Pd nanoparticles embedded in the outershell of a mesoporous core–shell catalyst for phenol hydrogenation in pure water

RSC Advances ◽  
2015 ◽  
Vol 5 (124) ◽  
pp. 102811-102817 ◽  
Author(s):  
Fengwei Zhang ◽  
Shuai Chen ◽  
Huan Li ◽  
Xian-Ming Zhang ◽  
Hengquan Yang

The Pd/MCN@MS-NH2catalyst simultaneously contains a hydrophobic carbon core and a hydrophilic silica shell, which is inclined to concentrate the phenol substrate around the active Pd NPs and exclude the cyclohexanone product from the catalyst surface.

Author(s):  
Yifu Zhang ◽  
Fangfang Zhang ◽  
Lei Yu ◽  
Meijuan Fan ◽  
Yalan Zhong ◽  
...  

2015 ◽  
Vol 17 (3) ◽  
pp. 1907-1917 ◽  
Author(s):  
Paolo Dambruoso ◽  
Marco Ballestri ◽  
Claudia Ferroni ◽  
Andrea Guerrini ◽  
Giovanna Sotgiu ◽  
...  

Photons and electrons cooperate for effective, clean sulfoxidations in pure water.


2015 ◽  
Vol 51 (5) ◽  
pp. 2550-2557 ◽  
Author(s):  
Shihao Xu ◽  
Yingguo Zhao ◽  
Fangcai Zheng ◽  
Yuanguang Zhang

RSC Advances ◽  
2016 ◽  
Vol 6 (17) ◽  
pp. 13873-13880 ◽  
Author(s):  
Xiaoling Lang ◽  
Meiqin Shi ◽  
Yekun Jiang ◽  
Huan Chen ◽  
Chunan Ma

The Pt–WC@C demonstrates higher electrochemical activity, which could be attributed to the better dispersed Pt on WC which leads to the improved synergistic effect between WC and Pt.


2020 ◽  
Vol 2 (11) ◽  
pp. 4996-5014
Author(s):  
Ruth Sang Jones ◽  
Barbara Maciejewska ◽  
Nicole Grobert

This review explores the rapidly emerging field of hetero-nanotubes consisting of a carbon core and hexagonal boron nitride shell.


2011 ◽  
Vol 172-174 ◽  
pp. 670-675 ◽  
Author(s):  
Ivailo S. Atanasov ◽  
Marc Hou

We address the question of the evolution of a nanostructured system in a metastable state to equilibrium. To this purpose, we use the case study of the transition of an AucorePdshell nanoalloy cluster containing up to about 600 atoms toward the equilibrium Au segregated configuration. We start from a molecular dynamics approach with an embedded atom potential. The way the transition develops at low temperatures is found to be very sensitive to the cluster morphology and the way energy is exchanged with the environment. The transition of icosahedral inverse core-shell Au-Pd clusters is predicted to nucleate locally at the surface contrary to clusters with other morphologies, and starting at lower temperatures compared to them.


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