of semiconductors in dye-sensitized solar cells. Self-quenching adversely affects the efficiency of solar cells. Here, we report the interaction of porphyrin with pristine and acid-functionalized fullerene molecules on the surface of ZnO nanoparticles under chemisorbed conditions. Chemisorption of porphyrin only on ZnO nanoparticles instigates aggregation of the porphyrin molecules. These aggregates can be effectively broken by chemisorbing fullerene molecules on the surface of the ZnO nanoparticles. This is due to self-assembly formation processes because of porphyrin–fullerene interactions. The nanohybrid material, consisting of ZnO nanorods, acid-functionalized porphyrin, and fullerene derivatives, was characterized by UV–visible spectroscopy, fourier transform infrared spectroscopy, fluorescence spectroscopy, and transmission electron microscopy. The material generates better performing dye-sensitized solar cells when compared with those fabricated from porphyrin-based photo-active material.


2018 ◽  
Vol 246 ◽  
pp. 236-245 ◽  
Author(s):  
Francis Chindeka ◽  
Philani Mashazi ◽  
Jonathan Britton ◽  
Gertrude Fomo ◽  
David O. Oluwole ◽  
...  

2018 ◽  
Vol 6 (42) ◽  
pp. 11444-11456 ◽  
Author(s):  
Jonnadula Venkata Suman Krishna ◽  
Narra Vamsi Krishna ◽  
Towhid H. Chowdhury ◽  
Suryaprakash Singh ◽  
Idriss Bedja ◽  
...  

We have designed and synthesised four novel porphyrin sensitizers for dye-sensitized solar cell applications and shown power conversion efficiency of 10.5%.


2018 ◽  
Vol 206 ◽  
pp. 12-20 ◽  
Author(s):  
Sekar Ramkumar ◽  
Jaime Llanos ◽  
Darío Espinoza ◽  
Paulraj Manidurai

2021 ◽  
Vol 33 (10) ◽  
pp. 2373-2378
Author(s):  
K. Gokula Krishnan ◽  
V. Saravanan ◽  
C. Udhaya Kumar ◽  
C. Ramalingan

Three novel cyanoacetamide decorated phenothiazines (1a-c) have been designed. Structural and photo-physical properties of the molecules 1a-c have been investigated. To better realize the charge transport process involved in the dye-sensitized solar cells (DSSCs), computational studies have been performed using B3LYP and CAM-B3LYP method for the dyes 1a-c. Theoretical findings for DSSCs include LHE (light-harvesting efficiency) and driving forces such as electron injection (ΔGinject) and dye regeneration have been calculated to envisage the most appropriate dyes for the application of DSSC.


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