Preparation of hydrophobic reduced graphene oxide supported Ni-B-P-O and Co-B-P-O catalysts and their high hydrodeoxygenation activities

2016 ◽  
Vol 18 (4) ◽  
pp. 984-988 ◽  
Author(s):  
Weiyan Wang ◽  
Pengli Liu ◽  
Kui Wu ◽  
Song Tan ◽  
Wensong Li ◽  
...  

Hydrophobic reduced graphene oxide supported Ni-B-P-O and Co-B-P-O catalysts were beneficial to disperse in the non-polar solvent, prevent the contact with water, and consequently protected the active phases and exhibited high catalytic activity in the liquid-phase p-cresol HDO reaction.

Nanoscale ◽  
2018 ◽  
Vol 10 (26) ◽  
pp. 12487-12496 ◽  
Author(s):  
Haichao Duan ◽  
Yu Yang ◽  
Jianhua Lü ◽  
Changli Lü

We report a facile, mussel-inspired construction of a thermo-responsive diblock copolymer-anchored rGO support for superfine PdNPs with high catalytic activity.


2018 ◽  
Vol 42 (14) ◽  
pp. 12222-12233 ◽  
Author(s):  
Mir Ghasem Hosseini ◽  
Raana Mahmoodi ◽  
Mehdi Abdolmaleki

Ni@Pd/rGO shows excellent catalytic activity and power density toward hydrazine oxidation in comparison with Ni@Pt/rGO and Ni@Ru/rGO.


RSC Advances ◽  
2015 ◽  
Vol 5 (57) ◽  
pp. 45641-45641
Author(s):  
Pei Song ◽  
Jiu-Ju Feng ◽  
Shu-Xian Zhong ◽  
Su-Su Huang ◽  
Jian-Rong Chen ◽  
...  

Correction for ‘Facile preparation of reduced graphene oxide supported PtNi alloyed nanosnowflakes with high catalytic activity’ by Pei Song et al., RSC Adv., 2015, 5, 35551–35557.


2018 ◽  
Vol 232 (3) ◽  
pp. 431-443 ◽  
Author(s):  
Xigang Du ◽  
Yonghua Duan ◽  
Jun Zhang ◽  
Gang Mi

AbstractCoMo nanoparticles (NPs) supported on reduced graphene oxide (RGO) were synthesized by a one-stepin situco-reduction of an aqueous solution of cobalt(II) chloride, sodium molybdate dihydrate and graphene oxide (GO) using NaBH4as the sole reductant under ambient conditions. The powder XRD, FTIR, EDS and TEM were employed to characterize the structure, size and composition of the CoMo/RGO catalysts. The as-synthesized Co0.9Mo0.1/RGO catalysts exhibited high catalytic activity for the hydrolytic dehydrogenation of ammonia borane (AB) at room temperature. The as-synthesized Co0.9Mo0.1/RGO nanocatalysts exhibited much higher catalytic activity than Co/RGO, Mo/RGO and the RGO-free Co0.9Mo0.1counterpart. Moreover, kinetic studies indicate that the catalytic hydrolysis of AB by Co0.9Mo0.1/RGO has first order kinetics with respect to the the catalyst concentration, but zero order kinetics with respect to the substrate concentration. The Co0.9Mo0.1/RGO catalyst has a turnover frequency (TOF) of 15.8 mol H2·(mol·Co0.9Mo0.1/RGO)−1·min−1at 25°C. Furthermore, the Co0.9Mo0.1/RGO show good recyclability for hydrogen generation from an aqueous solution of AB, which enables the practical reuse of the catalysts. Hence, this general method can be easily extended to the facile preparation of other RGO-based metallic systems.


Sign in / Sign up

Export Citation Format

Share Document