Photoluminescence properties of Pr3+, Sm3+ and Tb3+ doped SrAlSi4N7 and energy level locations of rare-earth ions in SrAlSi4N7

2014 ◽  
Vol 2 (37) ◽  
pp. 7952-7959 ◽  
Author(s):  
Zhi-Jun Zhang ◽  
Otmar M. ten Kate ◽  
Anneke Delsing ◽  
Pieter Dorenbos ◽  
Jing-Tai Zhao ◽  
...  

RE3+ (RE = Pr, Sm, and Tb)-doped SrAlSi4N7 samples were synthesized by a solid-state reaction method at high temperature, and their photoluminescence properties were investigated.

2016 ◽  
Vol 4 (16) ◽  
pp. 3443-3453 ◽  
Author(s):  
Kai Li ◽  
Sisi Liang ◽  
Hongzhou Lian ◽  
Mengmeng Shang ◽  
Bengang Xing ◽  
...  

A series of Ce3+ and Tb3+-doped BaLu2Si3O10 (BLSO) phosphors synthesized via the high-temperature solid-state reaction method were investigated.


2013 ◽  
Vol 815 ◽  
pp. 677-681 ◽  
Author(s):  
Wei Liang ◽  
Liang Feng Niu ◽  
Yuan Hao Gao ◽  
Yu Hua Wang

In present work, K2Y1-xZr (PO4)3:Prx3+(0.01x0.05) samples were prepared by solid-state reaction method and their photoluminescence properties were investigated in ultra-violet (UV) and vacuum ultra-violet (VUV) region. The photon cascade luminescence (PCL) of Pr3+had been observed. All the results indicate that, in this Pr3+-doped K2YZr (PO4)3phosphor, even if the1S0state is higher than the lowest 4f5d energy level, the photon cascade emission (PCE) process for Pr3+still could occur under 147 nm and 234 nm (4f15d1state) excitation. Therefore, K2YZr (PO4)3was an ideal host for Pr3+to implement the PCE process successfully.


2018 ◽  
Vol 6 (41) ◽  
pp. 19967-19973 ◽  
Author(s):  
Zhenyong Cen ◽  
Yu Huan ◽  
Wei Feng ◽  
Yan Yu ◽  
Peiyao Zhao ◽  
...  

Lead-free (1 − x)(0.96K0.46Na0.54Nb0.98Ta0.02O3–0.04Bi0.5(Na0.82K0.18)0.5ZrO3)–xCaZrO3 ((1 − x)(0.96KNNT–0.04BNKZ)–xCZ) piezoelectric ceramics were prepared by the conventional solid-state reaction method.


2020 ◽  
Vol 18 (11) ◽  
pp. 14-18
Author(s):  
Abbas K. Saadon ◽  
Kareem A. Jasim ◽  
Auday H. Shaban

The high temperature superconductor’s compounds are one of the hot spot field of science, due to their applications in industries. Hg0.8Sb0.2Ba2Ca2Cu3O8+δ and Hg0.8Sb0.2Ba2Ca1Cu2O6+δ, were manufactured using a doable-step of solid state reaction method. The samples were sintered at 800 ° C. The transition temperatures Tc are found from electrically resistively by using four probe techniques. The resistivity become zero when the transition temperature Tc(offset) have 131 and 119 K, and the onset temperature Tc(onset) have 139 K for Hg0.8Sb0.2Ba2Ca2Cu3O8+δ and 132 K for Hg0.8Sb0.2Ba2Ca1Cu2O6+δ. Analysis of X-ray diffraction showed a tetragonal structure with lattice parameters changes for all samples.


RSC Advances ◽  
2014 ◽  
Vol 4 (22) ◽  
pp. 11360-11366 ◽  
Author(s):  
Yahong Jin ◽  
Yihua Hu ◽  
He Duan ◽  
Li Chen ◽  
Xiaojuan Wang

The blue emitting long persistent phosphor (LPP) Li2ZnGeO4 and green emitting LPP Li2ZnGeO4:Mn2+ were newly prepared by a high temperature solid-state reaction method.


2015 ◽  
Vol 3 (27) ◽  
pp. 7096-7104 ◽  
Author(s):  
Kai Li ◽  
Mengmeng Shang ◽  
Yang Zhang ◽  
Jian Fan ◽  
Hongzhou Lian ◽  
...  

A series of Ca9Bi(PO4)7:Ce3+,Tb3+,Mn2+phosphors synthesizedviathe high-temperature solid-state reaction method can emit intense tunable color from purple-blue to red including white under UV excitation, which shows their potential application in UV-pumped white-light-emitting diodes.


2012 ◽  
Vol 512-515 ◽  
pp. 1488-1493 ◽  
Author(s):  
Li Hong Liu ◽  
Rong Jun Xie ◽  
Xu Dong Sun ◽  
Qing Huang ◽  
Naoto Hirosaki

This paper reports the photoluminescence properties of Ca9Eu1-xSmx(VO4)7 (x=0.2-0.4) synthesized at 1250 oC in air for 12 h using traditional solid-state reaction method. With the increase of Sm3+ substitution amount, purity Ca9Eu1-xSmx(VO4)7 phase was obtained even when the Eu3+ ions were totally substituted by Sm3+. The experimental results showed that when Sm3+ was codoped with Eu3+ into Ca9Eu1-xSmx(VO4)7 crystal structure, Sm3+ would act as a sensitizer and transfer the excitation energy to Eu3+ ions and finally enhance the emission intensity of Ca9Eu1-xSmx(VO4)7 under 405 nm excitation, which leads to more favorite of this kind of phosphor used in UV LED based white LEDs.


RSC Advances ◽  
2017 ◽  
Vol 7 (60) ◽  
pp. 37765-37770 ◽  
Author(s):  
Huanhuan Liu ◽  
Long Yuan ◽  
Hui Qi ◽  
Yanyan Du ◽  
Shan Wang ◽  
...  

Reversible thermochromic inorganic materials of Sm3Fe5O12with different particle sizes have been synthesized by a conventional high temperature solid state reaction method (2.51 μm) and sol–gel method (0.16 μm).


2011 ◽  
Vol 497 ◽  
pp. 31-37 ◽  
Author(s):  
Toru Kyomen ◽  
Ryuta Motani ◽  
Minoru Hanaya

Powder of Pr-doped CaTiO3 red phosphor was prepared at 1473 K by a conventional solid-state reaction method with addition of B2O3 or SiO2 as a flux. Primary particle sizes of the prepared samples were increased by using B2O3 flux but decreased by using SiO2 flux. Clear planes, edges, or steps were observed on surfaces of the primary particles. The intensity of photoluminescence induced by irradiation of light with a wavelength longer than ∼350 nm was enhanced about three times by using B2O3 flux. The intensity of photoluminescence induced by irradiation of light with a wavelength shorter than ∼350 nm was enhanced about twice by using either B2O3 or SiO2 fluxes. The origin for the flux effects is discussed.


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