Rare-earth free narrow-band green-emitting KAlSi2O6:Mn2+ phosphor excited by blue light for LED-phosphor material

RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 30001-30004 ◽  
Author(s):  
Xin Ding ◽  
Ge Zhu ◽  
Qian Wang ◽  
Yuhua Wang

A novel rare-earth free narrow-band green-emitting KAlSi2O6:Mn2+ phosphor excited by blue light for LED is synthesized by solid-state reaction.

2016 ◽  
Vol 18 (28) ◽  
pp. 19165-19172 ◽  
Author(s):  
Lihong Bao ◽  
Xiaoping Qi ◽  
Tana Tana ◽  
Lumen Chao ◽  
O. Tegus

Multiple nanocrystalline rare-earth hexaborides La1−xBaxB6 have been synthesized via a single step solid-state reaction.


2019 ◽  
Vol 7 (36) ◽  
pp. 11227-11233 ◽  
Author(s):  
Xiu Wang ◽  
Jia Wang ◽  
Xingyu Li ◽  
Haoyang Luo ◽  
Mingying Peng

In this work, a series of novel non-rare-earth ion activated phosphors Ba2Y5−xB5O17:xBi3+ for white light-emitting diodes (WLEDs) was prepared via the high temperature solid state reaction route.


2014 ◽  
Vol 2 (37) ◽  
pp. 7952-7959 ◽  
Author(s):  
Zhi-Jun Zhang ◽  
Otmar M. ten Kate ◽  
Anneke Delsing ◽  
Pieter Dorenbos ◽  
Jing-Tai Zhao ◽  
...  

RE3+ (RE = Pr, Sm, and Tb)-doped SrAlSi4N7 samples were synthesized by a solid-state reaction method at high temperature, and their photoluminescence properties were investigated.


2015 ◽  
Vol 3 (27) ◽  
pp. 7014-7021 ◽  
Author(s):  
Matteo Balestrieri ◽  
Silviu Colis ◽  
Mathieu Gallart ◽  
Guy Schmerber ◽  
Marc Ziegler ◽  
...  

The luminescence of rare earths in CeO2is sensitized by intrinsic Ce3+ions.


2014 ◽  
Vol 90 ◽  
pp. 133-140
Author(s):  
Erkul Karacaoglu ◽  
Bekir Karasu ◽  
Esra Öztürk

The Akermanite type alkaline earth silicate Ca2MgSi2O7 activated by different types of rare earths was prepared by the conventional solid state reaction method under weak reductive atmosphere. The phase formation, particle size distribution, particle morphologies and photoluminescence properties of the samples have been investigated respectively. The comparative results of SEM and laser particle size analysis revealed that the relatively regular morphology, smaller particle size distribution could be achieved for the phosphors synthesized by the solid state reaction method including dry-ground after which powders were sieved below 170 meshes. The effects of rare earth oxides; Nd2O3, Pr6O11, Ce2O3 and Sm2O3 on the luminescence properties of the host material, Ca2MgSi2O7, were studied. Remarkable enhancement and novel color emitting including white in luminescence characteristics of host material were observed as a result of doping the mentioned rare-earths were doped.


2021 ◽  
Vol 16 (2) ◽  
Author(s):  
Sukhdev Bairagi ◽  
Ghizal F. Ansari ◽  
K.S. Bartwal

In this work, the polycrystalline CaAl2O4: Eu2+, Nd3+ based blue phosphor was prepared by solid-state reaction method. The rare earth metal ions doped calcium aluminate phosphors have been studied in depth. The high quantum efficiency make them useful for anomalous long phosphorescence, good stability, luminous paints, radiation dosimetry, X-ray imaging, color display, and light emitting diodes. Phase, crystallinity and luminescent properties of the synthesized phosphors were examined by using powder X-ray diffraction (XRD). In the phosphor material, the photoluminescence (PL) spectrum has a broad emission peak of Eu2+ ion in blue region at (λmax = 440 nm) due to the energy transitions between the ground state 4f7 and the excited state 4f65d1 of the Eu2+ ion. This has importance in making the visible phosphor devices from this material. In this study the single dopant phosphors were synthesized; therefore, it is important to improve the long afterglow of the phosphors by codoping. The phosphors of CaAl2O4: Eu2+, Nd3+ had long persistence luminescence. In these phosphors, Eu2+ ions play the role of activators. Whereas Nd3+ ions generate deep traps that lead to the long persistent phosphorescence and act as the co-activators in the phosphors simultaneously. The concentration of Nd3+ ion co-doped has strong influence on the luminescence of phosphor.


2003 ◽  
Vol 793 ◽  
Author(s):  
Kuei-Fang Hsu ◽  
Sim Loo ◽  
Wei Chen ◽  
Ctirad Uher ◽  
Tim Hogan ◽  
...  

ABSTRACTAgPb10SbTe12 is one member of the cubic family of materials AgPbmSbTem+2, which adopts NaCl structure where Ag, Pb and Sb atoms occupy the Na site and Te atoms occupy the Cl site. Ingots of this compound were prepared by a solid state reaction for thermoelectric measurements. AgPb10SbTe12 is a narrow band gap semiconductor with Eg∼0.26 eV. In order to optimize the ZT of this member, compositions with deficiency of Ag and Bi-substitution were examined and found to exhibit enhanced power factor at 300 K. The Bi-substituted ingot had ZT∼0.39 at 300 K and ZT∼0.68 at 400 K. Carrier concentration and the mobility measurements are reported.


2014 ◽  
Vol 2 (48) ◽  
pp. 20621-20628 ◽  
Author(s):  
Sheng-Ping Guo ◽  
Guo-Cong Guo

New mixed-chalcogenide Dy4S4Te3 was synthesized by a facile high-temperature solid-state reaction based on energy gap engineering, polycrystalline powder shows photocatalytic activity for the decomposition of rhodamine B under halogen lamp irradiation.


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