A vinyl polymer having pendent sulfones prepared by atom-transfer radical polymerization of a sulfide-containing methacrylate and electrophoretic transparent coating on a stainless-steel anode

2015 ◽  
Vol 6 (23) ◽  
pp. 4336-4342 ◽  
Author(s):  
Tomomi Kameyama ◽  
Akinori Takasu

A vinyl polymer containing pendent sulfones (oxidation > 99%), which was then selectively coated onto a stainless-steel anode by electrophoretic deposition, in which the deposited film was transparent.

2014 ◽  
Vol 67 (4) ◽  
pp. 555 ◽  
Author(s):  
Xin-Xing Deng ◽  
Yang Cui ◽  
Yao-Zong Wang ◽  
Fu-Sheng Du ◽  
Zi-Chen Li

We report a facile ‘grafting from’ approach to graft copolymers with polyamide backbones and controlled vinyl polymer or polyester side chains. Two polyamides with in situ-formed pendant bromide or hydroxyl groups were obtained by Passerini-based multicomponent polymerization. They were used respectively to initiate the atom-transfer radical polymerization of vinyl monomers or the ring-opening polymerization of lactones to generate two new types of graft copolymers. One of the important features of the method is that the pendant initiators are generated in situ from non-branching monomers, and they are linked to the polymer backbone by ester bonds. Therefore, the vinyl polymer side chains could be detached from the backbones, and their structures could thus be fully characterized. Moreover, multicomponent polymerization and atom-transfer radical polymerization can even be carried out in a one-pot manner.


Langmuir ◽  
2006 ◽  
Vol 22 (1) ◽  
pp. 255-262 ◽  
Author(s):  
Milena Ignatova ◽  
Samuel Voccia ◽  
Bernard Gilbert ◽  
Nadya Markova ◽  
Damien Cossement ◽  
...  

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