The mechanism of excited-state proton transfer in 1-naphthol–piperidine clusters

2015 ◽  
Vol 17 (38) ◽  
pp. 25393-25402 ◽  
Author(s):  
Toshihiko Shimizu ◽  
Shun Manita ◽  
Shunpei Yoshikawa ◽  
Kenro Hashimoto ◽  
Mitsuhiko Miyazaki ◽  
...  

Photoexcitation directly triggers proton transfer in 1-naphthol–(piperidine)n. This mechanism is essentially different from 1-naphthol–(NH3)n in which the internal conversion process is required to promote excited-state proton transfer.

2015 ◽  
Vol 6 (10) ◽  
pp. 5762-5767 ◽  
Author(s):  
Rachel Crespo-Otero ◽  
Nawee Kungwan ◽  
Mario Barbatti

Topographical analysis of the dimer's excited state shows that internal conversion after first proton transfer blocks the stepwise process.


2021 ◽  
Author(s):  
Christophe Jouvet ◽  
Mitsuhiko Miyazaki ◽  
Masaaki Fujii

A general model of excited state hydrogen transfer (ESHT) which unifies ESHT and the excited state proton transfer (ESPT) is presented from experimental and theoretical works on phenol–(NH3)n. The hidden role of ESPT is revealed.


2021 ◽  
Vol 231 ◽  
pp. 117840
Author(s):  
Hao Dong ◽  
Huan Yang ◽  
Jinfeng Zhao ◽  
Xiaoyan Liu ◽  
Yujun Zheng

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