Study on the solution and solid-state fluorescence of novel BF2 complexes with (Z)-2-[phenanthridin-6(5H)-ylidene]-1-phenylethanone and its derivatives as ligands

2015 ◽  
Vol 39 (8) ◽  
pp. 6465-6473 ◽  
Author(s):  
Ding-Er Wu ◽  
Xiao-Lin Lu ◽  
Min Xia

A family of novel N,O-chelated BF2 complexes with intense solution and solid-state emission were synthesized and their photophysical properties were studied.

2016 ◽  
Vol 12 ◽  
pp. 825-834 ◽  
Author(s):  
Andreea Petronela Diac ◽  
Ana-Maria Ţepeş ◽  
Albert Soran ◽  
Ion Grosu ◽  
Anamaria Terec ◽  
...  

New indeno[1,2-c]pyran-3-ones bearing different substituents at the pyran moiety were synthesized and their photophysical properties were investigated. In solution all compounds were found to be blue emitters and the trans isomers exhibited significantly higher fluorescence quantum yields (relative to 9,10-diphenylanthracene) as compared to the corresponding cis isomers. The solid-state fluorescence spectra revealed an important red shift of λmax due to intermolecular interactions in the lattice, along with an emission-band broadening, as compared to the solution fluorescence spectra.


RSC Advances ◽  
2016 ◽  
Vol 6 (85) ◽  
pp. 82227-82232 ◽  
Author(s):  
O. V. Ershov ◽  
M. Yu. Ievlev ◽  
M. Yu. Belikov ◽  
K. V. Lipin ◽  
A. I. Naydenova ◽  
...  

Several novel aryl substituted 2-halogencinchomeronic dinitriles, possessing an intensive solid state fluorescence, were synthesized. The relationship between the chemical structures and photophysical properties of these compounds was investigated.


2020 ◽  
Vol 49 (2) ◽  
pp. 438-452 ◽  
Author(s):  
Bhupendra Kumar Dwivedi ◽  
Vishwa Deepak Singh ◽  
Yogesh Kumar ◽  
Daya Shankar Pandey

In this work, we present tetraphenylimidazole-based BODIPYs (HPIB1–HPIB4) as fluorescent molecular rotors exhibiting aggregation induced emission, solid state fluorescence and appreciable sensitivity towards viscosity.


2016 ◽  
Vol 20 (01n04) ◽  
pp. 429-437 ◽  
Author(s):  
Brijesh Chandra ◽  
Navendu Mondal ◽  
B. Sathish Kumar ◽  
Pradeepta K. Panda

A new subporphyrin namely, hydroxo-5,10,15-tri([Formula: see text]-propyl-3-carbazolyl)subporphyri natoboron(III) 6 has been synthesized via the reported litreture procedure by the condensation of pyridine-tri-[Formula: see text]-pyrrolylborane with 9-propyl-9H-carbazole-3-carbaldehyde. Its porphyrin analog [Formula: see text]. 5,10,15,20-tetra([Formula: see text]-propyl-3-carbazolyl)porphyrin has also been isolated from the reaction mixture, formed due to scrambling process and complexed with Zn(II). Photophysical properties of both subporphyrin and Zn(II)porphyrin have been studied in detail to confirm the intramolecular charge transfer process in subporphyrin analog. In addition, the ring contracted congener 6 also displays solid state fluorescence.


Polyhedron ◽  
2018 ◽  
Vol 155 ◽  
pp. 202-208 ◽  
Author(s):  
A.N. Gusev ◽  
V.F. Shul'gin ◽  
E.V. Braga ◽  
I. Nemec ◽  
B.F. Minaev ◽  
...  

2021 ◽  
Vol 9 (10) ◽  
pp. 3901-3908
Author(s):  
Fanyong Yan ◽  
Hao Zhang ◽  
Jinxia Xu ◽  
Yawei Wu ◽  
Yueyan Zang ◽  
...  

Author(s):  
Mykhaylo A. Potopnyk ◽  
Mykola Kravets ◽  
Roman Luboradzki ◽  
Dmytro Volyniuk ◽  
Volodymyr Sashuk ◽  
...  

Two novel AIE-active donor–acceptor organoboron complexes with a carbazole donor unit are developed and their morphology-dependent solid-state fluorescence properties are established.


2020 ◽  
Vol 75 (4) ◽  
pp. 365-369
Author(s):  
Long Tang ◽  
Yu Pei Fu ◽  
Na Cui ◽  
Ji Jiang Wang ◽  
Xiang Yang Hou ◽  
...  

AbstractA new metal-organic framework, [Pb(hmpcaH)2]n (1), has been hydrothermally synthesized from Pb(OAc)2 · 3H2O and 2-hydroxy-6-methylpyridine-4-carboxylic acid (hmpcaH2; 2), and characterized by IR spectroscopy, elemental and thermogravimetric analysis, and single-crystal X-ray diffraction. In complex 1, each hmpcaH− ligand represents a three-connected node to combine with the hexacoordinated Pb(II) ions, generating a 3D binodal (3,6)-connected ant network. The crystal structure of 2 was determined. The solid-state fluorescence properties of 1 and 2 were investigated.


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