Novel in situ-foaming materials derived from a naphthalene-based poly(arylene ether ketone) containing thermally labile groups

2015 ◽  
Vol 6 (28) ◽  
pp. 5125-5132 ◽  
Author(s):  
Duo Qi ◽  
Chengji Zhao ◽  
Liyuan Zhang ◽  
Xuefeng Li ◽  
Guibin Li ◽  
...  
Keyword(s):  
Arylene Ether ◽  
Ether Ketone

A novel in situ-foaming material was prepared from a naphthalene-based poly(arylene ether ketone) by grafting with thermally-labile tert-butyloxycarbonyl which can decompose and in situ generate gases.

In situ synthesis of transparent fluorescent cadmium sulfide–poly(arylene ether ketone) nanocomposite hybrids

2013 ◽  
Vol 25 (8) ◽  
pp. 879-885 ◽  
Author(s):  
Yinan Zhang ◽  
Dong Jiang ◽  
Hui Wang ◽  
Haibo Zhang ◽  
Zhenhua Jiang
Keyword(s):  
Cadmium Sulfide ◽  
In Situ Synthesis ◽  
Arylene Ether ◽  
Ether Ketone

Mild and in situ photo-crosslinking of anthracene-functionalized poly (aryl ether ketone) for enhancing temporal stability of organic NLO materials

2021 ◽  
Vol 56 (9) ◽  
pp. 5910-5923
Author(s):  
Yanxin Tian ◽  
Yulin He ◽  
Pan Liu ◽  
Hui Zhang ◽  
Qiuying Zheng ◽  
...  
Keyword(s):  
Temporal Stability ◽  
Aryl Ether ◽  
Nlo Materials ◽  
Aryl Ether Ketone ◽  
Ether Ketone

Enhanced CO2 permeability of thermal crosslinking membrane via sulfonation/desulfonation of phenolphthalein-based cardo poly(arylene ether ketone)

2020 ◽  
Vol 598 ◽  
pp. 117824 ◽  
Author(s):  
Ruisong Xu ◽  
Lin Li ◽  
Mengjie Hou ◽  
Jiajia Xue ◽  
Yuzhe Liu ◽  
...  
Keyword(s):  
Arylene Ether ◽  
Thermal Crosslinking ◽  
Ether Ketone

scholarly journals Sulfonated Binaphthyl-Containing Poly(arylene ether ketone)s with Rigid Backbone and Excellent Film-Forming Capability for Proton Exchange Membranes

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1287 ◽  
Author(s):  
Wenmeng Zhang ◽  
Shaoyun Chen ◽  
Dongyang Chen ◽  
Zhuoliang Ye
Keyword(s):  
Mechanical Properties ◽  
Proton Conductivity ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Thermal Stabilities ◽  
Chemical Structures ◽  
Arylene Ether ◽  
Film Forming ◽  
Ether Ketone ◽  
Microscopic Morphology

Sterically hindered (S)-1,1′-binaphthyl-2,2′-diol had been successfully copolymerized with 4,4′-sulfonyldiphenol and 4,4′-difluorobenzophenone to yield fibrous poly(arylene ether ketone)s (PAEKs) containing various amounts of binaphthyl unit, which was then selectively and efficiently sulfonated using ClSO3H to yield sulfonated poly(arylene ether ketone)s (SPAEKs) with ion exchange capacities (IECs) ranging from 1.40 to 1.89 mmol·g−1. The chemical structures of the polymers were confirmed by 2D 1H–1H COSY NMR and FT-IR. The thermal properties, water uptake, swelling ratio, proton conductivity, oxidative stability and mechanical properties of SPAEKs were investigated in detail. It was found that the conjugated but non-coplanar structure of binaphthyl unit endorsed excellent solubility and film-forming capability to SPAEKs. The SPAEK-50 with an IEC of 1.89 mmol·g−1 exhibited a proton conductivity of 102 mS·cm−1 at 30 °C, much higher than that of the state-of-the-art Nafion N212 membrane and those of many previously reported aromatic analogs, which may be attributed to the likely large intrinsic free volume of SPAEKs created by the highly twisted chain structures and the desirable microscopic morphology. Along with the remarkable water affinity, thermal stabilities and mechanical properties, the SPAEKs were demonstrated to be promising proton exchange membrane (PEM) candidates for potential membrane separations.

Sign in / Sign up

Export Citation Format

Share Document