scholarly journals Role of temperature in the recombination reaction on dye-sensitized solar cells

2015 ◽  
Vol 17 (35) ◽  
pp. 22699-22710 ◽  
Author(s):  
J. Maçaira ◽  
I. Mesquita ◽  
L. Andrade ◽  
A. Mendes

The DSC recombination kinetics was studied up to 100 °C without electrolyte leakage or external contamination using a unique laser assisted glass sealing process. In addition to temperature having a strong influence on the recombination reaction rate, the energy of the exited electrons was found to be critical for determining the recombination activation energy.

2019 ◽  
Author(s):  
Ana Lucia Pinto ◽  
Luis Cruz ◽  
Vânia Gomes ◽  
Hugo Cruz ◽  
Giuseppe Calogero ◽  
...  

2013 ◽  
Vol 1 (13) ◽  
pp. 4345 ◽  
Author(s):  
Xiu Wang ◽  
Ran Deng ◽  
Sneha A. Kulkarni ◽  
Xiaoyan Wang ◽  
Stevin Snellius Pramana ◽  
...  

2014 ◽  
Vol 67 (5) ◽  
pp. 819
Author(s):  
Syed Mujtaba Shah ◽  
Zafar Iqbal ◽  
Muzaffar Iqbal ◽  
Naila Shahzad ◽  
Amina Hana ◽  
...  

Porphyrin dyes have an inherent tendency to aggregate. This leads to a self-quenching phenomenon that hinders electron transfer to the conduction band of semiconductors in dye-sensitized solar cells. Self-quenching adversely affects the efficiency of solar cells. Here, we report the interaction of porphyrin with pristine and acid-functionalized fullerene molecules on the surface of ZnO nanoparticles under chemisorbed conditions. Chemisorption of porphyrin only on ZnO nanoparticles instigates aggregation of the porphyrin molecules. These aggregates can be effectively broken by chemisorbing fullerene molecules on the surface of the ZnO nanoparticles. This is due to self-assembly formation processes because of porphyrin–fullerene interactions. The nanohybrid material, consisting of ZnO nanorods, acid-functionalized porphyrin, and fullerene derivatives, was characterized by UV–visible spectroscopy, fourier transform infrared spectroscopy, fluorescence spectroscopy, and transmission electron microscopy. The material generates better performing dye-sensitized solar cells when compared with those fabricated from porphyrin-based photo-active material.


2018 ◽  
Vol 246 ◽  
pp. 236-245 ◽  
Author(s):  
Francis Chindeka ◽  
Philani Mashazi ◽  
Jonathan Britton ◽  
Gertrude Fomo ◽  
David O. Oluwole ◽  
...  

2017 ◽  
Vol 5 (11) ◽  
pp. 5373-5382 ◽  
Author(s):  
Jayraj V. Vaghasiya ◽  
Keval K. Sonigara ◽  
Jyoti Prasad ◽  
Thomas Beuvier ◽  
Alain Gibaud ◽  
...  

Efficient electron donors, phenothiazine (PTZ)/phenoxazine (POZ) substituted imidazolium (IMI) and benzimidazolium (BIMI) iodide solid organic ionic conductors (SOICs) possessing good thermal stability and high conductivity are synthesized and used as electrolytes in solid state dye solar cell (ss-DSSC).


2011 ◽  
Vol 50 (6) ◽  
pp. 06GF08 ◽  
Author(s):  
Shyam S. Pandey ◽  
Kyung-Young Lee ◽  
Azwar Hayat ◽  
Yuhei Ogomi ◽  
Shuzi Hayase

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