Tetrabutylammonium tribromide impregnated MCM-48 as a heterogeneous catalyst for selective oxidation of sulfides

RSC Advances ◽  
2015 ◽  
Vol 5 (48) ◽  
pp. 38044-38047 ◽  
Author(s):  
Prasanta Gogoi ◽  
Sukanya Hazarika ◽  
Pranjit Barman

We report here tetrabutylammonium tribromide supported on MCM-48 as a highly efficient heterogeneous catalyst for the selective oxidation of sulfides, in ethanolic medium using hydrogen peroxide as an oxidant.

2018 ◽  
Vol 149 (1) ◽  
pp. 141-150 ◽  
Author(s):  
Apurba Dutta ◽  
Mitali Chetia ◽  
Abdul A. Ali ◽  
Ankur Bordoloi ◽  
Praveen S. Gehlot ◽  
...  

2015 ◽  
Vol 19 (12) ◽  
pp. 1232-1237 ◽  
Author(s):  
Saeed Rayati ◽  
Fatemeh Nejabat ◽  
Nasireh Naghashian

In the present research meso-tetrakis(4-carboxyphenyl)porphyrinatomanganese(III) acetate (Mn(TCPP)OAc) nanoparticles have been prepared for the first time without any stabilizing agent or supporting matrix under ultrasonic irradiation. Scanning electron microscopy (SEM) was used to characterize and investigate the nanocatalyst. Rapid, efficient, facile and highly selective oxidation of a wide range of olefins by tetra-[Formula: see text]-butylammonium hydrogen monopersulfate over the prepared manganese nanocatalyst was investigated. Also oxidation of sulfides and alkanes in the presence of the (Mn(TCPP)OAc) nanoparticles were studied. The catalyst is recovered by filtration and reused at least five times.


RSC Advances ◽  
2014 ◽  
Vol 4 (83) ◽  
pp. 44274-44281 ◽  
Author(s):  
Ahmad Bayat ◽  
Mehdi Shakourian-Fard ◽  
Nona Ehyaei ◽  
Mohammad Mahmoodi Hashemi

Selective oxidation of sulfides to corresponding sulfoxides using H2O2 as a green oxidant at room temperature have been investigated by a magnetic supported iron (iron(ii) acetylacetonate) as an efficient and recyclable heterogeneous catalyst with excellent sulfide conversion and good sulfoxide selectivity.


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